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IMPROVEMENT IN MEASURING OSCILLATION BEHAVIOR OF NONLINEAR CHEMICAL REACTIONS UNDER MICROGAVITY

Research Project

Project/Area Number 09640718
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field 分離・精製・検出法
Research InstitutionOCHANOMIZU UNIVERSITY

Principal Investigator

FUJIEDA Shuko  OCHANOMIZU UNIVERSITY,DEPARTMENT OF CHEMISTRY,PROFESSOR, 理学部, 教授 (70017200)

Co-Investigator(Kenkyū-buntansha) SHIBATA Fumiaki  OCHANOMIZU UNIVERSITY,DEPARTMENT OF PHYSICS,PROFESSOR, 理学部, 教授 (20011702)
富田 功  お茶の水女子大学, 理学部, 教授 (60015518)
Project Period (FY) 1997 – 1998
Project Status Completed (Fiscal Year 1998)
Budget Amount *help
¥3,200,000 (Direct Cost: ¥3,200,000)
Fiscal Year 1998: ¥800,000 (Direct Cost: ¥800,000)
Fiscal Year 1997: ¥2,400,000 (Direct Cost: ¥2,400,000)
KeywordsCHEMICAL OSCILLATION REACTION / BELOUSOV-ZHABOTINSKY REACTION / MICROGRAVITY / GRAVITY / NONLINEAR REACTION / COMPLEX SCIENCE / IMAGE DATA / CHEMICAL WAVES OF REACTION-DIFFUSION SYSTEM / ベロ-ゾフ-ザボチンスキー反応 / 無重力場
Research Abstract

Kondepudi and Prigogine indicated theoretically that nonequilibrium system might be influenced largely on the selection and the creation of structure even in very week gravitational field. Belousov-Zhabotinsky (BZ) reactions are typical of a chemical oscillation reaction and well known as nonlinear chemical phenomena in nonequilibrium process. In the present study, for the purpose of inspecting experimentally the theoretical research, the transfer velocity of chemical waves in the diffusion-reaction system of BZ reaction were observed accurately as image data under microgravity condition by improving the starting materials and reaction vessels. The reaction solution was composed of bromate, sulfuric acid, ferroin and 1,4-cyclohexanedione (CHD) for a bubble free system. The free-fall facility of JAMIC (Japan Microgravity Center, Kami-sunagawa, Hokkaido) was used to generate microgravitational circumstance. The good quality of microgravity was available for 9.8 s. The image data observed via CCD camera and 8 mm video deck were analyzed by NIH image. In glass tubing vessels, transfer velocities of the chemical waves were successfully estimated in the series under normal gravity before falling, microgravity in falling, large gravity for ending and again normal gravity after falling.

Report

(3 results)
  • 1998 Annual Research Report   Final Research Report Summary
  • 1997 Annual Research Report
  • Research Products

    (15 results)

All Other

All Publications (15 results)

  • [Publications] S.Fujieda, et al.: "Automated Experimental Assembly for Studying the Reaction-Diffusion Behavior of Belousov-Zhabotisky Reactions iinder Microgravity" Analytical Sciences. 15. 159-164 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] S.Fujieda, et al.: "Nonequilibrium / nonlinear Chemical Oscillation in the Virtual Absence of Gravity" Advances in Space Research. 印刷中. (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] F.Shibata, et al.: "Periodically Driven Linear System with Multiplicative Colpured Noise" Physical Review. E57. 6555-6563 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Shuko Fujieda, Yoshihito Mogami, Wei Zhang, Hiromi Shinohara and Sayaka Handa: "Automated Experimental Assembly for Studying the Reaction-Diffusion Behavior of Belousov-Zhabotinsky Reactions under Microgravity" Analytical Sciences. 15. 159-164 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Shuko Fujieda, Yoshihiro Mogami, Keiko Moriyasu and Yoshihito Mori: "Nonequilibrium/Nonlinear Chemical Oscillation in the Virtual Absence of Gravity" Advances in Space Research. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] A.V.Barzykin, K.Seki and F.Shibata: "Periodically Driven Linear System with Multiplicative Colored Noise" Phys.Rev.E. 57. 6555-6563 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] S.Fujieda et al.: "Automated Experimental Assembly for Studying the Reaction-Diffusion Behavior of Belousor-Zhabotiusky Reactions under Microgravity" Analytical Science. 15・2. 159-164 (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] S.Fujieda et al.: "Nonequilibrium/Nonlinear Chemical Oscillation in the Virtual Absence of Gravity" Advances in Space Research. 印刷中. (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] F.Shibata et al.: "Periodically Driven hinear System with Multiplicative Colourea Noise" Physical Review. E57. 6555-6563 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] S.Fujieda, Y.Mogami, A.Furuya, W.Zhang et al.: "Effect of Microgravity on the Spatial Oscillation Behavior of Belousov-Zhabotinsky Reactions Catalyzed by Ferroin" J.Phys.Chem.A. 101, No.43. 7926-7928 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] M.Murao, F.Shibata: "Quantum Dynamics of a Strongly Caupled Dissipative System Toward Thermal Equilibrium II" Physica A. 238. 265-278 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] S.Fujieda, H.Ogata: "Calorimetry and potentiometry of chemical oscillation in Briggs-Rauscher reactions with simultaneous measurements of the produced oxygen-volume" Talanta. 43. 1989-1995 (1996)

    • Related Report
      1997 Annual Research Report
  • [Publications] S.Fujieda, Y.Mogami, W.Zhang, T.Araiso: "Experimental System Assembled for Studying the Chemical Oscillation Behavior of Belousov-Zhabotinsky Reactions in the Microgravity" Anal.Sci.12. 815-818 (1996)

    • Related Report
      1997 Annual Research Report
  • [Publications] I.Tomita, A.Enomoto, Y.Hasegawa, Y.Watanabe: "Intercalation of porphyrin (TMPyP) and copper-porphyrin into γ-zirconium phosphate" J.Incl.Phenom.23. 213-221 (1996)

    • Related Report
      1997 Annual Research Report
  • [Publications] C.Uchiyama, F.Shibata: "A Systematic Projection Operator Formaism in Non-Equilibrium Statistical Mechanics" J.Phys.Soc.Jpn.65,No.4. 887 (1996)

    • Related Report
      1997 Annual Research Report

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Published: 1997-04-01   Modified: 2016-04-21  

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