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STUDY ON LOW TEMPERATURE FORMATION OF VERY THIN AND HIGH-QUALITY Si-BASED INSULATING FILMS AND ITS FUNCTIONAL EVALUATION

Research Project

Project/Area Number 09650363
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Electronic materials/Electric materials
Research InstitutionKYUSHU UNIVERSITY

Principal Investigator

NAKASHIMA Hiroshi  ADVANCED SCIENCE AND TECHNOLOGY CENTER FOR COOPERATIVE RESEARCH,KYUSHU UNIVERSITY,ASSOCIATE PROFESSOR, 先端科学技術共同研究センター, 助教授 (70172301)

Co-Investigator(Kenkyū-buntansha) FURUKAWA Katsuhiko  ADVANCED SCIENCE AND TECHNOLOGY CENTER FOR COOPERATIVE RESEARCH,KYUSHU UNIVERSIT, 先端科学技術共同研究センター, 助手 (40264121)
Project Period (FY) 1997 – 1998
Project Status Completed (Fiscal Year 1998)
Budget Amount *help
¥3,400,000 (Direct Cost: ¥3,400,000)
Fiscal Year 1998: ¥1,400,000 (Direct Cost: ¥1,400,000)
Fiscal Year 1997: ¥2,000,000 (Direct Cost: ¥2,000,000)
KeywordsSILICON / VERY THIN FILM / ECR PLASMA / LOW TEMPERATURE FORMATION OF THIN FILM / ELECTRICAL FUNCTIONALITY / SPUTTERING / 低温薄膜形成
Research Abstract

This research aimed to establish techniques for fabricating very thin and high quality Si-based insulating films at low temperature by using sputtering-type ECR plasma and to find the functionality of the deposited films, The results are summarized as follows :
1.we have established the deposition techniques of SiO_2 having breakdown field 0110 MV/cm at low temperature of 130゚C
2.We have succeeded in the fabrication of very thin SiO_2 having a thickness of 9 nm which showed high breakdown characteristics of 9 MV/cm interface state densities of less than 1CHIl0^<1I>cm^<-2>eV^<-1>, and fixed charge of less than 1CHIl0^<1I>cm^<-2>.
3.We have succeeded in the fabrication of SiON films having breakdown characteristics of 13 MV/cm at low temperature of 130゚C by optimizing the plasma from mixture gases of oxygen and nitrogen.
4.Dense SiN film was deposited by using sputtering-type ECR plasma at room temperature. The refractive index, chemical etching rate, IR characteristics of the SiN films had almost the same as that deposited by CVD at 900 ゚C.

Report

(3 results)
  • 1998 Annual Research Report   Final Research Report Summary
  • 1997 Annual Research Report
  • Research Products

    (27 results)

All Other

All Publications (27 results)

  • [Publications] H. Nakashima: "Low-temperature deposition of high-quality silicon dioxide films by sputtering-type electron cyclotron resonance plasma" J. Vac. Sci. Technol. A. 15. 1951-1954 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] K.Furukawa: "In situ FT-IR reflective absorption spectroscopy for characterization of SiO2 thin films from deposited using sputtering-type electron cyclotron resonance microwave plasma" Appl. Surf. Sci.121/122. 228-232 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Y. C. Liu: "In-situ infrared relective absorption spectroscopy characterization of SiN films deposited using sputtering-type ECR microwave plasma" Appl. Surf. Sci.121/122. 233-236 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] D. W. Gao: "Effect of preoxidation on deposition of thin-gate quality silicon oxide film at low by using a sputter-type electron cyclotron resonance plasma" J. Appl. Phys.82. 5680-5685 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] D. W. Gao: "Deposition of high-quality silicon oxynitride film at low temperature by using a sputtering-type electron cyclotron resonance plasma" Jpn. J. Appl. Phys.36. L1692-L1694 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] K. Furukawa: "Observation of Si Cluster Formation in SiO_2 Films through Annealing Process using x-ray Photoelectron Spectroscopy and Infrared Techniques" Appl. Phys. Lett.72. 725-727 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] K. Furukawa: "Effects of Oxygen Content on Properties of Silicon Oxide Films Prepared at Room Temperature by Sputtering-type Electron Cyclotron Resonance Plasma" J. Appl. Phys.84. 4579-4584 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] 中島 寛: "スパッタ堆積による高品位Si系絶縁膜の形成" インテリジェント材料. 8. 16-20 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Y.C.Liu: "Compositional and Structural Studies of Amorphous Silicon-Nitrogen Alloys Deposited at Room Temperature using a Sputtering-type ECR Microwave Plasma" Philosophical Magazine. 79. 137-148 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] H.Nakashima, H.Nakashima, K.Furukawa, Y.C.Liu, D.W.Gao, Y.Kashiwazaki, K.Muraoka, K.Shibata, and T.Tsurushima: ""Low-temperature deposition of high-quality silicon dioxide films by sputtering-type electron cyclotron resonance plasma"" J.Vac.Sci.Technol.A.Vol.15. 1951-1954 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] K.Furukawa, Y.C.Liu, D.W.Gao, H.Nakashima, K.Uchino, K.Muraoka: ""In situ FT-IR reflective absorption spectroscopy for characterization of SiO2 thin films from deposited using sputtering-type electron cyclotron resonance microwave plasma"" Appl.Surf.Sci.Vols.121/122. 228-232 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Y.C.Liu, K.Furukawa, D.W.Gao, H.Nakashima, K.Uchino, K.Muraoka: ""In-situ Infrared Reflective Absorption Spectroscopy Characterization of SiN Films Deposited using Sputtering-type ECR Microwave Plasma"" Appl.Surf.Sci.Vols.121/122. 233-236 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] D.W.Gao, Y.Kashiwazaki, K.Muraoka, H.Nakashima, K.Furukawa, Y.C.Liu, K.Shibata, T.Tsurushima: ""Effect of Preoxidation on Deposition of Thin Gate-quality Silicon Oxide Film at Low Temperature by using a Sputter-type Electron Cyclotron Resonance Plasma"" J.Appl.Phys.Vol.82, No.11. 5680-5685 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] D.W.Gao, Y.Kashiwazaki, K.Muraoka, H.Nakashima, K.Furukawa, Y.C.Liu, T.Tsurushima: ""Deposition of High-quality Silicon Oxynitride Film at Low Temperature by using a Sputtering-type Electron Cyclotron Resonance Plasma"" Jpn.J.Appl.Phys.Vol.36, No.12B. L1692-1694 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] K.Furukawa, Y.C.Liu, D.W.Gao, H.Nakashima, K.Uchino, K.Muraoka, H.Tsuzuki: ""Observation of Si Cluster Formation in SiO_2 Films through Annealing Process using x-ray Photoelectron Spectroscopy and Infrared Techniques"" Appl.Phys.Lett.Vol.72, No.6. 725-727 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] K.Furukawa, Y.Liu, H.Nakashima, D.W.Gao, Y.Kashiwazaki, K.Uchino, K.Muraoka, H.Tsuzuki: ""Effects of Oxygen Content on Properties of Silicon Oxide Films Prepared at Room Temperature by Sputtering-type Electron Cyclotron Resonance Plasma" J.Appl.Phys.Vol.84, No.8. 4579-4584 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Hiroshi nakashima: ""Deposition of High-quality Si-Based Insulating films using Sputtering Techniques"" Intelligent Materials. Vol.8, No.2. 16-20 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Y.C.Liu, K.Furukawa, H.Nakashima, Y.Kashiwazaki, D.W.Gao, K.Uchino, K.Muraoka, H.Tsuzuki: ""Compositional and Structural Studies of Amorphous Silicon-Nitrogen Alloys Deposited at Room Temperature using a Sputtering-type ECR Microwave Plasma" Philosophical Magazine. Vol.79. 137-148 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] K. Furukawa: "Observation of Si Cluster Formation in SiO^2 Films through Annealing Process using x-ray Photoelectron Spectroscopy and Infrared Techniques" Appl. Phys. Left.72. 725-727 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] K. Furukawa: "Effects of Oxygen Content on Properties of Silicon Oxide Films Prepared at Room Temperature by Sputtering-type Electron Cyclotron Resonance Plasma" J. Appl. Phys.84. 4579-4584 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 中島 寛: "スパッタ堆積による高品質位Si系絶縁膜の形成" インテリジェント材料. 8. 16-20 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Y. C. Liu: "Compositional and Structural Studies of Amorphous Silicon-Nitrogen Alloys Deposited at Room Temperature using a Sputtering-type ECR Microwave Plasma Plasma" Philosophical Magazine B. 79. 137-148 (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] H.Nakashima,K.Furukawa 他6名: "Low-temperature deposition of high-quality silicon dioxide films by sputtering-type electron cyclotron resonance plasma" J.Vac.Sci.Technol.A. 15. 1951-1954 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] K.Furukawa,H.Nakashima 他4名: "In situ FT-IR reflective absorption spectroscopy for characterization of SiO2 thin films from deposited using sputtering-type electron cyclotron resonance microwave plasma" Appl.Surf.Sci.121/122. 228-232 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] K.Furukawa,H.Nakashima 他4名: "In-situ infrared relective absorption spectroscopy characterization of SiN films deposited using sputtering-type ECR microwave plasma plasma" Appl.Surf.Sci.121/122. 233-236 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] H.Nakashima,K.Furukawa 他6名: "Effect of preoxidation on deposition of thin-gate quality silicon oxide film at low by using a sputter-type electron cyclotron resonance plasma" J.Appl.Phys.82. 5680-5685 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] H.Nakashima,K.Furukawa 他5名: "Deposition of high-quality silicon oxynitride film at low temperature by using a sputtering-type electron cyclotron resonance plasma" Jpn.J.Appl.Phys.36. L1692-L1694 (1997)

    • Related Report
      1997 Annual Research Report

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Published: 1997-04-01   Modified: 2016-04-21  

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