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Study of the structures on glass surface with aid of luminescence measurement

Research Project

Project/Area Number 09650730
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic materials/Physical properties
Research InstitutionFUKUI UNIVERSITY

Principal Investigator

KUZUU Nobu  FUKUI UNIVERSITY,ASSOCIATE PROFESSOR, 工学部, 助教授 (70283158)

Co-Investigator(Kenkyū-buntansha) TANAKA Mitsuya  FUKUI UNIVERSITY ASSISTANT, 工学部, 助手 (40227179)
IWATA Kazuyoshi  FUKUI UNIVERSITY,PROFESSOR, 工学部, 教授 (00020230)
Project Period (FY) 1997 – 1998
Project Status Completed (Fiscal Year 1998)
Budget Amount *help
¥3,400,000 (Direct Cost: ¥3,400,000)
Fiscal Year 1998: ¥600,000 (Direct Cost: ¥600,000)
Fiscal Year 1997: ¥2,800,000 (Direct Cost: ¥2,800,000)
KeywordsSilica Glass / Lumisescence / Laser induced damage / Excimer laser / Surface structure / Defect structure / 破壊機構 / 表面機構 / 照射誘起欠陥 / 分子動力学法
Research Abstract

In the term of this project, we obtained the following results :
1. Effect of annealing on a silica glass block with ground surface : By annealing at 1150゚C, creation of absorption bands due to defect structures and decrement of OH content were observed near surface. The nature of defects and the amount of the change of OH content strongly depend on the roughness and curvature of the surface.
Excimer-laser-induced emission on ground surface of fused silica : By irradiation with ArF excimer laser, luminescence spectra with peaks at 1.9, 3.2 and around 2.9--2.7 eV were observed. The intensities of the peaks at 1.9 and 3.2 eV were suppressed by Ar+ ion etching.
2. Laser induced damage threshold (LIDT) of fused silica at 1064, 532, 355, and 266 nm :
LIDT at 1064--355 nm were proportional to 0.43-th power of the wavelength. At 266 nm, LIDT was about half. of the extrapolated value by the above relation. This low LIDI is due to two-photon absorption which only occurs at 266 nm.
3. Optical fused silica for vacuum UV : We found that ArF-excimer-laser induced absorption in a soot-remelted silica containing 40 ppm OH and no Cl have relatively high resistance to the excimer lasers and excellent optical transmission in vacuum UV.
4. Molecular dynamics simulations for vitreous silica : A molecular dynamics simulation program considering the covalent bonds was developed.
Based on the above results, we will study the defect structure and mechanism for the fracture on silica glass surface by studying the effect of etching and hear treatments on the excimer-laser-induced luminescence.

Report

(3 results)
  • 1998 Annual Research Report   Final Research Report Summary
  • 1997 Annual Research Report
  • Research Products

    (16 results)

All Other

All Publications (16 results)

  • [Publications] 葛生 伸: "Structural change in near-surface of silica glass block by heat treatment" 日本セラミックス協会学術論文誌. 106. 525-527 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] 吉田 國雄: "Wavelength dependence of laser-induced damage in fused silica and fused quartz" Proceedings of SPIE. 3244. 164-175 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] 葛生 伸: "Properties of silica glass : Effect of terminal structure and granular structures" Japanese Journal of Applied Physics,. Suppl.37-1. 28-31 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] 吉田 國雄: "Laser-Induced Bulk Damage of Various types of Silica Glasses with Fundamental and Higher Harmonics of Nd : YAG Laser" Japanese Journal of Applied Physics. 37. 1882-1883 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] 葛生 伸: "Laser-induced bulk damage in various types of vitreous silica at 1064,532,355 and 266 nm : Evidence of different damage mechanisms between at 266 nm and at longer wavelengths" Applied Optics. 印刷中. (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] N.Kuzuu, J.W.Foley, and N.Kamisugi: "Structural Change in Near-Surface of Silica Glass Block by Heat Treatment" J.Ceram.Soc.Jpn.VOL.106. 525-527 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] K.Yoshida, N.Umemura, N.Kuzuu, H.Yoshida, T.Kamimura, and T.Sasaki: "Wavelength dependence of laser-induced damage in fused silica and fused quartz" Proc.SPIE. vol.3244. 525-527 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] N.Kuzuu: "Properties of silica glass : Effect of terminal structure and granular structres" Jpn.J.Appl.Phys.Suppl.vol.37-1. 28-31 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Y.Yoshida, H.Yoshida, T.Kamimuta, and N.Kuzuu: "Laser-Induced Bulk Damage of Various types of Silica Glasses with Fundamental and Higher Harmonics of Nd : YAG Laser" Jpn.J.Appl.Phys. vol.37. 1882-1883 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] N.Kuzuu, K.Yoshida, H.Yoshida, T.Kamimura, and N.Kamusugi: "Laser-induced bulk damage in various types of vitreous silica at 1064,532,355 and 266nm : Evidence of different damage mechanisms between at 266 nm and at longer wavelengths" Appl.Opt. (in press). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] 葛生 伸: "Structural change in near-surface of silica glass block by heat treatment" 日本セラミックス協会学術論文誌. 106. 525-527 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 吉田 國雄: "Wavelength dependence of laser-induced damage in fused silica and fused quartz" 日本セラミックス協会学術論文誌. 106. 525-527 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 葛生 伸: "Properties of silica glass: Effect of terminal structure and granular structures" Japanese Journal of Applied Physics,. Suppl.37-1. 28-31 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 吉田 國雄: "Laser-Induced Bulk Damage of Various types of Silica Glasses with Fundamental and Higher Harmonics of Nd: YAG Laser" Japanese Journal of Applied Physics. 37. 1882-1883 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 葛生 伸: "Laser-induced bulk damage in various types of vitreous silica at 1064, 532, 355 and 266 nm: Evidence of different damage mechanisms between at 266 nm and at longer wavelengths" Applied Optics. (印刷中). (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] 葛生 伸: "Structural Change in the Near-Surface of a Silica Glass Block Heat Treatment" 日本セラミックス協会学術論文誌. 106・5.

    • Related Report
      1997 Annual Research Report

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Published: 1997-04-01   Modified: 2016-04-21  

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