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MBE成長した窒化インジウム及び関連混晶の構造及び光学的物性評価に関する研究

Research Project

Project/Area Number 09F09272
Research Category

Grant-in-Aid for JSPS Fellows

Allocation TypeSingle-year Grants
Section外国
Research Field Applied materials science/Crystal engineering
Research InstitutionRitsumeikan University

Principal Investigator

WANG Ke (2011)  立命館大学, 立命館グローバル・イノベーション研究機構, ポストドクトラルフェロー

名西 ヤス之 (2010)  立命館大学, 理工学部, 教授

名西 やす之 (2009)  Ritsumeikan University, 理工学部, 教授

Co-Investigator(Kenkyū-buntansha) WANG Ke  立命館大学, 総合理工学研究機構, 外国人特別研究員
Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥2,500,000 (Direct Cost: ¥2,500,000)
Fiscal Year 2011: ¥400,000 (Direct Cost: ¥400,000)
Fiscal Year 2010: ¥900,000 (Direct Cost: ¥900,000)
Fiscal Year 2009: ¥1,200,000 (Direct Cost: ¥1,200,000)
KeywordsInN / InGaN / RF-MBE / p型ドーピング / サーモパワー / ECV / 選択成長 / MBE / フォトルミネッセンス / その場観察 / RHEED / Mgドーピング
Research Abstract

InNおよび関連混晶材料であるInGaNの光学的・構造学的・電気的特性とその成長メカニズムについては未だ不明な点が多い。最適な成長条件を見出し、電気的・光学的特性の改善を図るためには緻密で基礎的な研究が必要である。
本年度は、RF-MBE法を用いて作製したMgドーピングInGaN結晶の電気的特性評価に関して評価を行った。InリッチInGaN(In組成約90%、80%)、GaリッチInGaN(In組成 約10%、20%)に対して、Mgセル温度を変化させることで、異なるドーピング濃度のMgドーピングInGaN混晶を作製した。GaリッチInGaNについては、ホール効果測定によってMgドーピングによるp型伝導を確認することができたが、InリッチInGaNにおいては、表面電荷蓄積層の影響によるp型伝導を示す結果は得られなかった。しかしながら、サーモパワー測定、ECR測定の結果、InリッチInGaNにおいても、p型伝導を示唆する結果が得られており、最適なMgドーピング濃度にてバルク内部でp型領域が存在していることが示された。
次にInN結晶の高品質化技術として、AINをナノマスクとして用いたIhNの選択成長技術を開発した。サファイア基板上にAINを数秒間成長させた後、IhN低温バッファ層を成長させると、N極性とIn極性のIhNが混在して成長する。その後、580度まで基板温度を上げることで、N極性lnNのみの選択成長が実現された。その過程において、刃状転位転位密度が10^9/cm^2程度に一桁近く低減した。また、X線半値幅、キャリア濃度、移動度、PL発光半値幅などにおいても改善が見られた。本手法は、従来、結晶高品質化が困難であったサファイア基板上N極性InNにおいても、光学的・構造学的・電気的特性を大きく改善する効果が期待できる結晶成長技術となろう。

Report

(3 results)
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (26 results)

All 2012 2011 2010 2009

All Journal Article (6 results) (of which Peer Reviewed: 6 results) Presentation (20 results)

  • [Journal Article] Investigation on InN Mole Fraction Fluctuation in InGaN Films Grown by RF-MBE2011

    • Author(s)
      T.Kimura, E.Fukumoto, T.Yamaguchi, K.Wang, M.Kaneko, T.Araki, E.Yoon, Y.Nanishi
    • Journal Title

      phys.stat.sol.(c)

      Volume: 8 Issue: 5 Pages: 1499-1502

    • DOI

      10.1002/pssc.201001203

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] PN junction rectification in electrolyte gated Mg-doped InN2011

    • Author(s)
      E.Alarcon-Llado, M.A.Mayer, B.W.Boudouris, R.A.Segalman, N.Miller, T.Yamaguchi, K.Wang, Y.Nanishi, E.E.Haller, J.W.Ager
    • Journal Title

      Appl.Phys.Lett.

      Volume: 99 Issue: 10

    • DOI

      10.1063/1.3634049

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mg doped InN and confirmation of free holes in InN2011

    • Author(s)
      K.Wang, N.Miller, R.Iwamoto, T.Yamaguchi, M.Mayer, T.Araki, Y.Nanishi. J.W Ager III, K.M.Yu, W.Walukiewicz
    • Journal Title

      Appl.Phys.Lett.

      Volume: 98

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Roles of indium adlayer and droplets in In-polar InN growth by molecu larbearn epitaxy2011

    • Author(s)
      Ke Wang, Tomohiro Yamaguchi, Tsutomu Araki1, Euijoon Yoon, Yasushi Nanishi
    • Journal Title

      Jpn.J.Appl.Phys., 01AE02 (2010)

      Volume: 50

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Optical polarization anisotropy of nonpolar InN epilayers2010

    • Author(s)
      K.Wang, T.Yamaguchi, A.Takeda, T.Kimura, K.Kawashima, T.Araki, Y.Nanishi
    • Journal Title

      Physica State Solidi (a)

      Volume: 207 Pages: 1356-1360

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Optical polarization anisotropy of nonpolar InN epilayers2010

    • Author(s)
      K.Wang, T.Yamaguchi, A.Takeda, T.Kimura, K.Kawashima, T.Araki, Y.Nanishi
    • Journal Title

      Physica State Solidi(a) (In press(掲載決定))

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] InN Overgrowth Through in Situ A1N Nano-Mask on Sapphire Substrate2012

    • Author(s)
      王科、荒木努、武内道一、山口智広、名西信之
    • Organizer
      2012年春季第59回応用物理学関係連合講演会
    • Place of Presentation
      早稲田大学(東京都)
    • Year and Date
      2012-03-17
    • Related Report
      2011 Annual Research Report
  • [Presentation] 窒化物半導体新領域開拓にむけての材料技術最近の展開2012

    • Author(s)
      名西信之、山口智広、王科、荒木努、E.Yoon
    • Organizer
      2012年春季第59回応用物理学関係連合講演会
    • Place of Presentation
      早稲田大学(東京都)(招待講演)
    • Year and Date
      2012-03-16
    • Related Report
      2011 Annual Research Report
  • [Presentation] Free Holes in Mg Doped InN Confirmed by Thermopower Experiments2012

    • Author(s)
      K.Wang, T.Yamaguchi, T.Araki, Y.Nanishi, N.Miller, M.Mayer, J.W.Ager, K.M.Yu, W.Walukiewicz
    • Organizer
      4th International Symposium on Advanced Plasma Science and its Applications for Nitrides and Nanomaterials 2012
    • Place of Presentation
      中部大学(愛知県)
    • Year and Date
      2012-03-08
    • Related Report
      2011 Annual Research Report
  • [Presentation] Importance of Advanced Plasma for Frontier Nitride Semiconductor Technologies2012

    • Author(s)
      Y.Nanishi, T.Yamaguchi, K.Wang, T.Araki, E.Yoon
    • Organizer
      4th International Symposium on Advanced Plasma Science and its Applications for Nitrides and Nanomaterials 2012
    • Place of Presentation
      中部大学(愛知県)(招待講演)
    • Year and Date
      2012-03-05
    • Related Report
      2011 Annual Research Report
  • [Presentation] Application of DERI Method to thick InGaN and InN/InGaN MQW structure Growth2012

    • Author(s)
      Y.Nanishi, T.Yamaguchi, K.Wang, T.Araki, E.Yoon
    • Organizer
      KAUST-UCSB-NSF Workshop on Solid-State Lighting
    • Place of Presentation
      Thwal(サウジアラビア)(招待講演)
    • Year and Date
      2012-02-14
    • Related Report
      2011 Annual Research Report
  • [Presentation] Application of DERI Method to InGaN Growth and Mg Doping2011

    • Author(s)
      Y.Nanishi, T.Yamaguchi, K.Wang, T.Araki, E.Yoon
    • Organizer
      Advanced Workshop on 'Frontiers in Electronics' (WOFE 2011)
    • Place of Presentation
      San Juan(プエルトリコ)(招待講演)
    • Year and Date
      2011-12-21
    • Related Report
      2011 Annual Research Report
  • [Presentation] Strong Luminescence from Self-Assembled InN Nanocolumns with Few Dislocations Grown by Molecular Beam Epitaxy2011

    • Author(s)
      K.Wang, T.Araki, T.Yamaguchi, E.Yoon, Y.Nanishi
    • Organizer
      The 9th International Conference on Nitride Semiconductors (ICNS-9)2011
    • Place of Presentation
      グラスゴー(スコットランド)
    • Year and Date
      2011-07-15
    • Related Report
      2011 Annual Research Report
  • [Presentation] Investigation of InN Nanocolumns Grown on GaN Templates by Molecular Beam Epitaxy2011

    • Author(s)
      K.Wang, T.Yamaguchi, T.Araki, E.Yoon, Y.Nanishi
    • Organizer
      The 9th International Conference on Nitride Semiconductors (ICNS-9) 2011
    • Place of Presentation
      グラスゴー(スコットランド)
    • Year and Date
      2011-07-13
    • Related Report
      2011 Annual Research Report
  • [Presentation] Evaluation of P-type InN Using Temperature Dependence of I-V Characteristics2011

    • Author(s)
      H.Sakurai, J.Kikawa, R.Iwamoto, K.Wang, T.Yamaguchi, T.Araki, Y.Nanishi
    • Organizer
      The 9th International Conference on Nitride Semiconductors (ICNS-9) 2011
    • Place of Presentation
      グラスゴー(スコットランド)
    • Year and Date
      2011-07-13
    • Related Report
      2011 Annual Research Report
  • [Presentation] Temperature Dependence of I-V Characteristics of p-type InN Grown by RF-MBE2011

    • Author(s)
      H.Sakurai, J.Kikawa, R.Iwamoto, K.Wang, T.Yamaguchi, T.Araki, Y.Nanishi
    • Organizer
      30th Electronic Materials Symposium (EMS30)
    • Place of Presentation
      ラフォーレ琵琶湖(滋賀県)
    • Year and Date
      2011-07-01
    • Related Report
      2011 Annual Research Report
  • [Presentation] Molecular Beam Epitaxial Growth and Characterization of InN Nanocolumns on GaN2011

    • Author(s)
      K.Wang, T.Yamaguchi, T.Araki, E.Yoon, Y.Nanishi
    • Organizer
      Electronic Materials Conference 2011 (EMC2011)
    • Place of Presentation
      サンタバーバラ(アメリカ)
    • Year and Date
      2011-06-24
    • Related Report
      2011 Annual Research Report
  • [Presentation] Growth of InN Nanocolumns on GaN Templates and Sapphire by RF-MBE2011

    • Author(s)
      K.Wang, T.Yamaguchi, T.Araki, E.Yoon, Y.Nanishi
    • Organizer
      5th Asia-Pacific Workshop on Widegap Semicondu ctors
    • Place of Presentation
      鳥羽国際ホテル(三重県)
    • Year and Date
      2011-05-25
    • Related Report
      2011 Annual Research Report
  • [Presentation] Recent Progress of InN and Related Alloys Grown by DERI Method2011

    • Author(s)
      Y.Nanishi, T.Yamaguchi, K.Wang, T.Araki, E.Yoon
    • Organizer
      2011 E-MRS Spring Meeting
    • Place of Presentation
      ニース(フランス)(招待講演)
    • Year and Date
      2011-05-11
    • Related Report
      2011 Annual Research Report
  • [Presentation] Surface kinetics of indium adlayers and droplets and their roles in InN growth by molecular beam epitaxy2010

    • Author(s)
      Ke Wang, Tomohiro Yamaguchi, Tsutomu Araki1, Euijoon Yoon, Yasushi Nanishi
    • Organizer
      International Workshop on Nitride semiconductors (IWN)2010
    • Place of Presentation
      Florida, USA
    • Year and Date
      2010-09-23
    • Related Report
      2010 Annual Research Report
  • [Presentation] Mg doped InN and search for holes2010

    • Author(s)
      K.Wang, N.Miller, R.Iwamoto, T.Yamaguchi, M.Mayer, T.Araki, Y.Nanishi, J.W Ager III, K.M.Yu, W.Walukiewicz
    • Organizer
      International Workshop on Nitride semiconductors (IWN)2010
    • Place of Presentation
      Florida, USA
    • Year and Date
      2010-09-22
    • Related Report
      2010 Annual Research Report
  • [Presentation] Evidence of free holes in Mg doped InN2010

    • Author(s)
      K.Wang, R.Iwamoto, T.Yamaguchi, N.Miller, M.Mayer, T.Araki, Y.Nanishi, J.W Ager III, K.M.Yu, W.Walukiewicz
    • Organizer
      International Symposium on Growth of Nitride semiconductors (ISGN) 2010
    • Place of Presentation
      Montpellier, France
    • Year and Date
      2010-07-08
    • Related Report
      2010 Annual Research Report
  • [Presentation] Mg doped InN and search for p-type InN2010

    • Author(s)
      K.Wang, R.Iwamoto, T.Yamaguchi, N.Miller, M.Mayer, T.Araki, Y.Nanishi, J.W Ager III, K.M.Yu, W.Walukiewicz
    • Organizer
      Electronic Materials Conference (EMC) Jun 2010
    • Place of Presentation
      Notre Dame, USA
    • Year and Date
      2010-06-20
    • Related Report
      2010 Annual Research Report
  • [Presentation] Adsorption and Desorption of Indium Adlayer on GaN Surface2010

    • Author(s)
      王科、山口智広、荒木努、名西〓之
    • Organizer
      2010年春季 第57回 応用物理学関係連合講演会
    • Place of Presentation
      東海大学(平塚市)
    • Year and Date
      2010-03-17
    • Related Report
      2009 Annual Research Report
  • [Presentation] In Situ Monitoring of InN grown by RF-MBE2010

    • Author(s)
      K.Wang, T.Yamaguchi, T.Araki, Y.Nanishi
    • Organizer
      2nd International Symposium on Advanced Plasma Science and its Applications for Nitrides and Nanomaterials
    • Place of Presentation
      Meijo University, Nagoya, Japan
    • Year and Date
      2010-03-10
    • Related Report
      2009 Annual Research Report
  • [Presentation] Polarized Photoluminescence from Polar and Nonpolar InN Films2009

    • Author(s)
      K.Wang, T.Yamaguchi, T.Araki, Y.Nanishi
    • Organizer
      The 8th International Conference on Nitride Semiconductors(ICNS 2009)
    • Place of Presentation
      ICC Jeju, Jeju, Korea
    • Year and Date
      2009-10-19
    • Related Report
      2009 Annual Research Report

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Published: 2009-04-01   Modified: 2024-03-26  

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