| Project/Area Number |
09650758
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Structural/Functional materials
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| Research Institution | Nagoya University |
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Principal Investigator |
MATSUO Susumu Nagoya Univ., School of Science and Informatics, Professor, 情報文化学部, 教授 (10023293)
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| Co-Investigator(Kenkyū-buntansha) |
NAKAO Hiroshi Nagoya Univ., School of Science and Informatics, Assistant Profrssor, 情報文化学部, 助教授 (40198164)
ISHIMASA Tsutomu Nagoya Univ., School of Engineering, Assistant Professor, 工学部, 助教授 (10135270)
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| Project Period (FY) |
1997 – 1998
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| Project Status |
Completed (Fiscal Year 1998)
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| Budget Amount *help |
¥3,300,000 (Direct Cost: ¥3,300,000)
Fiscal Year 1998: ¥700,000 (Direct Cost: ¥700,000)
Fiscal Year 1997: ¥2,600,000 (Direct Cost: ¥2,600,000)
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| Keywords | quasicrystal / icosahedral phase / phason / strain / strain relaxation / magnetic susceptibility |
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| Research Abstract |
The dependence of the magnetic susceptibility on time was investigated in F-type Al-Pd-Mn icosahedral alloys after the change in the temperature. The susceptibility varied as a square root of time, which is characteristic of the relaxation of the phason in the theory of the strain response of the quasicrystal. Such a change in the susceptibility was considered to originate from the critical conditions for the formation of local magnetic moments in the Al-Pd-Mn icosahedral alloys, which resulted in the fact that only a small fraction of the whole Mn atoms had magnetic moment. These facts leaded to the investigations of the atomic positions in the Al-Pd-Mn icosahedral phases and related crystal approximants. Atomic clusters and the positions of Mn atoms were determined in the investigations, and a new structure related to the phason strains was found. The study of the time-dependence of the macroscopic strain is under way on applying stress.
Simulation calculations were performed for the magnetic structures in a model of atomic positions of Ho in F-type Zn-Mg-Ho icosahedral phase at low temperatures on the assumption that the Ho atoms were interacting via RKKY-like alternating interactions. A long-range antiferromagnetic order was found in the case of the antiferromagnetic interaction for the shortest Ho-Ho distance and the ferromagnetic one for the second shortest Ho-Ho distance. Only a short-range antiferromagnetic order was found in the case of the reversed sign interactions. These facts strongly suggest that the phason strains affect the magnetism of the icosahedral phases drastically.
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