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Methods to visualize solid-state redox reaction of lead-tin silicate glass and their use to explore new materials for advanced lithium batteries

Research Project

Project/Area Number 09650910
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field 工業物理化学
Research InstitutionOSAKA CITY UNIVERSITY

Principal Investigator

OHZUKU Tsutomu  Department of Engineering, Osaka City University, Professor, 工学部, 教授 (40116439)

Co-Investigator(Kenkyū-buntansha) SAWAI Keijiro  Department of Engineering, Osaka City University, Associate Professor, 工学部, 助教授 (50206017)
Project Period (FY) 1997 – 1998
Project Status Completed (Fiscal Year 1998)
Budget Amount *help
¥3,100,000 (Direct Cost: ¥3,100,000)
Fiscal Year 1998: ¥800,000 (Direct Cost: ¥800,000)
Fiscal Year 1997: ¥2,300,000 (Direct Cost: ¥2,300,000)
Keywordselectrochemistry / silicate glass / dilatometry / acoustic emission / lithium battery / insertion material / solid-state redox reaction
Research Abstract

Research directed toward the better understanding of anomalous behavior on solid-state redox reactions of lead-tin silicate glass was carried out in the fiscal year of 1997-1998. Since X-ray diffraction was featureless, new methods to visualize and follow the phenomena took place in a solid matrix were necessary. Therefore, we have intensively developed the following new methods :
(1) optical microscopy using optical microscope with CCD camera to see what are going on in a micrometer scale,
(2) acoustic emission histometry using in-situ electrochemical cells with acoustic sensor and transducer, which is designed and fabricated in our laboratory, to detect cracking sounds of lead-tin silicate glass particles, and
(3) dilatometry using home-made dilatometer with in-situ electrochemical cells which was designed to detect dimensional changes in 0.1 micrometer accuracy.
These new methods worked very well to visualize and characterize the anomalous behaviors of lead-tin silicate (or borate) glass. The methods were also applied to lithium insertion materials consisting of lithium, transition metal, and oxygen ions, and the results were compared with those from lead-tin silicate glass. According to our results, lead-tin silicate glass or borate glass can be applied to a negative electrode material for lithium ion batteries although some improvement would be needed to erase cracking sound by acoustic emission histometry.
As were stated above, we have successfully visualized phenomena which have not detect so far and gave useful information to materials chemists for advanced lithium batteries.

Report

(3 results)
  • 1998 Annual Research Report   Final Research Report Summary
  • 1997 Annual Research Report
  • Research Products

    (22 results)

All Other

All Publications (22 results)

  • [Publications] T.Ohzuka and A.Ueda: "Phenomiuological Expression of Solid-state Redox potentiats of LiCuO_2,LiCoy_2NiyO_2,and LiNiO_2,Insertion Electrodes" J.Electrochem.Socy. 144・8. 2780-2785 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] T.Ohzuka,H.Tomura,and K.Sawai: "Monitoring of particle Fraotare by Acoustic Emission during charge and Discharge of Li/MnO_2 cells" J.Electrochem.Socy. 144・10. 3496-3500 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] T.Ohzuka,T.Yanagawa,M.Kouguchi,and A.Ueda: "An Innovative Insertion Material of LiAl1/4Ni3/4 O_2(R3m)for Lithium Ion(Shuttlecock) Batteries" J.Power Sources. 68. 131-134 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] T.Ohzuka,S.Kitano,M.Iwanaga,H.Matsuno,A.Ueda: "Comparative study of Li[LixMn2-x] O_4 and LT-LiMnO_2 for Lithium-Ion Batteries" J.Power Sources. 68. 646-651 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] K.Sawai,H.Tomura,and T.Ohzuka: "Acoustsc Emission Histometry for Battery Matersal Research" Denki Kagaku. 66・3. 301-307 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] T.Ohzuka and K.Nakaura: "Solid State Electrochemistry of Intercalation Compound of LiAl1/2Niy_2O_2(R3m)for Lithium-Ion Batteries" Denki Kagaku. 66・12. 1209-1214 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] K.Sawai and T.Ohzuku: "A Method of Impedance Spectroscopy for Predicting the Dynamic Behavior of Electrochemical System and its Application to a High-Area Carbon Electrode" J.Electrochem.Soc.Vol.144, No.3. 988-995 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] T.Ohzuku and A.Ueda: "Phenominological Expression of Solid-State Redox Potentials of LiCoO_2, LiCo_<1/2>Ni_<1/2>O_2, and LiNiO_2 Insertion Electrodes" J.Electrochem.Soc.Vol.144, No.8. 2780-2785 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] T.Ohzuku, H.Tomura, and K.Sawai: "Monitoring of Particle Fracture by Acoustic Emission during Charge and Discharge of Li / MnO_2 Cells" J.Electrochem.Soc.Vol.144, No.10. 3496-3500 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] T.Ohzuku, T.Yanagawa, M.Kouguchi, and A.Ueda: "An Innovative Insertion Material of LiAl_<1/4>Ni_<3/4>O_2(R3m) for Lithium Ion (Shuttlecock) Batteries" J.Power Sources. Vol.68. 131-134 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] T.Ohzuku, S.Kitano, M.Iwanaga, H.Matsuno, and A.Ueda: "Comparative Study of Li[Li_xMn_<2-x>]O_4 and LT-LiMnO_2 for Lithium-Ion Batteries" J.Power Sources. Vol.68. 646-651 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] K.Sawai, H.Tomura, and T.Ohzuku: "Acoustic Emission Histometry for Battery Material Research" Denki Kagaku (presently Electrochemistry). Vol.66, No.3. 301-307 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] T.Ohzuku and K.Nakura: "Solid State Electrochemistry of Intercalation Compound of LiAl_<1/2>Ni_<1/2>O_2(R3m) for Lithium-Ion Batteries" Denki Kagaku (presently Electrochemistry). Vol.66, No.12. 1209-1214 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] K.Sawai and T.Ohzuku: "projection of Charge and Discharge Curves at Constant Current by Impedance Spectroscopy" Electrochemistry. Vol.67, No.1. 34-38 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] T.Ohzuku and A.Ueda: "Phenominological Expression of Solid-State Redox Potentials of LiCoO_2,LiCoV_3Ni_<1/2>O_2,and LiNiO_2 Insertion Electrodes" J.Electrochem.Soc.,. 144・8. 2780-2785 (1997)

    • Related Report
      1998 Annual Research Report
  • [Publications] T.Ohzuku,H.Tomura,and K.Sawai: "Monitoring of Particle Fracture by Acoustic Emission during charge and Discharge of Li/MnO_2 cells" J.Electrochem.Soc.,. 144・10. 3496-3500 (1997)

    • Related Report
      1998 Annual Research Report
  • [Publications] T.Ohzuku,T.Yanagawa,M.Kouguchi,and A.Ueda: "An Innovative Insertion Material of LiAl_<1/4>Ni_<3/4>O_2(R3m^^-)for Lithium Ion(Shuttlecock)Batteries" J.Power Sources. 68. 131-134 (1997)

    • Related Report
      1998 Annual Research Report
  • [Publications] T.Ohzuku,S.Kitano,M.Iwanaga H.Matsuno,and A.Ueda: "Comparative Study of Li[Lix Mn_<2-x>]O_4 and LT-LiMnO_2 for Lithium-Ion Batteries" J.Power Sources. 68. 646-651 (1997)

    • Related Report
      1998 Annual Research Report
  • [Publications] K.Sawai,H.Tomura,and T.Ohzuku: "Acoustic Emission Histometry for Battery Material Research" Denki Kagaku. 66・3. 301-307 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] T.Ohzuku and K.Nakura: "Solid State Electrochemistry of Intercalation Compound of LiAl_<1/2>Ni_<1/2>O_2(R3m)for Lithium-Ion Batteries" Denki Kagaku. 66・12. 1209-1214 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] T.Ohzuku,H.Tomura and K.Sawai: "Monitoring of Particle Fracture by Acoustic Emission during charge and Discharge of LT/MnO_2 Cells" J.Electrochem.Soc.,. 144・10. 3496-3500 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] K.Sawai,H.Tomura and T.Ohzuku: "Acoustic Emission Histometry for Battery Material Research" Denki Kagaku. 66・3. 301-307 (1998)

    • Related Report
      1997 Annual Research Report

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Published: 1997-04-01   Modified: 2016-04-21  

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