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Surface Modification by Carbon for Enhanced Performance

Research Project

Project/Area Number 10044108
Research Category

Grant-in-Aid for Scientific Research (B).

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic chemistry
Research InstitutionHOKKAIDO UNIVERSITY

Principal Investigator

KONNO Hidetaka (1999-2000)  Hokkaido Univ., Grad.School of Eng., Prof., 大学院・工学研究科, 教授 (50002316)

稲垣 道夫 (1998)  北海道大学, 大学院・工学研究科, 教授 (20023054)

Co-Investigator(Kenkyū-buntansha) OHTSUKA Toshiaki  Hokkaido Univ., Grad.School of Eng., Prof., 大学院・工学研究科, 教授 (20113532)
INAGAKI Michio  Aichi Institute of Tech., Fac.of Eng., Prof., 応用化学科, 教授 (20023054)
VERTES A.  エートヴェシュ大学, 教授
SKOWRONSKI J  ボズナニ工科大学, 教授
MORAWSKI A.  シュチェチン大学, 教授
金野 英隆  北海道大学, 大学院・工学研究科, 助教授 (50002316)
Project Period (FY) 1998 – 2000
Project Status Completed (Fiscal Year 2000)
Budget Amount *help
¥3,500,000 (Direct Cost: ¥3,500,000)
Fiscal Year 2000: ¥1,100,000 (Direct Cost: ¥1,100,000)
Fiscal Year 1999: ¥1,000,000 (Direct Cost: ¥1,000,000)
Fiscal Year 1998: ¥1,400,000 (Direct Cost: ¥1,400,000)
KeywordsCarbon film / Carbonization / Organic polymers / Specific surface area / Carbon-coated ceramics / Carbon-coated metals / Fine structure / Surface finishing / フェノール樹脂 / トリハロメタン / ポリ塩化ビニル
Research Abstract

By using promising characteristics of carbon materials, A) surface modification of carbon materials and B) carbon coating of metals and ceramics were caiited out to enhance the functions of respective materials. Results are summarized as below.
A-1) By oxidation of the carbon materials derived from phenol resin, activated carbons having high efficiencies for adsorption of trihalomethane and molecular sieving properties were produced. Fine structure of pores was investigated by STM and SEM.
A-2) Surface modification of graphite flakes were carried out using weak oxygen plasma. A method to create defect clusters confined to 1-2 surface layers was established
B-1) A new process to coat ceramics powder with thin uniform carbon layer was developed by heating the mixed powder of ceramics and organic polymers under inert atmospheres.
B-2) A process to coat aluminum components with carbonaceous-films was developed using the method derived from B-1) in which formation of porous oxide films on aluminum was an important step for uniform and adhesive coating.
B-3) By heating the mixed powder of transition metal oxides and organic polymers under inert atmospheres, carbon or graphite coated metal particles were formed at 1150-12OO℃. The process is promising for the production of graphite at low temperatures.

Report

(4 results)
  • 2000 Annual Research Report   Final Research Report Summary
  • 1999 Annual Research Report
  • 1998 Annual Research Report
  • Research Products

    (40 results)

All Other

All Publications (40 results)

  • [Publications] M.Inagaki: "Gas adsorption behavior of activated carbon spheres from phenol resin"Tanso. 1998[No.183]. 146-150 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] V.Vignal,: "Quantitative assessment of pores in oxidized carbon spheres using scanning tunneling microscopy"J.Mater.Res.. 14. 1102-1112 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Inagaki: "Effects of carbonization atmosphere and subsequent oxidation on pore structure of carbon spheres observed by scanning tunnelinf microscopy"J.Mater.Res.. 14. 3152-3157 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Inagaki: "Effect of oxygen plasma treatment on gas adsorption behavior and surface structure of carbon spheres derived from phenol resin"J.Mater.Res.. 14. 3208-3210 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Konno: "Structural Changes in Carbon Films Derived from Kapton Observed by the PositronAnnihilation Lifetime Technique"Carbon. 38. 1419-1422 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] A.W.Morawski: "Adsorption of Trihalomethanes (THMs) onto Carbon Spheres"Desalination. (印刷中).

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Inagaki: "A new simple process for carbon coating of ceramic particles using poly (vinyl chloride)"J.Europ.Ceram.Soc.. 18. 1011-1015 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Inagaki: "Graphite formation from a mixture of Fe_3O_4 and polyvinylchloride at 1000℃"Carbon. 36. 1706-1708 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Inagaki: "Preparation of carbons-coated transition metal particles from mixtures of metal oxide and polyvinylchloride"Carbon. 37. 329-334 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Konno: "Formation of carbonaceous-coatings on aluminium using poly (vinyl alcohol)"J.Europ.Ceram.Soc.. 20. 1391-1396 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Inagaki: "Formation of Graphite Crystals at 1000-1200℃ from Mixtures of Vinyl Polymers with Metal Oxides"Carbon. 39(印刷中). (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] T.Tsumura: "Surface Modification of Carbon Materials for Lithium Ion Batteries"Solid State Ionics. (印刷中). (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Inagaki and M.Sunahara: "Gas Adsorption-Desorption Behavior of Activated Carbon Spheres Derived from Phenol Resin"Tanso. [No.183]. 146-150 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Inagaki, H.Miura and H.Konno: "A New Simple Process for Carbon Coating of Ceramic Particles Using Poly (Vinl chloride)"J.Europ.Ceram.Soc.. 18. 1011-1015 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Inagaki, Y.Okada, V.Vignal, H.Konno and K.Oshida: "Graphite Formation from a Mixture of Fe_3O_4 and Polyvinylchloride at 1000℃"Carbon. 36. 1706-1708 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Inagaki, Y.Okada, H.Miura and H.Konno: "Preparation of Carbon-Coated Transition Metal Particles from Mixtures of Metal Oxide and Polyvinylchloride"Carbon. 37. 329-334 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] V.Vignal, A.W.Morawski, H.Konno and M.Inagaki: "Quantitative Assessment of Pores in Oxidized Carbon Spheres Using Scanning Tunneling Microscopy"J.Mater.Res.. 14. 1102-1112 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Inagaki, V.Vignal, H.Konno and A.W.Morawski: "Effects of Carbonization Atmosphere and Subsequent Oxidation on Pore Structure of Carbon Spheres Observed by STM"J.Mater.Res.. 14. 3152-3157 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Inagaki, M.Sunahara, A.Shindo, V.Vignal and H.Konno: "Effect of Oxygen Plasma Treatment on Gas Adsorption Behavior and Surface Structure of Carbon Spheres Derived from Phenol Resin"J.Mate.Res.. 14. 3208-3210 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Konno, K.Suvegh, A.Vertes and M.Inagaki: "Structural Changes in Carbon Films Derived from Kapton Observed by the Positron Annihilation Lifetime Technique"Carbon. 38. 1419-1422 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Konno, K.Oyamada and M.Inagaki: "Formation of Carbonaceous-Coatings on Aluminium Using Poly (vinyl alcohol)"J.Europ.Ceram.Soc.. 20. 1391-1396 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] A.W.Morawski, R.Kaleczuk and M.Inagaki: "Adsorption of Trihalomethanes (THMs) onto Carbon Spheres"Desalination. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Inagaki, K.Fujita, Y.Takeuchi, K.Oshida, H.Iwata and H.Konno: "Formation of Graphite Crystals at 1000-1200℃ from Mixtures of Vinyl Polymers with Metal Oxides"Carbon. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] T.Tsumura, A.Katanosaka, I.Souma, T.Ono, Y.Aihara, J.Kuratori and M.Inagaki: "Surface Modification of Carbon Materials for Lithium Ion Batteries"Solid State Ionics. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Konno, K.Oyamada, M.Inagaki: "Formation of carbonaceous-coatings on aluminium using poly (vinyl alcohol)"J.Europ.Ceram.Soc.. 20. 1391-1396 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] H.Konno, K・Suvegh, A.Vertes and M.Inagaki: "Structural Changes in Carbon Films Derived from Kapton Observed by the Positron Annihilation Lifetime Technique"Carbon. 38. 1419-1422 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] A.W.Morawski, R.Kaleczuk and M.Inagaki: "Adsorption of Trihalomethanes (THMs) onto Carbon Spheres"Desalination. (印刷中).

    • Related Report
      2000 Annual Research Report
  • [Publications] M.Inagaki, K.Fujita, Y.Takeuchi, K.Oshida, H.Iwata and H.Konno: "Formation of Graphite Crystals at 1000-1200℃ from Mixtures of Vinyl Polymers with Metal Oxides"Carbon. 39(印刷中). (2001)

    • Related Report
      2000 Annual Research Report
  • [Publications] T.Tsumura, M.Inagaki ら: "Surface Modification of Carbon Materials for Lithium Ion Batteries"Solid State Ionics. (印刷中).

    • Related Report
      2000 Annual Research Report
  • [Publications] H. Konno, K. Oyamada, M. Inagaki: "Formation of carbonaceous-coatings on aluminium using poly(vinyl alcohol)"J. Europ. Ceram. Soc.. 20. 印刷中 (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] M. Inagaki, Y. Okada, H. Miura, H. Konno: "Preparation of carbons-coated transition metal particles from mixtures of metal oxide and polyyinylchloride"Carbon. 37. 329-334 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] H. Konno, T. Nakahashi, M. Inagaki, T. Sogabe: "Nitrogen Incorporation into boron-doped graphite and formation of B-N bonding"Carbon. 37. 471-475 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] H. Konno, H. Oka, K. Shiba, H. Tachikawa, M. Inagaki: "Carbonization of boron containing polyimide films"Carbon. 37. 887-895 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] V. Vignal, A. W. Morawski, H. Konno, M. Inagaki: "Quantitative assessment of pores in oxidized carbon spheres using scanning tunneling microscopy"J. Mater. Res.. 14. 1102-1112 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] M. Inagaki, V. Vignal, H. Konno, A. W. Morawski: "Effects of carbonization atmosphere and subsequent oxidation on pore structure of carbon spheres observed by scanning tunneling microscopy"J. Mater. Res.. 14. 3152-3157 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] M. Inagaki, M. Sunahara, A. Shindo, V. Vignal, H. Konno: "Effect of oxygen plasma treatment on gas adsorption behavior and surface structure of carbon spheres derived from phenol resin"J. Mater. Res.. 14. 3208-3210 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] M.Inagaki: "Gas Adsorption-Desorption Behavior of Activated Carbon Spneres Derived from Phenol Resin" 炭素. 1998. 146-150 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] M.Inagaki: "A New Simple Process for Carbon Coating of Ceramic Particles using Poly(Vinyl Chloride)" J.European Ceramic Society. 18. 1011-1015 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] M.Inagaki: "Graphite formation from a mixture of Fe_3O_4 and poly vinylchloride at 1000゚C" Carbon. 36・11. 1706-1708 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] M.Inagaki: "Preparation of Carbon-Coated Transition Metal Particles from Mixtures of Metal Oxide and Poly vinylchloride" Carbon. 37(印刷中). (1999)

    • Related Report
      1998 Annual Research Report

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Published: 1998-04-01   Modified: 2016-04-21  

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