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Hierarchical Mesoscopic Structures of Polymer Complexes

Research Project

Project/Area Number 10044051
Research Category

Grant-in-Aid for Scientific Research (B).

Allocation TypeSingle-year Grants
Section一般
Research Field 機能・物性・材料
Research InstitutionHOKKAIDO UNIVERSITY

Principal Investigator

SHIMOMURA Masatsugu  Hokkaido Univ., Research Institute for Electronic Science, Pro., 電子科学研究所, 教授 (10136525)

Co-Investigator(Kenkyū-buntansha) NISHIKAWA Takehiro  Hokkaido Univ., Research Institute for Electronic Science, Res. Asso., 電子科学研究所, 助手 (40281836)
KARTHAUS Olaf  Hokkaido Univ., Research Institute for Electronic Science, Res. Asso., 電子科学研究所, 助手 (80261353)
IJIRO Kuniharu  Hokkaido Univ., Research Institute for Electronic Science, Asso. Pro., 電子科学研究所, 助教授 (90221762)
OFFENHAUSSER アンドレアス  Max Planck研究所, 助手
KNOLL Wolfga  Max Planck研究所, 教授
Project Period (FY) 1998 – 1999
Project Status Completed (Fiscal Year 1999)
Budget Amount *help
¥4,400,000 (Direct Cost: ¥4,400,000)
Fiscal Year 1999: ¥2,200,000 (Direct Cost: ¥2,200,000)
Fiscal Year 1998: ¥2,200,000 (Direct Cost: ¥2,200,000)
KeywordsPolymer complexes / Dissipative structures / Surface Plasmon Resonance / Honeycomb structure / Micropattern / Molecular Recognition / Self-organization / Self-assembled monolayer(SAM) / キャストフィルム / 細胞培養 / 階層構造 / 糖鎖高分子 / 階層的構造化 / メゾスコピックパターン / 高分子 / ナノ構造 / 走査プローブ顕微鏡
Research Abstract

This study is cooperative research between physicists of the surface analysis and polymer chemists of thin film preparation. The purpose of this study is hierarchical structuring of the two-dimensional polymer complexes from nanometer to micrometer scale by using self-assembling and self-organization of molecules and molecular assemblies. Self-assembled monolayers of nucleobase amphiphile were preapered on gold surface. The formation of the complementary base pairing at the monolayer interface was observed by surface plasmon resonance technique. A honeycomb patterned film having bio-compatibility was prepared by the simple casting method. The two-dimensional topography of the patterned polymer thin film was observed as contrast image of the plasmon resonance microscope.

Report

(3 results)
  • 1999 Annual Research Report   Final Research Report Summary
  • 1998 Annual Research Report
  • Research Products

    (23 results)

All Other

All Publications (23 results)

  • [Publications] O.Karthaus他: "Mesoscopic Patterns of Polythiophenes for Electronic Applications"Molecular Crystals and Liquid Crystals. 327. 253-256 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] R.Ookura他: "Stabilization of Micropatterned Polymer Films as Artificial Extracellular Matrices for Tissue Engineering"Molecular Crystals and Liquid Crystals. 337. 461-465 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T.Nishikawa他: "Honeycomb Patterned Thin Films of Amphiphilic Polymers as Cell Culture Substrates"Materials Science and Engineering. C8-9. 495-500 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] O.Karthaus他: "Mesoscopic 2D Ordering of Inorganic/organic Hybrid Materials"Materials Science and Engineering. C10. 103-106 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T.Nishikawa他: "Surface Plasmon Optical Characterization of Web-Patterned Thin Polymer Films"Langmuir. 16. 1337-1342 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M.Shimomura: "Hierarchical Structuring of Nanostructured 2-Dimentional Polymer Assemblies. in "Chemistry in the 21st Century-Mesoscopic Chemistry""H.Masuhara,C.DeSchryver,IUPAC monographBlackwell Science. 260 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] O. Karthaus, T. Koito, N. Maruyama, M. Shimomura: "Mesoscopic Patterns of Polythiophenes for Electronic Applications."Mol. Cryst. Liq. Cryst.. 327. 253-256 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] R. Ookura, J. Nishida, T. Nishikawa, M. Shimomura: "Stabilization of Micropatterned Polymer Films as Artificial Extracellular Matrices for Tissue Engineering."Mol. Cryst. Liq. Cryst.. 337. 461-464 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T. Nishikawa, J. Nishida, R. Ookura, S. Nishimura, S. Wada, T. Karino, M. Shimomura: "Honeycomb Patterned Thin Films of Amphiphilic Polymers as Cell Culture Substrates."Mater. Sci. Eng.. C8-9. 495-500 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] O. Karthaus, X. Cieren, N. Maruyama, M. Shimomura: "Mesoscopic 2D Ordering of Inorganic / organic Hybrid Materials."Mater. Sci. Eng.. C10. 103-106 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T. Nishikawa, J. Nishida. S. Nishimura, W. Knoll, M. Shimomura: "Surface Plasmon Optical Characterization of Web-Patterned Thin Polymer Films."Langmuir. 16. 1337-1342 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] O. Karthaus: "Mesoscopic Patterns of Polythiophenes for Electronic Applications"Molecular Crystals and Liquid Crystals. 327. 253-256 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] R. Ookura: "Stabilization of Micropatterned Polymer Films as Artificial Extracellular Matrices for Tissue Engineeing"Molecular Crystals and Liquid Crystals. 337. 461-464 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] T. Nishikawa: "Honeycomb Patterned Thin Films of Amphophilic Polymers as Cell Culture Substrates"Materials Science and Engineering. C8-9. 485-500 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] O. Karthaus: "Mesoscopic 2D Ordering of Inorganic/organic Hybrid Materials"Materials Science and Engineering. C10. 103-106 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] T. Nishikawa: "Surface Plasmon Optical Characterization of Web-Patterned Thin Polymer Films"Langmuir. 16. 1337-1342 (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] M. Shimomura: "Hierarchical Structuring of Nanostructured 2-Dimensional Polymer Assemblies in "Chemistry for the 21st Century-Organic Mesoscopic Chemistry""H. Masuhara, F.C. DeSchryver, IUPAC monograph, Blackwell Science. 260 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] M.Shimomura他: "Mesoscopic Pattern Formation of Nanostructured Polymer Assemblies." Supramolecular Science. 5. 331-336 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] M.Shimomura他: "Construction of two-dimensional DNA-mimetics Supramolecular Architecture with Highly Stacked Base-Pairs of Amphiphilic Adenine and Thymine at the Air-Water Interface" Thin Solid Films. 327-329. 603-606 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] M.Shimomura他: "Mesoscopic Patterns of Molecular Aggregates on Solid Substrates." Thin Solid Films. 327-329. 854-856 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] M.Shimomura他: "Formation of Ordered Mesoscopic Patterns in Polymer Cast Films by Dewetting." Thin Solid Films. 327-329. 829-832 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] M.Shimomura他: "Photonic and Electronic Application of Mesoscopic Polymer Assemblies." Molecular Crystal Liquid Crystal. 322. 305-312 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Y.Okahata他: "Anisotropic Electric Conductivity in an Aligned DNA Cast Film." Journal of American Chemical Society. 120. 6165-6166 (1998)

    • Related Report
      1998 Annual Research Report

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Published: 1998-04-01   Modified: 2021-04-07  

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