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Fabrication of high-potential nanocomposite magnets by controlling crystallite orientation

Research Project

Project/Area Number 09650002
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Applied materials science/Crystal engineering
Research InstitutionTohoku University

Principal Investigator

KATO Hiroaki  Graduate School of Engineering, Tohoku University, Associate Professor, 大学院・工学研究科, 助教授 (40177465)

Co-Investigator(Kenkyū-buntansha) KUBOTA Hitoshi  Graduate School of Engineering, Tohoku University, Research Associate, 大学院・工学研究科, 助手 (30261605)
Project Period (FY) 1997 – 1998
Project Status Completed (Fiscal Year 1998)
Budget Amount *help
¥3,400,000 (Direct Cost: ¥3,400,000)
Fiscal Year 1998: ¥800,000 (Direct Cost: ¥800,000)
Fiscal Year 1997: ¥2,600,000 (Direct Cost: ¥2,600,000)
Keywordsnanocomposite magnet / exchange coupling / heated-substrate sputtering / permanent magnet / SmFe_<12> / alpha-Fe / Nd_2(Fe_<1-x>Co_x)_<14>B / high-field-annealing / 基板加熱スパッタ法 / 強磁場中熱処理
Research Abstract

1. Fabrication of highly-oriented SmFe_<12>/alpha-Fe nanocomposite films
We have successfully fabricated a series of nanocomposite films composed of c-axis oriented SmFe_<12> (hard magnetic phase) and alpha-Fe (soft phase), and investigated the relation between the degree of orientation and magnetic properties. (1), sub/Ti/(SmFe_<12>, alphaFe)/Ti films : Although exchange-coupled nanocomposite films have been obtained over the entire range of alpha-Fe fraction VFe, the orientation of SmFe_<12> has been changed from (001)-texture to the mixture of (101) and (001) textures with increasing V_<Fe>. Both coercive force Hc and maximum energy product (BH)_<max> took a maximum around V_<Fe>=6%. (2), sub/(SmFe_<12>, alpha-Fe)/Ti films : By removing the Ti underlayers, we have for the first time succeeded to fabricate the highly-oriented SmFe_<12>/alpha-Fe nanocomposite films, in which(001)-texture has been kept up to V_<Fe>-50%. Both Hc and(BH)_<max> took a maximum around V_<fe> 25%, where (BH)_ … More <max> of 20 MGOe was obtained. (3), In order to analyze the origin of the magnetic properties, especially of the Hc increase, we have made a micromagnetic calculation and compared it with the experiment We then found that observed V_<Fe> dependence of H_c could be explained by using parameters of the weak exchange-coupling between hard phases and strong coupling between soft-hard phases.
2. Fabrication of Nd-Fe-Co-B nanocomposite ribbons by high-field-annealing
In order to orient the easy axis of hard magnetic phase in bulk nanocomposite samples, we have investigated the effect of high-field annealing on the crystallization of amorphous ribbons, composed of Nd2(Fe_<1-x>Co_x)14B as a hard phase and (Fe_<1-x>Co_x) as a soft phase. It is found that, when the annealing temperature is below the Curie temperature of the hard phase, the volume fraction of the hard phase is larger in the field of 100 kOe than that in zero field. Any significant deviation from the random alignment has not been observed up to now Less

Report

(3 results)
  • 1998 Annual Research Report   Final Research Report Summary
  • 1997 Annual Research Report
  • Research Products

    (20 results)

All Other

All Publications (20 results)

  • [Publications] 野村拓哉: "基板加熱スパッタによるSmFe_<12>/α-Fe系ナノコンポジット薄膜の作製" 日本応用磁気学会誌. 23, 4-2印刷中. (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] 石曽根昌彦: "Nd-Fe-B/α-Fe系ナノコンポジット薄膜の磁気特性" 日本応用磁気学会誌. 23, 4-2印刷中. (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] M.Ishizone: "Fabrication and magnetic properties of exchange-coupled Nd-Fe-B/Fe nanocomposite thin films" Journal of the Magnetics Society of Japan. 23, 1-2. 282-284 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] H.Kato: "Spin-reorientation and magnetostriction in highly oriented (Er_<1-x>Tb_x)_2Fe_<14>B" Journal of the Magnetics Society of Japan. 23, 1-2. 495-497 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] H.Kato: "Magnetic properties of random-anisotropy amorphous magnets (R_xFe_<1-x>)_<80>Si_<12>B_8 with R=Pr, Nd, Sm, Tb, Dy and Er" Journal of Magnetism & Magnetic Materials. 189, 3. 263-273 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] M.Shindo: "Magnetic properties of exchange-coupled α-Fe/Nd-Fe-B multilayer thin-film magnets" Journal of Applied Physics. 81, 8. 4444-4446 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] T.Nomura, H.Kato, M.Ishizone, H.Kubota, T.Miyazaki and M.Motokawa: "Fabrication of SmFe_<12>/alpha-Fe nanocomposite films by rf-sputtering onto heated substrates" J.Magn.Soc.Japan. 23-4-2 (in printing). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] M.Ishizone, H.Kato, T.Miyazaki, M.Shindo, A.Sakuma and M.Motokawa: "Magnetic properties of Nd-Fe-B/alpha-Fe nanocomposite thin films" J.Magn.Soc.Japan. 23-4-2 (in printing). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] M.Ishizone, H.Kato, T.Miyazaki, M.Shindo, and A.Sakuma: "Fabrication and magnetic properties of exchange-coupled Nd-Fe-B/Fe nanocomposite thin films" J.Magn.Soc.Japan. 23-1-2. 282-284 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] H.Kato, T.Ishizaki, F.Sato and T.Miyazaki: "Spin-reorientation and magnetostriction in highly oriented (Er_<1-x>Tb_x)_2Fe_<14>B" J.Magn.Soc.Japan. 23-1-2. 495-497 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] H.Kato, N.Kurita, Y.Ando, T.Miyazaki and M.Motokawa: "Magnetic properties of random-anisotropy amorphous magnets (R_xFe_<1-x>)_<80>Si_<12>B_8 with R=Pr, Nd, Sm, Tb, Dy and Er" J.Magn.Magn.Mater.189-3. 263-273 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] M.Shindo, M.Ishizone, A.Sakuma, H.Kato and T.Miyazaki: "Magnetic properties of exchange-coupled alpha-Fe/Nd-Fe-B multilayer thin-film magnets" J.Appl.Phys.81-8. 4444-4446 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] 野村拓哉: "基板加熱スパッタによるSmFe_<12>/α-Fe系ナノコンポジット薄膜の作製" 日本応用磁気学会誌. 23,4-2(印刷中). (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] 石曽根昌彦: "Nd-Fe-B/α-Fe系ナノコンポジット薄膜の磁気特性" 日本応用磁気学会誌. 23,4-2(印刷中). (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] M.Ishizone: "Fabrication and magnetic properties of exchange-coupled Nd-Fe-B/Fe nanocomposite thin films" Journal of the Magnetics Society of Japan. 23,1-2. 282-284 (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] H.Kato: "Spin-reorientation and magnetostriction in highly oriented (Er_<1-x>Tb_x) _2Fe_<14>B" Journal of the Magnetics Society of Japan. 23,1-2. 495-497 (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] H.Kato: "Magnetic properties of random-anisotropy amorphous magnets (R_xFe_<1-x>) _<80>Si_<12>B_8" Journal of Magnetism & Magnetic Materials. 189,3. 263-273 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 今岡伸嘉: "Mn添加Sm_2Fe_<17>N_xの磁気特性と微細構造" 日本応用磁気学会誌. 22,4-2. 353-356 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] M.Shindo: "Magnetic properties of exchange-coupled α-Fe/Nd-Fe-B multilayer thin-film magnets" Journal of Applied Physics. 81,8. 4444-4446 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 新藤 幹夫: "α-Fe/Nd-Fe-B交換結スパッタ多層膜の磁気特性" 日本応用磁気学会誌. 21,4-2. 361-364 (1997)

    • Related Report
      1997 Annual Research Report

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Published: 1997-04-01   Modified: 2016-04-21  

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