• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

International Joint Study on Complex-Based Magnetic Materials

Research Project

Project/Area Number 10044089
Research Category

Grant-in-Aid for Scientific Research (B).

Allocation TypeSingle-year Grants
Section一般
Research Field 機能・物性・材料
Research InstitutionKumamoto University

Principal Investigator

MATSUMOTO Naohide  Kumamoto University, Dept. Chem., Professor, 理学部, 教授 (80145284)

Co-Investigator(Kenkyū-buntansha) NAKASHIMA Toshio  Ooita University, Faculty of Education, Professor, 教育学部, 教授 (70201879)
NAKAMURA Masaaki  Kumamoto University, Dept. Chem., Lecturer, 理学部, 講師 (00172437)
KAI Fumiaki  Kumamoto University, Dept. Chem., Professor, 理学部, 教授 (90040104)
Project Period (FY) 1998 – 1999
Project Status Completed (Fiscal Year 1999)
Budget Amount *help
¥6,000,000 (Direct Cost: ¥6,000,000)
Fiscal Year 1999: ¥2,100,000 (Direct Cost: ¥2,100,000)
Fiscal Year 1998: ¥3,900,000 (Direct Cost: ¥3,900,000)
Keywordscomplex / magnet / blocking method / ferromagnet / spin / multi-dimensional / 磁性 / 多次元構造 / 結晶 / 集合体 / 金属
Research Abstract

The field of molecular magnetism has shown quite spectacular advances in the last decade and several different approaches are currently used for the synthesis of the molecular based magnets. We have focused on a building block method by the use of two kinds of building locks, one of them containing a potential bridging ligand and other of them potential coordination sites. This method is very effective and successful to control the multi-dimensional extended structure and the magnetic property by choosing proper building blocks. The reaction products of two building components, [MnL(HィイD22ィエD2O)]ClOィイD24ィエD2 and [Fe(CN)ィイD26ィエD2]ィイD13-ィエD1, produces a variety of the extended multi-dimensional structures including 1D, 2D, 3D and discrete polynuclear structures and a variety of magnetic properties such as ferromagnet, ferrimagnet, and metamagnet.

Report

(3 results)
  • 1999 Annual Research Report   Final Research Report Summary
  • 1998 Annual Research Report
  • Research Products

    (19 results)

All Other

All Publications (19 results)

  • [Publications] 松本他: "{M_n(Salon)CN}_n : The first One-dimensional Chain with Alternating High- and low-spin Mn^<IV>"Angewandte Chemie International Edition. 38. 171-173 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 砂月他: "Synthesis, Magnetic properties, and Incomplete Double-Cu base Structure of Mn(III)-M(II) Complexes"Inorganic Chemistry. 37. 5566-5574 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 椎他: "Deprotonation-induced Enantioselective Aggregation and Deprotonation-induced Ligand Reamanagement of Copper(II)"Inorganic Chemistry. 38. 3513-3522 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 松本他: "pH-Dependent Monomer【double half arrows】Olinomer Interconversion of Copper (II) Complexes"Inorganic Chemistry. 38. 1165-1173 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] H. Miyasaka, H. Ieda, N. Matsumoto, N. Re, R. Crescenzi, and C. Floriani: "Assembling Bi-, Tri- and Pentanuclear Complexes into Extended Structures using a Desolvation Reaction: Synthesis, Structure, and Magnetic Properties of Manganese(III)-Schiff-Base-Hexacyanoferrate Polymeric Compounds and their Derived Extended structures"Inorg. Chem.. 37. 255-263 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] N. Re, R. Crescenzi, C. Floriani, and N. Matsumoto: "The Synthesis and Characterization of Two-Dimensional Ferromagnetic Extended Structures containing High-Spin (S = 5/2) and Low-Spin (S=1/2) Iron(III) Bridged by Cyanide Groups"Inorg. Chem.. 37. 2717-2722 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] N. Matsumoto, Y. Sunatsuki, H. Miyasaka, Y. Hashimoto, D. Leuou, and J. P. Tuchagues: "[{Mn(salen)CN}n]: The First One-dimensional Chain with Alternating High-spin and Low-spin Mnlll Centers Exhibits Metamagnetism"Angew. Chem. Int. Ed. Engl.. 38. 171-173 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y. Sunatsuki, H. Shimada, T. Matsuo, M. Nakamura, F. Kai, N. Matsumoto, and N. Re: "Synthesis, Magnetic Properties, and Incomplete Double-Cubane Structure of Manganese(III)-Metal(II) Complexes [Mn(MeOH)L(OH)M(bpy)]ィイD22ィエD2: (M = Zn, Cu, Ni, and Mn; HィイD24ィエD2L = 1,2-Bis(2-hydroxybenzamido)benzene; bpy =2,2i-Bipyridine"Inorg. Chem.. 37. 5566-5574 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Mimura, T. Matsuo, N. Matsumoto, S. Takamizawa, W. Mori, and N. Re: "Bis[(methanol) {N-salicylidene-N'-(2-phenylimidazol-4-ylmethylidene)-1,3-propane-diamino}nickel(II)] Bridged by Di-μ-phenoxo Moiety and the Deprotonated Imidazolate-Bridged Cyclic-Tetranuclear Complex"Bull. Chem. Soc. Jpn.. 71. 1831-1837 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] N. Matsumoto, Y. Motoda, T. Matsuo, T. Nakashima, N. Re, F. Dahan, and J. P. Tuchagues: "pH-Dependent Monomer Oligomer Interconversion of Copper(II) Complexes with N-(2-R-imidazol-4-ylmethylidene)-2-aminoethylpyridine (R=Methyl and Phenyl)"Inorg. Chem.. 38. 1165-1173 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Y. Shii, Y. Motoda, T. Matsuo, F. Kai, T. Nakashima, J. P. Tuchagues, and N. Matsumoto: "Deprotonation-induced Enantioselective Aggregation and Deprotonation-induced Ligand Rearrangement of Copper(II) Complexes Yield 1D Homochiral and Heterochiral Chains and a Cyclic Tetramer, Respectively"Inorg. Chem.. 38. 3513-3522 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 松本他: "{Mn(salon)CN}_h: The First one-dimensional Chain with Alterhating High- and low-spin Mn^<III>"Angewaviolte Chemie International Edition. 38. 171-173 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 砂月他: "Synthesis, Magnetic Properties, and Incomplete Double-cubare structure of Mn(III)-M(II) Complexes"Inorganic Chemistry. 37. 5566-5574 (1998)

    • Related Report
      1999 Annual Research Report
  • [Publications] 椎他: "Deprotonation-induced Enantioselective Aggregation and Deprotonation-induced Ligand Roamangement of Copper(II)"Inorganic Chemistry. 38. 3513-3522 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 松本他: "pH-Pependent Monomer 【double half arrows】 Oligomer Interconversion of Copper(III) complexes"Inorganic Chemistry. 38. 1165-1173 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 砂月,松本,N.Re他: "不完全ダブルキューバン錯体の合成,構造磁性" Inorganic Chemistry. 37・21. 5566-5574 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 宮坂,松本,C.フロリマーニ他: "マンガン(III)シッフ塩基と[Fe(CN)_6]^<3->反応による集積錯体" Inorganic Chemistry. 37・2. 255-263 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 砂月,中村,ツシャガ他: "ヘテロ金属二核,四核錯体の合成" Bulletin of the Chemical Society of Japan. 71・11. 2611-2619 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 松本,ツシャガ他: "[Mn(Salen)CN]_nのメタ磁性" Angewandte Chemie Inter.Ed.Engl.38・1/2. 171-173 (1999)

    • Related Report
      1998 Annual Research Report

URL: 

Published: 1998-04-01   Modified: 2016-04-21  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi