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Application of pervaporation separation to the production of high-octane fuel additives

Research Project

Project/Area Number 09650846
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field 反応・分離工学
Research InstitutionYamaguchi University

Principal Investigator

KITA Hidetoshi  Yamaguchi University, Faculty of Engineering, Associate Professor, 工学部, 助教授 (10177826)

Co-Investigator(Kenkyū-buntansha) TANAKA Kazuhiro  Yamaguchi University, Faculty of Engineering, Associate Professor, 工学部, 助教授 (30188289)
OKAMOTO Kenichi  Yamaguchi University, Faculty of Engineering, Professor, 工学部, 教授 (20029218)
Project Period (FY) 1997 – 1998
Project Status Completed (Fiscal Year 1998)
Budget Amount *help
¥3,400,000 (Direct Cost: ¥3,400,000)
Fiscal Year 1998: ¥1,300,000 (Direct Cost: ¥1,300,000)
Fiscal Year 1997: ¥2,100,000 (Direct Cost: ¥2,100,000)
KeywordsMembrane Separation. / Zeolite Membrane. / Pervaporation. / Methyl-t-butyl ether. / Ethyl-t-butyl ether. / high-octane fuel additive
Research Abstract

The properties of polyimide membranes and zeolitic membranes prepared on the surface of porous tubular support using the hdrothermal synthesis were evaluated by the pervaporation of methyl tert-butyl ether and methanol mixtures. The experimental results showed NaY zeolite membrane preferentially permeated alcohol in pervaporation and vapor permeation of alcohol/ether or alcohol/benzene mixtures. The high selectivity of the NaY zeolite membrane can be attributed to the selective sorption of alcohol into the membrane. The performance of the NaY zeolite membrane is far superior than any other membrane previously reported. Pervaporation through NaY zeolite membrane provides an alternative to the conventional industrial purification of MTBE and ETBE.The NaY membrane was also characterized by X- ray diffraction and scanning electron microscopy.

Report

(3 results)
  • 1998 Annual Research Report   Final Research Report Summary
  • 1997 Annual Research Report
  • Research Products

    (18 results)

All Other

All Publications (18 results)

  • [Publications] 喜多, 英敏: "NaY Zeolite Membrane for the Pervaporation Separation Methanol-Methyl tert-Butyl Ether Mixture" J.Chem.Soc.Chem.Commun.45-46 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] 喜多, 英敏: "無機膜によるパーバーパレーション分離" 膜. 23・2. 62-69 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] 喜多, 英敏: "マイクロ波加熱によるゼオライト膜の作成" ケミカルエンジニヤリング. 43・8. 604-609 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] 喜多, 英敏: "Preparation of X and Y-type zeolite membranes and pervaporation properties" Am.Chem.Soc.Symp.Ser.(印刷中). (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] 喜多, 英敏: "マイクロ波加熱によるゼオライト膜の作成" 化学工学シンポジウムシリーズ. (印刷中). (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] 喜多, 英敏: "無機膜によるパーベーパレーション分離" ケミカルエンジニヤリング. 44(印刷中). (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] H.Kita, T.Inoue, H.Asamura, K.Tanaka, K.Okamoto: "NaY zeolite membrane for the pervaporation separation of methanol-methyl tert-butyl ether Mixtures" J.Chem.Soc.Chem.Commun.45-46 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] H.Kita: "Pervaporation through inorganic membranes" Maku (Membrane). 23. 62-69 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] H.Kita: "Preparation of zeolite membranes by microwave heating" Chemical Engineering. 43. 604-609 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] H.Kita, H.Asamura, K.Tanaka, K.Okamoto: "Preparation of X and Y-type zeolite membranes and pervaporation properties" Am.Chem.Soc.Symp.Ser. (in press). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] H.Kita, T.Harada, K.Okamoto: "Preparation of zeolite membranes by microwave heating" Symp.Ser.Chem.Eng.Jpn.(in press). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] H.Kita: "Pervaporation through inorganic membranes" Chemical Engineering. (in press). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] 喜多,英敏: "Preparation of X and Y-type Zeolite Membranes and Pervaporation Properties" Am.Chem.Soc.Symposium Series. (印刷中). (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] 喜多,英敏: "無機膜によるパーベーパレーション分離" ケミカルエンジニヤリング. 44巻(印刷中). (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] 喜多,英敏: "マイクロ波加熱により作成したゼオライト膜の透過物性" 化学工学シンポジウムシリーズ. (印刷中). (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] 喜多,英敏: "NaY zeolite membrane for the pervaporation separation of methanol-methyl-tert-butyl ether mixtures" J.Chem.Soc.,Chem.Commun.45-46 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 喜多,英敏: "Preparation of X and Y-type zeolitemembranes and Pervaporation Properties" Proc.Am.Chem.Soc.,PMSE. 77巻. 327 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 喜多,英敏: "無機膜によるパ-ベ-パレーション分離" 膜. 23巻(印刷中). (1998)

    • Related Report
      1997 Annual Research Report

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Published: 1997-04-01   Modified: 2016-04-21  

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