Development of Flow-cell System with a Column Electrode for Various Analytical Uses
| Project/Area Number |
09650896
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
工業分析化学
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| Research Institution | Tokyo University of Pharmacy and Life Science |
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Principal Investigator |
KUSU Fumiyo Tokyo University of Pharmacy and Life Science School of Pharmacy, Professor, 薬学部, 教授 (70057371)
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| Co-Investigator(Kenkyū-buntansha) |
ARAI Kensuke Tokyo University of Pharmacy and Life Science School of Pharmacy, Assistant Prof, 薬学部, 講師 (10266885)
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| Project Period (FY) |
1997 – 1998
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| Project Status |
Completed (Fiscal Year 1998)
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| Budget Amount *help |
¥3,000,000 (Direct Cost: ¥3,000,000)
Fiscal Year 1998: ¥500,000 (Direct Cost: ¥500,000)
Fiscal Year 1997: ¥2,500,000 (Direct Cost: ¥2,500,000)
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| Keywords | electrolysis equipment / electroanalysis / electrode reaction / electrolytic cell / flow coulometry / organic electrochemistry / フローク-ロメトリー |
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| Research Abstract |
Flow electrolysis system with a column electrode was developed for various analytical use. It has become apparent that the system with simple operation is useful for high-efficient electrolysis of inorganic and organic compounds, analysis of electrode reactions of organic compounds, and highly sensitive determination of substances. The results obtained are summarized as follows :
1. Assembly of flow electrolysis cell with a column electrode
Carbon fiber was served as the working electrode packed in a column of Vycol glass cylinder in the electrolysis cell for flow coulometry.
2. Construction of the system
The system consists of a pump, sample injector, electrolysis cell with a column electrode, potentiostat, recorder, and multi-wavelength spectrophotometer. System efficiency was assessed by electrolysis of potassium hexacyanoferrate(III).
3. Electrolysis of organic compounds
Electrolysis of nitrobenzene, 2-methyl-1, 4-naphthoquinone, nifedipine and epinephrine was made using the system.
4. Identification of electrolysis products
Electrolysis products of alpha-tocophelol and 3,5-di-tert-butyl-1,2-benzoquinone were identified.
5. Electrosynthesis of reagents of short lifetime
Chemiluminescent reagent was prepared using a small scall flow electrolysis cell, which was applied to high-sensitive determination of a isoluminol derivative.
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Report
(3 results)
Research Products
(12 results)
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[Publications] K,Arai, T.Sato, H.Tamanouchi, M.Ohtomo, K.Takamura, T.Sueoka, F.Kusu: "Electrolysis of 2-methyl-1,4-naphthoquinone and 3,5-di-tert-butyl-1,2-benzoquinone using the Flow-cell System with a Column Electrode" Electrochim.Acta. (in press).
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