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Synthesis of Novel Polyamides Having Helical Structures and Their Phototransformation

Research Project

Project/Area Number 09650970
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field 高分子合成
Research InstitutionYAMAGATA UNIVERSITY

Principal Investigator

TAKEISHI Makoto  Polymer Science & Engineering, Yamagata University, Professor, 工学部, 教授 (20007214)

Project Period (FY) 1997 – 1999
Project Status Completed (Fiscal Year 1999)
Budget Amount *help
¥3,000,000 (Direct Cost: ¥3,000,000)
Fiscal Year 1999: ¥500,000 (Direct Cost: ¥500,000)
Fiscal Year 1998: ¥900,000 (Direct Cost: ¥900,000)
Fiscal Year 1997: ¥1,600,000 (Direct Cost: ¥1,600,000)
KeywordsPolyamide / Helix / Phototransformation / Nonlinear optical material / ポリエステル / ポリケトン / らせん高分子 / 光学活性
Research Abstract

Aromatic polyamides having new helical structures were synthesized by combination of optically active dissymmetric joints, such as biphenylene and binaphthlene, with aromatic hard segments, such as phenylene and 4,4'-azophenylene. CD spectra of the polymers obtained that the helical structures are stable up to 120℃ in a polar solvent, and the structures were maintained in strong acids such as methanesulfonic asid. A polyamide that contains azobezene moieties in the main chain was transformed on irradiation of UV light because of trans-cis photoisomerization of the photosensitive moieties. This polymer can be use as a nonlinear optical material. The preparative method was applied to preparation of similar polyesters, polyurethanes, and polyamines.

Report

(4 results)
  • 1999 Annual Research Report   Final Research Report Summary
  • 1998 Annual Research Report
  • 1997 Annual Research Report
  • Research Products

    (24 results)

All Other

All Publications (24 results)

  • [Publications] 武石誠.近藤史尚.木村宏: "らせん高分子"高分子加工. 46. 146-151 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 近藤史尚.岩泉卓.木村宏.武石誠: "ホルマール化酒石酸と芳香族ジアミンを用いたらせんポリアミドの合成"高分子論文集. 54. 908-913 (1997)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] F.Kondo,S.kakimi,H.Kimura,and M.Takeishi: "Synthesis and Photoinduced Transformation of Helical Aromatic Polyamides consisting of Axially Dissymmetric Biphenylene Joints and Azobenzene Segments in the Backbone"Polymer International. 46. 339-344 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Fumitaka KONDO,Daishin TAKAHASHI,Hiroshi KIMURA,and Makoto TAKEISHI: "Synthesis and Photoinduced Transformation of Helical Aromatic Polyamides Having Optically Active Binaphthol Units in the Main Chain"Polymer Journal. 30. 161-162 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 武石誠.阿形裕也.木村宏: "新しいらせん高分子"日本ゴム協会誌. 72. 263-269 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] H.Kimura,D.Takahashi,T.Ymamaguchi,M.Takeishi: "Synthesis of Optically Active Polyarylates Having Axially Chiral Binaphthylene Unit"繊維学会誌. 56. 169-174 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M.Takeishi, F.Kondo, H.Kimura: "Herical Polytmers."Polymer Applications. 46. 146-151 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] F.Kondo, T.Iwaizumi, H.Kimura, M.Takeishi: "Synthesis of Herical Polyamides from a Tartaric Acid Derivatives and Aromatic Diamines."Kobunshi Ronbunshu. 54. 908-9113 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] F.Kondo, S.Kkimi, H.Kimura, M.Takeishi: "Synthesis and Photoinduced Transformation of a Helical Aromatic Polyamides Consisting of Axially Dissymmetric Biphenylene Joints and Azobenzene Segments in the Backbone."Polym. Iinternat.. 46. 339-344 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] F.Kondo, D.Takahashi, H.Kimura, M.Takeishi: "Synthesis and Photoinduced Transformation of a helical Aromatic Polyamide Having Optically Active Binaphthol Units in the Main Chain."Polm. J. 30. 161-162 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M.Takeishi, Y.Agata, H.Kimura: "New Helical Polymers."Nippon Gomu Kyokaishi. 72. 2263-269 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] H.Kimura, D.Takahashi, T.Yamaguchi, M.Takeishi: "Synthesis of Optically Active Polyesters Having Axially Chiral Binaphthalene Units"Sen-I Gakkaishi. 56. 1169-174 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] H.Kimura,T.Yoshimari,M.Takeishi: "Synthesis and Biodegradation of polyesters Based on O-Methylene Tartaric Acid."Polymre Journal. 31(4). 388-392 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] H.Kimura,S.Sasaki,M.Takeishi: "Biosynthesis of Poly(3-hydroxyalkanoate)s with Terminal Alkane Groups in the Side Chains."Chemistry Letters. 1999. 1189-1190 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] H.Kimura,T.Takahashi,M.Takeishi: "Effective Biosynthesis of Poly(3-hydroxybutyrate) from Plant Oils by Chromobacterium SP."Polymer Journal. 31(2). 210-212 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] H.Suzuki,M.Takeishi,I.Narisawa: "Synthesis of Polysiloxane-Grafted Fluoropolymers and Their Hydrophobic Poroperties."Journal of Applied Polymer Science. 42. in press (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] H.Suzuki,T.Kabayashi,M.Takeishi: "Synthesis of Polydime thylsiloxane-Grafted Fluoropolymers and Poroperties for Hydrophobic Materials."Polymre Journal. 32. in press (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] H.Kimura,D.Takahashi,M.Takeishi: "Synthesis of Oppticaly Active Polyarylates Having Axiably Chiral Binaphttylene Llnit."Seni Gakkaishi. 56(3). 701-706 (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] Rikiya Sato, Kenichi Nakahashi, Hiroshi Iwadate,Makoto Takeishi: "Synthesis of a New Nitrone for Detection of Radical Species" Chemistry Letters. 1998. 7-8 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] F.Kondo,D.Takahashi, H.Kimura,and M.Takeishi: "Synthesis and Photoinduced Transformation of a New Helix Aromatic Polyamide" Polymer Journal. Vol.30,No.2,. 161-162 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] F.Kondo,S.Kakimi, H.Kimura,and M.Takeishi: "Synthesis and Photoinduced Transformation of Helical Aromatic Polyamides consisting of Axially Dissymmetric Biphenylene Joints and Azobenzene Segments in the Backbone" Polymer International. Vol.46. 339-344 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 近藤史尚, 岩泉卓, 木村宏, 武石誠: "ホルマ-ル化酒石酸と芳香族ジアミンを用いたらせんポリアミドの合成" 高分子論文集. Vol.54,No.12,. 908-913 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] F.Kondo, D.Takahashi, H.Kimura, and M.Takeishi: "Synthesis and Photoinduced Transformation of a New Helix Aromatic Polyamide" Polymer Journal. Vol.30,No.2,. 161-162 (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] F.Kondo, S.Kakimi, H.Kimura, and M.Takeishi: "Synthesis and Photoinduced Transformation of Helical Aromatic Polyamides consisting of Axially Dissymmetric Biphenylene Joints and Azobenzene Segments in the Backbone" Polymer International. (in press). (1998)

    • Related Report
      1997 Annual Research Report

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Published: 1997-04-01   Modified: 2016-04-21  

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