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Development of Odor-Sensors Based on Sensory Test

Research Project

Project/Area Number 09838014
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field 感性工学
Research InstitutionSHINSHU UNIVERSITY

Principal Investigator

SHIRAI Hirofusa  Textile Science and Technology, Shinshu University Professor, 繊維学部, 教授 (80021153)

Co-Investigator(Kenkyū-buntansha) HANABUSA Kenji  Textile Science and Technology, Shinshu University Associate Professor, 繊維学部, 助教授 (60126696)
KIMURA Mutsumi  Textile Science and Technology, Shinshu University Associate, 繊維学部, 助手 (60273075)
Project Period (FY) 1997 – 1998
Project Status Completed (Fiscal Year 1998)
Budget Amount *help
¥3,200,000 (Direct Cost: ¥3,200,000)
Fiscal Year 1998: ¥1,400,000 (Direct Cost: ¥1,400,000)
Fiscal Year 1997: ¥1,800,000 (Direct Cost: ¥1,800,000)
KeywordsGas sensor / Odor / Metallophthalocyanine / Perylene / Sensory Test / 硫化水素 / メルカプタン / 生体酸化酵素 / 酸化反応 / 触媒 / 高分子
Research Abstract

The performance of the present gas-sensors is based on the change of electric conductivity which is affected by the adsorption of electron-donor gases such as H_2S and mercaptan on the surface of the electrodeposited perylene film. It was confirmed that the present gas-sensors were detectable to low concentration of H_2S or mercaptan. The sensing properties to H_2S and. mercaptan were also investigated using soluble perylene derivatives. It was confirmed that low concentrations of H2S and mercaptan was detectable by the gas-sensor at room temperature and the current responses to the existence of H_2S and mercaptan were considerably quick These results suggest that adsorption and desorption of H_2S or mercaptan on the surfaces of film is easily achieved at room temperature. On and Co phthalocyanine films on indium/tin oxide (ITO) coated glass electrodes were prepared by cathodical polarization of the electrolytic solution containing CaCl_2 as a supporting electrolyte with a constant current The performance of the present gas-sensors is based on the change of electrical conductivity which is affected by the adsorption of acceptor gases such as NO_2 and SO_2 on the surface of the phthalocyanine film. It was confirmed that the present gas-sensors were detectable to ppm levels of NO_2 or SO_2.

Report

(3 results)
  • 1998 Annual Research Report   Final Research Report Summary
  • 1997 Annual Research Report
  • Research Products

    (24 results)

All Other

All Publications (24 results)

  • [Publications] T.Kudo: "Fabrication of gas sensors based on soluble phthalocyauin" Journal of Porphyrins and Phthalocyanines. 3(1). 5-9 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] T.Kudo: "Gas-sensors based on electrodeposited metallophthalocyanine film" Sensors and Actuators:B. (印刷中).

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] T.Kudo: "Fabrication of gas-sensors based on electro-deposited perylene derivatives" Sensors and Actuators:B. (印刷中).

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] T.Kudo: "Fabrication of gas-sensor based on soluble perylene derivative" Sensors and Actuators:B. 印刷中.

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] M.Kimura: "Fluorescence eheruosensor for Metal ions Using conjugated polymers" Adv.Mater. 459(10). 459-462 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Mutsumi Kimura, Yuji Yamaguchi, Toshiki Koyama, Kenji Hanabusa, Hirofusa Shirai: "Catalytic oxidation of 2-mercaptoethanol by cationic water-soluble phthalocyaninatocobalt (II) complexes" J.Porphyrins and Phthalocyanines. 1. 309-313 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Hirofusa Shirai, Shun-ichi Kondo, Kazumi Nishihata, Etsuko Adachi, Masahiro Suzuki, Shinji Uchida, Mutsumi Kimura, Toshiki Koyama, Kenji Hanabusa: "Functional Metallomacrocycles and Their Polymers 36. Synthsis and Properties of Polyester Containing a Metallophthalocyanine Ring" Journal of Porphyrins and Phthalocyanines. 2. 31-38 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Takashi Ichinohe, Makoto Miyajima, Yasuhisa Noguchi, Masahiro Itoh, Mutsumi Kimura, Toshiki Koyama, Kenji Hanbusa, Akira Hachimori, Hirofusa Shirai: "Bactericidal Activities of Radical Species Generated by Catalytic Reaction of Iron (III) Octacarboxyphthalocyanine" J.Porphyrins and Phthalocyanines. 2 (2). 101-106 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] Mutsumi Kimura, Toshihiro Hirai, Kenji Hanabusa, Hirofusa Shirai: "Fluorescence Chemosensor for Metal Ions Using Conjugated Polymers" Adv.Mater.459 (10). 459-462 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] T.Kudo, M.Kimura, K.Hanabusa, H.Shirai: "Fabrication of p-n junction diodes from phthalocyanine and electropolymerized perylene derivatives" J.Porphyrins and Phthalocyanines. 2 (3). 231-235 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] T.Kudo, M.Kimura, K.Hanabusa, H.Shirai: "Electrical properties of junctions between electrodeposited magnesium phthalocyanine and aluminum" Polymer Journal. 30(3). 177 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] T.Kudo, M.Kimura, K.Hanabusa, H.Shirai, T.Sakaguchi: "Fabrication of gas sensors based on soluble phthalocyanines" Journal of Porphyrins and Phthalocyanines. 3 (1), (in press). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] T.Kubo, M.Kimura, K.Hanabusa, H.Shirai: "Preparation of electro-codeposited film consisting of phthalocyanine and perylene derivatives" Journal of Porphyrins and Phthalocyanines. (in press). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] T.Kudo, M.Kimura, K.Hanabusa, H.Shirai, T.Sakaguchi: "Gas-sensors based on electrodeposited metallophthalocyanine film" Sensors and Actuators B. (in press). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] T.Kudo, M.Kimura, K.Hanabusa, H.Shirai, T.Sakaguchi: "Fabrication of gas-sensors based on electrodeposited perylene derivative" Sensors and Actuators : B. (in press). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] T.Kudo, M.Kimura, K.Hanabusa, H.Shirai, T.Sakaguchi: "Fabrication of gas-sensor based on soluble perylene derivative" Sensors and Actuators : B. (in press). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1998 Final Research Report Summary
  • [Publications] T.Kudo: "Fabrication of gas sensors based on soluble phthalocyanines" Journal of Porphyrins and Phthalocyanines. 3(1). 5-9 (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] T.Kudo: "Gas-sensors based on electrodeposited metallo-phthalocyanine film" Sensors and Actuators : B. 印刷中.

    • Related Report
      1998 Annual Research Report
  • [Publications] T.Kudo: "Fabrication of gas-sensors based on electro-deposited perylene derivatives" Sensors and Actuators : B. 印刷中.

    • Related Report
      1998 Annual Research Report
  • [Publications] T.Kudo: "Fabrication of gas-sensors based on soluble perylene derivative" Sensors and Actuators : B. 印刷中.

    • Related Report
      1998 Annual Research Report
  • [Publications] M.Kimura: "Fluorescence Chemosensor for metal ions Using Conjugated polymers" Adv.Mater. 459(10). 459-462 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] H. Shirai et al.: "Functional Metallomacrocycles and their polymers 36. Synthesis and properties of polyester containing a Metallophthalocyanine ring" Journal of Porphyrins and Phthalocyanines. 2. 31-38 (1998)

    • Related Report
      1997 Annual Research Report
  • [Publications] M.Kimura et al.: "Catalytic oxidation of 2-mercaptoethanol by cationic Water-soluble phthalocyaninatocobalt (II) complexes" Journal of Porphyrins and Phthalocyanines. 1. 309-313 (1997)

    • Related Report
      1997 Annual Research Report
  • [Publications] M.Kimura et al.: "Fluorescence chemosensor for metal ions using conjugated polymers" Advanced Materials. (発表予定).

    • Related Report
      1997 Annual Research Report

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Published: 1997-04-01   Modified: 2016-04-21  

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