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Preparation of Resposive Poymer Surfaces to Environmental Changes

Research Project

Project/Area Number 09650993
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field 高分子構造・物性(含繊維)
Research InstitutionShizuoka University

Principal Investigator

INAGAKI Norihiro  Shizuoka Univ., Fac.of Eng., Professor, 工学部, 教授 (30022015)

Co-Investigator(Kenkyū-buntansha) TASAKA Shigeru  Shizuoka Univ., Fac.of Eng., Asso.Prof., 工学部, 助教授 (10134793)
Project Period (FY) 1997 – 1998
Project Status Completed (Fiscal Year 1998)
Budget Amount *help
¥3,300,000 (Direct Cost: ¥3,300,000)
Fiscal Year 1998: ¥700,000 (Direct Cost: ¥700,000)
Fiscal Year 1997: ¥2,600,000 (Direct Cost: ¥2,600,000)
Keywordspolymer surface / graft copolymerization / poly (tetrafluoroethylene) / hydrophilic / XPS / sodium vinylsulfonate / glycidyl methacrylate / poly (p-phenylene terephthalamide) / ホリマー表面 / ポリテトラフルオロエチレン / テフロン / ビニルスルフォン酸
Research Abstract

Poly(tetrafluoroethylene) (PTFE) and poly(p-phenylene terephthalamide) (PPTA) were modified by graft copolymerization using sodium vinylsulfonate (SVS) and glycidyl methacrylate (GMA) as monomers to form responsive surface to environmental changes. Peroxides were formed on PTFE and PPTA surfaces by argon plasma exposure, and the graft copolymerization of SVS or GMA was carried out from the peroxides on the PTFE and PPTA surfaces. The chemical composition of the grafted PTFE and PPTA surfaces was analyzed with XPS.The coverage with the SVS graft polymers on the PTFE surface was estimated to be 43 % from the XPS spectra, and the coverage with the GMA graft polymers on the PPTA surface was 31 - 49 %. The grafted PTFE surface was somewhat hydrophilic, but the hydrophilicity was lower than the plasma-treated PTFE.The contact angle of water against the grafted PTFE decreased from 111 degrees to 84 degrees. The low hydrophilicity of the grafted PTFE surface may be due to incomplete coverage with the SVS graft polymers. The graft copolymerization with GMA improved adhesion between PPTA and epoxy adhesive. The 90 peel strength was increased 2.7 times by the graft polymerization. The failure from the PPTA/epoxy adhesive joints occurred in the epoxy adhesive layer rather than at the interface between the PPTA and the epoxy adhesive layer.

Report

(3 results)
  • 1998 Annual Research Report   Final Research Report Summary
  • 1997 Annual Research Report
  • Research Products

    (22 results)

All Other

All Publications (22 results)

  • [Publications] N.Inagaki, S.Tasaka, and Y.W.Park: "Effects of the surface modification by remote hydrogen plasma on adhesion in the electroless copper/tetrafluoroethylene-hexafluoropropylene copolymer (FFP) system" Journal of Adhesion Science and Technology. 12. 1105-1119 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] N.Inagaki, S.Tasaka, and T.Inoue: "Surface modification of aromatic polyamide film by plasma graft copolymerization of glycidylmethacrylate for epoxy adhesion" Journal of Applied Polymer Science. 69. 1179-1185 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] N.Inagaki, S.Tasaka, T.Horiuchi and R.Suyama: "Surface modification of poly(aryl ether ether ketone)film by remote oxygen plasma" Journal of Applied Polymer Science. 68. 271-279 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] 稲垣訓宏: "リモートプラズマ処理によるポリマーの表面改質" 日本接着学会誌. 34. 73-77 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] N.Inagaki, S.Tasaka, H.Kawai, and Y.Yamada: "Surface modification of aromatic polyamide film by remote oxygen plasma" Journal of Polymer Science. vol.64. 831-840 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] N.Inagaki, S.Tasaka, and M.Makino: "Plasma polymer deposition from mixture of tetra-methoxysilane and oxygen on PET films and their oxygen gas barrier properties" Journal of Applied Polymer Science. vol.64. 1031-1039 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] N.Inagaki: "Surface modification of polymers using plasma and excimer laser" Hyomen Kagaku. vol.18. 543-548 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] N.Inagaki, S.Tasaka, and Y.Goto: "Surface modification of poly (tetrafluoroethylene) film by plasma graft polymerization of sodium vinyl-sulfonate" Journal of Applied Polymer Science. vol.66. 77-84 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] N.Inagaki: "Surface modification of polymers by remote plasma" Journal of Adhesion Society of Japan. vol.34. 73-77 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] N.Inagaki, S.Tasaka, T.Horiuchi, and R.Suyama: "Surface modification of Poly (aryl ether ether ketone) film by remote oxygen plasma" Journal of Applied Polymer Science. vol.68. 271-279 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] N.Inagaki, S.Tasaka, and T.Inoue: "Surface modification of aromatic polyamide film by plasma graftcopolymerization of glycidyl metha-crylate for epoxy adhesion" Journal of Applied Polymer Science. vol.69. 1179-1185 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] N.Inagaki, S.Tasaka, and Y.W.Park: "Effects of the surface modification by remote hydrogen plasma on adhesion in the electroless copper/tetrafluroethylene-hexafluoropropylene copolymer (FEP) system" Journal of Adhesion Science & Technology. vol.12. 1105-1119 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] N.Inagaki, S.Tasaka and Y W Park: "Effects of the surface modification by remote hydrogen plasma on adhesion in the electroless copper/tetrafluoroethylene-hexafluoropropylene copolymer (FEP) system" Journal of Adhesion Science and Technology. 12. 1105-1119 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] N.Inagaki, S.Tasaka,and T.Inoue: "Surface modification of aromatic polyamide film by plasma graft copolymerization of glycidylmethacrylate for epoxy adhesion" Journal of Applied Polymer Science. 69. 1179-1185 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] N.Inagaki,S.Tasaka,T.Horiuchi and R.Suyama: "Surface modification of poly (aryl ether ether ketone) film by remote oxygen plasma" Journal of Applied Polymer Science. 68. 271-279 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 稲垣訓宏: "リモートプラズマ処理によるポリマーの表面改質" 日本接着学会誌. 34. 73-77 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] N.Inagaki, S.Tasaka, H.Kawai, Y.Yamada: "Surface Modification of Aromatic Polyamide Film by Remote Oxygen Plasma" Journal of Applied Polymer Science. 64. 831-840 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] N.Inagaki, S.Tasaka, M.Makino: "Plasma Polymer Deposition from Mixture of Tetramethoxysilane and Oxygen on PET Films and thier Oxgen Barrier Properties" Journal of Applied Polymer Science. 64. 1031-1039 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] N.Inagaki, S.Tasaka, Y.Goto: "Surface Modification of Poly(tetrafluoroethylene)Film by Plasma Graft Polymerization of Sodium Vunylsulfonate" Journal of Applied Polymer Science. 66. 77-84 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] N.Inagaki: "Surface Modification by Plasma Treatment" Jpn.Journal of Tribology. 41. 1215-1224 (1996)

    • Related Report
      1997 Annual Research Report
  • [Publications] 稲垣訓宏: "プラズマ,エキシマレーザーを利用した高分子表面の改質" 表面科学. 18. 543-548 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] 稲垣訓宏: "リモートプラズマ処理によるポリマーの表面改質" 日本接着学会誌. 34. 73-77 (1998)

    • Related Report
      1997 Annual Research Report

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Published: 1997-04-01   Modified: 2016-04-21  

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