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Electronic Excited States of Adsorbed Molecules

Research Project

Project/Area Number 09640704
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field 機能・物性・材料
Research InstitutionThe Institute of Physical and Chemical Research (RIKEN)

Principal Investigator

MUNAKATA Toshiaki  RIKEN,Microwave Physics Laboratory, Senior Scientist, マイクロ波物理研究室, 先任研究員 (20150873)

Project Period (FY) 1997 – 1998
Project Status Completed (Fiscal Year 1998)
Budget Amount *help
¥3,200,000 (Direct Cost: ¥3,200,000)
Fiscal Year 1998: ¥500,000 (Direct Cost: ¥500,000)
Fiscal Year 1997: ¥2,700,000 (Direct Cost: ¥2,700,000)
KeywordsTwo-photon photoemission / benzene / copper / surface electronic phenomena / adsorption / electronic excited state / desorption / フェムト秒レーザー / フェトム秒レーザー
Research Abstract

When a molecule is adsorbed on a metal surface, new electronic states are formed in the vicinity of the Fermi level (E_F). Identification of the adsorption-induced electronic states, which act as frontier orbitals in chemical reactions at surfaces, is still an experimental challenge. Two-photon photoemission (2PPE) spectroscopy is used to probe normally unoccupied electronic states, but has a capability to probe the occupied and unoccupied states at the same time. Here a bonding electronic state induced by benzene adsorption on Cu (111) has been observed by means of 2PPE spectroscopy. The adsorption-induced bonding state is found at 0.3 eV blow E_F. Photoemission from the bonding state, which is weak in conventional one photon photoemission, is greatly enhanced by resonance with the image potential state. An angle resolved photoemission work for a benzene-adsorbed Cu (111) surface with photon energy of 5.45 eV has revealed that an adsorption-induced state due to hybridization of benzene pi^* and copper shows dispersion with electron momentum along the surface. The dispersion is well reproduced by a parabola with an effective electron mass ratio m^*/m_C=0.9. This suggests that the bonding state extends many copper lattice spacing from the adsorbed molecule. The bonding orbital is thought to be the origin of long range interactions of molecules on a metal surface.

Report

(3 results)
  • 1998 Annual Research Report   Final Research Report Summary
  • 1997 Annual Research Report
  • Research Products

    (15 results)

All Other

All Publications (15 results)

  • [Publications] T.Munakata: "Fine structure of the two-photon photoemission from benzene adsorbed on Cu(111)." Chem.Phys.Letters,. 271. 377-380 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] T.Munakata: "Two-Photon photoemission from Benzene Adsorbed on Cu(111)." J.Electron Spectrosc.Rel.Phenom.,. 88-91. 591-595 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] T.Munakata: "Two-Photon photoemission from adsorption-induced electoronic states of benzene/Cu(111)." Surf.Sci.印刷中.

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] T.Munakata: "Dispersion of an adsorption-induced electronic state of benzen/Cu(111)." J.Chem.Phys.110. 2736-2737 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] T.Munakata, T.Sakashita, M.Tsukakoshi and J.Nakamura: "Fine structure of the two-photon photoemission from benzene adsorbed on Cu(111)" Chem.Phys.Letters. 271. 377-380 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] T.Munakata, T.Sakashita, and K.Shudo: "Two-Photon Photoemission from Benzene Adsorbed on Cu(111)" J.Electron Spectrosc.Rel.Phenom.88-91. 591-595 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] T.Munakata and K.Shudo: "Two-photon photoemision from adsorption-induced electronic states of benzene/Cu(111)" Surf.Sci.in press.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] T.Munakata: "Dispersion of an adsorption-induced electronic state of benzene/Cu(111)" J.Chem.Phys.110. 2736-2737 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] T.Munakata: "Fine structure of the two-photon photoemission from benzene adsorbed on Cu(111)" Chem.Phys.Letters,. 271. 377-380 (1997)

    • Related Report
      1998 Annual Research Report
  • [Publications] T.Munakata: "Two-photon Photoemission from Benzene Adsorbed on Cu(111)." J.Electron Spectrosc.Rel.Phenom.88-91. 591-595 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] T.Munakata: "Two-photon photoemision from adsorption-induced electronic states of benzene/Cu(111)." Surf.Sci.(印刷中).

    • Related Report
      1998 Annual Research Report
  • [Publications] T.Munakata: "Dispersion of an adsorption-induced electronic state of benzene/Cu(111)." J.Chem.Phys.,. 110. 2736-2737 (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] T.Munakata: "Fine structure of the two-photon photoemission from benzene adsorbed Cu(111)" Chemical Physics Letters. 271. 377-380 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] T.Munakata: "Two-photon photoemission from benzcne adsorbed on Cu(111)" J.Electron Spectrosc.Rel.Phenom.(印刷中).

    • Related Report
      1997 Annual Research Report
  • [Publications] 坂下 武: "吸着ベンゼンの2光子光電子分光" レーザー科学研究. 19. 93-95 (1997)

    • Related Report
      1997 Annual Research Report

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Published: 1997-04-01   Modified: 2016-04-21  

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