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Process Modeling of Anisotropic Chemical Etching of Silicon

Research Project

Project/Area Number 10044149
Research Category

Grant-in-Aid for Scientific Research (B).

Allocation TypeSingle-year Grants
Section一般
Research Field Applied physics, general
Research InstitutionNagoya University

Principal Investigator

SATO Kazuo  Nagoya University, Graduate School of Engineering, Professor, 工学研究科, 教授 (30262851)

Co-Investigator(Kenkyū-buntansha) SHIKIDA Mitsuhiro  Nagoya University, Graduate School of Engineering, Assist. Professor, 工学研究科, 助手 (80273291)
MOKTADIR Zak  LAAS/CNRS, 研究員
CAMON Henri  LAAS/CNRS, グループリーダー
VAN Suchtele  トエンテ大学, MESA研究所, プロジェクトリーダー
ELWENSPOEK M  トエンテ大学, MESA研究所, 教授
Project Period (FY) 1998 – 1999
Project Status Completed (Fiscal Year 1999)
Budget Amount *help
¥3,100,000 (Direct Cost: ¥3,100,000)
Fiscal Year 1999: ¥1,600,000 (Direct Cost: ¥1,600,000)
Fiscal Year 1998: ¥1,500,000 (Direct Cost: ¥1,500,000)
KeywordsSilicon / Etching rate / Surface roughness / Orientation-dependent etching / Potassium-hydroxide (KOH) / Tetramethyl-ammonium-hydroxide (TMAH) / Model / Fractal / 異方性エッチング / 結晶 / 粗さ / モデリング / 水酸化カリウム / シリコン単結晶 / 結晶異方性エッチング / プロセスシミュレーション / マイクロマシン
Research Abstract

We investigated orientation-dependent anisotropic etching of single-crystal silicon. The group of Nagoya University measured etching rates of silicon using alkaline solutions such as potassium-hydroxide (KOH) and tetramethyl-ammonium-hydroxide (TMAH) water solutions. They evaluated the orientation dependence in the etching rate for a number of crystallographic orientations under wide ranges of etching conditions in temperature and etchant concentrations.
The group of the Univ. of Twente and the Univ. of Nijmegen tried to describe such orientation dependence using a limited number of physical parameters, which used to be used in crystal growth that is the reverse process of etching. They introduced 9 parameters, and by fitting those values to experimental data provided from Nagoya Univ., they succeeded in describing etching rates within an error of 5% for one etching condition using KOH water solution. The results were presented in two international conferences, and will be published in Sensors and Actuators : A. It is our future work to describe orientation dependence for a wide range of etching conditions, because the orientation dependence significantly varies according to the conditions.
The group of LAAS/CNRS simulated the etching process in atomic scale using Monte Carlo method based on a model, which considers weakening of silicon back-bonds according to the increase in the number of OH attached to the silicon surface-atom. The simulated orientation dependence was similar to that of the experimental results of TMAH rather than KOH both measured by Nagoya Univ.
We organized a workshop focused on silicon anisotropic etching. The first workshop was held in 1998 in Holten, the Netherlands, and going to be held in 2000 in Toulouse, France. We are planning the third in 2002 in Japan.

Report

(3 results)
  • 1999 Annual Research Report   Final Research Report Summary
  • 1998 Annual Research Report
  • Research Products

    (52 results)

All Other

All Publications (52 results)

  • [Publications] 山城隆,他: "シリコンの結晶異方性エッチングにおける加工面粗さ"日本機械学会第75期通常総会講演会論文集. 1. 73-74 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 式田光宏,他: "結晶異方性エッチングにおけるシリコン単結晶の粗面化"電気学会研究会資料. MM-98-15. 7-11 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] K. Sato: "Characterization of etching properties of single-crystal silicon for KOH and TMAH solutions"Proc. of Workshop on Physical Cemistry of Wet Chemical Etching of Silicon. 5/17-19, Holten. 6-7 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] K. Tokoro, et al.: "Anisotropic Etching Properties of Silicon in KOH and TMAH Solutions"Proc. of IEEE MHS-98. 11/25-28, Nagoya. 65-70 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M. Shikida, et al.: "Comparison of Anisotropic Etching Properties between KOH and TMAH Solutions"Proc. of IEEE Int. MEMS-99. 1/17-21, Orland. 315-320 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] J. van Suchtelen, et al.: "Simulation of Anisotropic Wet-Chemical Etching Using a Physical Model"Proc. of IEEE Int. MEMS-99. 1/17-21, Orland. 332-337 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] K. Sato, et al.: "Anisotropic etching rates of single-crystal silicon for TMAH water solution as a function of crystallographic orientation"Sensors and Actuators. A73, 1-2. 131-137 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] O. Tabata, et al.: "Effect of pottasium ion on anisotropy of TMAH"Tech. Dig. Int. Conf. Solid-State Sensors and Actuators. June, Sendai. 542-545 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 佐藤一雄,他: "結晶異方性エッチング解析システムMICROCADの開発"電子情報通信学会論文誌. J82-C-2-3. 84-91 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] K. Sato, et al.: "Roughening of single-crystal silicon surface etched by KOH water solution"Sensors and Actuators. A73, 1-2. 122-130 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M. Shikida, et al.: "Anisotropically etched surface morophology of single-crystal silicon as a function of orientation"Tech. Dig. Int. Conf. Solid-State Sensors and Actuators. June, Sendai. 1218-1221 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M. Shikida, et al.: "Change in etching rate and surface morphology of (110) silicon ; effects of dissolved silicon concentration in KOH etchant"Tech. Dig. Int. Conf. Solid-State Sensors and Actuators. June, Sendai. 1868-1869 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M. Shikida, et al.: "Observation of facet growth on (110) plane during an anisotropic KOH etching"Tech. Dig. Int. Conf. Solid-State Sensors and Actuators. June, Sendai. 1870-1871 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Z. Moktadir, et al.: "Roughness characterization of Si (110) etched in TMAH by atomic force microscopy"Proc. MRS Fall Meeting 1999. Nov. Boston (in print). (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] E. van Veenendaal, et al.: "Simulation of anisotropic wet-chemical etching using a physical model"Sensors and Actuators. A (in print). (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M. Shikida, et al.: "Differences in anisotropic etching properties of KOH and TMAH"Sensors and Actuators. A (in print). (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 佐藤一雄(分担執筆): "エンサイクロペディア電子情報通信ハンドブック"電子情報通信学会編,オーム社. 1339 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T. Yamashiro, K. Tokoro et al.: "Surface roughness of silicon etched by chemical anisotropic etchants"Proc. The 75th JSME Spring Annual Meeting. 73-74 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M. Shikida, T. Yamashiro et al.: "Characterization of roughness of anisotropically etched silicon surface"Tech. Dig. Micromachine Meeting of IEEJ. MM98-15. 7-11 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] K. Sato: "Characterization of etching properties of single-crystal silicon for KOH and TMAH solutions"Proc. Workshop on Physical Chemistry of Wet Etching of Silicon. 6-7 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] K. Tokoro, D. Uchikawa et al.: "Anisotropic etching properties of silicon in KOH and TMAH solutions"Proc. IEEE Int. Symp. MHS. 65-70 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M. Shikida, K. Sato et al.: "Comparison of anisotropic etching properties between KOH and TMAH solutions"Proc. IEEE Int. MEMS 99 Conf.. 315-320 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] J. van Suchtelen, K. Sato et al.: "Simulation of anisotropic wet-chemical etching using a physical model"Proc. IEEE Int. MEMS 99 Conf.. 332-37 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] K. Sato et al.: "Anisotropic etching rates of single-crystal silicon for TMAH water solution as a function of crystallographic orientation"Sensors and Actuators. A73, 1-2. 131-137 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] O. Tabata, M. Yashima et al.: "Effect of potassium ion on anisotropy of TMAH"Tech. Dig. Int. Conf. Solid-State Sensors and Actuators. 542-545 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] K. Sato, K. Asaumi et al.: "Development of an orientation-dependent anisotropic etching simulation system MICROCAD"Trans. Institute of Electronics, Information and Communication Engineers. C2. 84-91 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] K. Sato, M. Shikida et al.: "Roughening of single-crystal silicon surface etched by KOH water solution"Sensors and Actuators. A73 1-2. 122-130 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M. Shikida, K. Tokoro et al.: "Anisotropically etched surface morphology of single-crystal silicon as a function of orientation"Tech. Dig. Int. Conf. Solid-State Sensors and Actuators. 1218-1221 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M. Shikida et al.: "Change in etching rate and surface morphology of (110) silicon ; effects of dissolved silicon concentration in KOH etchant"Tech. Dig. Int. Conf. Solid-State Sensors and Actuators. 1868-1869 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M. Shikida, K. Sato et al.: "Observation of facet growth on (110) plane during an anisotropic KOH etching"Tech. Dig. Int. Conf. Solid-State Sensors and Actuators. 1870-1871 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Z. Moktadir, K. Sato et al.: "Roughness characterization of Si (110) etched in TMAH by atomic force microscopy"Proc. MRS Fall Meeting 1999. in print.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] E. van Veenendaal, A. J. Nijdam et al.: "Simulation of anisotropic wet-chemical etching using a physical model"Sensors and Actuators. in print. (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M. Shikida, K. Sato et al.: "Differences in anisotropic etching properties of KOH and TMAH"Sensors Actuators. in print. (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] K. Sato et al.: "Encyclopedia Electronics, Information and Communication Handbook"Society of EIC, Ohmsha. (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] K.Sato,et al.: "Anisotropic etching rates of single-crystal silicon for TMAH water solution as a function of crystallographic orientation"Sensors and Actuators. A73,1-2. 131-137 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] O.Tabata,et al.: "Effect of pottasium ion on anisotropy of TMAH"Tech.Dig.Int.Conf.Solid-State Sensors and Actuators. June,Sendai. 542-545 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 佐藤一雄,他: "結晶異方性エッチング解析システムMICROCADの開発"電子情報通信学会論文誌. J82-C-2-3. 84-91 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] K.Sato, et al.: "Roughening of single-crystal silicon surface etched by KOH water solution"Sensors and Actuators. A73,1-2. 122-130 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] M.Shikida,et al.: "Anisotropically etched surface morphology of single-crystal silicon as a function of orientation"Tech.Dig.Int.Conf.Solid-State Sensors and Actuators. June,Sendai. 1218-1221 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] M.Shikida,et al.: "Change in etching rate and surface morphology of (110) silicon; effects of dissolved silicon concentration in KOH etchant"Tech.Dig.Int.Conf.Solid-State Sensors and Actuators. June,Sendai. 1868-1869 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] M.Shikida,et al.: "Observation of facet growth on (110) plane during an anisotropic KOH etching"Tech.Dig.Int.Conf.Solid-State Sensors and Actuators. June,Sendai. 1870-1871 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Z.Moktadir,et al.: "Roughness characterization of Si (110) etched in TMAH by atomic force microscopy"Proc.MRS Fall Meeting 1999. Nov.,Boston(in print). (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] E.van Veenendaal,et al.: "Simulation of anisotropic wet-chemical etching using a physical model"Sensors and Actuators. A(in print). (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] M.Shikida,et al.: "Differences in anisotropic etching properties of KOH and TMAH"Sensors and Actuators. A(in print). (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] K.Sato,et al.: "Characterization of orientation dependent etching properties of single crystal silicon:Effects of KOH concentration" Sensors and Actuators. A64-1. 87-93 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 式田光宏,他: "結晶異方性エッチングにおけるシリコン単結晶の粗面化" 電気学会研究会資料. MM-98-15. 7-11 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] K.Sato: "Characterization of etching properties of single-crystal silicon for KOH and TMAH solutions" Proc.of Workshop on Physical Cemistry of Wet Chemical Etching of Silicon. 5/17-19,Holten. 6-7 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] K.Tokoro,et al.: "Anisotropic Etching Properties of Silicon in KOH and TMAH Solutions" Proc.of IEEE MHS-98. 11/25-28,Nagoya. 65-70 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] M Shikida,et al.: "Comparison of Anisotropic Etching Properties between KOH and TMAH Solutions" Proc.of IEEE Int.MEMS-99 Conf.1/17-21,Orland. 315-320 (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] J.van Suchtelen,et al.: "Simulation of Anisotropic Wet-Chemical Etching Using a Physical Model" Proc of IEEE Int.MEMS-99 Conf.1/17-21,Orland. 332-337 (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] 佐藤一雄: "Physical Chemistry of Wet Anisotropic Etching of Silicon" 電気学会E部部門誌. E118-9. 433 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 佐藤一雄(分担執筆): "エンサイクロペディア電子情報通信ハンドブック" 電子情報通信学会編,オーム社, 1339 (1998)

    • Related Report
      1998 Annual Research Report

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Published: 1998-04-01   Modified: 2016-04-21  

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