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Design and Development of Unique Photocatalytic Systems for the Decomposition of NOx

Research Project

Project/Area Number 10044170
Research Category

Grant-in-Aid for Scientific Research (B).

Allocation TypeSingle-year Grants
Section一般
Research Field 触媒・化学プロセス
Research InstitutionOsaka Prefecture University

Principal Investigator

ANPO Masakazu  Osaka Prefecture University, College of Engineering, Professor, 工学部, 教授 (70094498)

Co-Investigator(Kenkyū-buntansha) MATSUOKA Masaya  Osaka Prefecture University, College of Engineering, Research Associate, 工学部, 助手 (80305648)
YAMASHITA Hiromi  Osaka Prefecture University, College of Engineering, Associate Professor, 工学部, 助教授 (40200688)
GIAMELLO Eli  イタリア, トリノ大学, 助教授
CHE Michel  フランス, パリ第6大学, 教授
LOUIS Cather  フランス, 触媒研究所, 主任研究員
Project Period (FY) 1998 – 1999
Project Status Completed (Fiscal Year 1999)
Budget Amount *help
¥3,200,000 (Direct Cost: ¥3,200,000)
Fiscal Year 1999: ¥1,400,000 (Direct Cost: ¥1,400,000)
Fiscal Year 1998: ¥1,800,000 (Direct Cost: ¥1,800,000)
KeywordsMetal ion-implantation method / TiOィイD22ィエD2 photocatalyst / NOx decomposition / Utilization of solar beam / Cr ion-implanted TiOィイD22ィエD2 / Utilization of visible light / Ag / ZSM-5 / 酸化チタン / 太陽光 / イオン注入法 / NO光触媒分解反応 / ゼオライト / ESR
Research Abstract

Until now, photocatalytic reactions involving TiO2 photocatalysts for the decomposition of NOx were known to proceed only under UV light irradiation. In this research project, by the application of advanced metal ion-implantation with various transition metal ions such as V and Cr, it was found that novel TiO2 photocatalysts which absorb and operate efficiently under visible light irradiation for the decomposition of NOx could be developed. In-situ ESR and XAFS investigations revealed that the implanted V ions which exist as VィイD14+ィエD1 at the lattice position in place of TiィイD14+ィエD1 ion play a significant role in the shift in the absorption bands of TiO2 toward visible light regions. On the other hand, highly dispersed TiO2 catalysts anchored within the pore structure of the Y-zeolite by an ion-exchange method (Ti-Y zeolite) exhibited higher photocatalytic activity as compared to powdered TiO2. V or Cr ion-implantation on the Ti-Y zeolite also leads to a shift in the absorption band of the catalyst toward visible light regions and it was found that these V or Cr ion-implanted Ti-Y zeolites successfully decompose NOx under irradiation with visible light longer than 450nm, while maintaining just as a high photocatalytic activity as observed before applying ion-implantation. Furthermore, in-situ ESR and FT-IR investigations *lucidated the electron transfer from the photo-excited active site of the photocatalyst into the p anti-bonding molecular orbital of NO which led to a weakening of the N-O bond and initiated the decomposition of the NO molecule. It can be said that the present research has opened the way to many innovative possibilities, significantly to address urgent environmental problem and also as an important breakthrough in the utilization of solar energy.

Report

(3 results)
  • 1999 Annual Research Report   Final Research Report Summary
  • 1998 Annual Research Report
  • Research Products

    (148 results)

All Other

All Publications (148 results)

  • [Publications] Sang. Chul. MOON: "Stoichimetric Decomposition of Pure Water over Pt-Loaded Ti/B Binary Oxide under UV-Irradiation"Chem. Lett.. 117-118 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Hiromi YAMASHITA: "Photocatalytic Reduction of CO2 with H2O on Ti/Si Binary Oxide Catalysts prepared by the Sol-Gel Method"Stud. Surf. Sci. Catal.. 114. 561-564 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Masakazu ANPO: "Photocatalytic Reduction of CO2 with H2O on Titanium Oxide Anchored within Zeolites"Stud. Surf. Sci. Catal. 114. 177-182 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Masakazu ANPO: "Design of Unique Titanium Oxide Photocatalysts by an Advanced Metal Ion-implantation Method and Photocatalytic Reactions under Visible Light Irradiation"Res. Chem. Intermed.. 24. 143-149 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Shu, Guo, Zhang: "The Photoluminescence Property and Photocatalytic Reactivity of the V-HMS Mesoporous Zeolite : Pore Size Effect of the Photocatalytic Properties"Microporous Mater.. 621-627 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Masakazu ANPO: "The Relationship between the Local Structure of Copper (I) Ions on Cu+/ZeoliteCatalysts and Their Photocatalytic Reacrivities for the Decomposition of Nox into N2 and O2 at 275K"Coord. Chem. Rev.. 171. 175-184 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Hiromi YAMASHITA: "Preparation of Titanium Oxide Photocatalysts Anchored on Porous Silica Glass by Metal Ion-Implantation Method and Their Photocatalytic Reactivities for the Degradation of 2-Propanol Diluted in Water"J. Phys. Chem. B. 102. 10707-10711 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Hiromi YAMASHITA: "Chracterization of Ti/Si Binary Oxides Preparedby the Sol-Gel Method and Their Photocatalytic properties : The Hydrogenation and Hydrogenolysis of CH3CCH with H2O"Korean J. Chem. Eng.. 15. 491-495 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Masakazu ANPO: "Photocatalytic Reduction of CO2 with H2O on Ti-MCM-41 and Ti-MCM-48 Mesoporous eolite Catalysts"Catal. Today. 44. 327-332 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Hiromo YAMASHITA: "Selective Formation of CH3OH in the Photocatalytic Reduction of CO2 with H2O on Titanium Oxides Highly Dispersed within Zeolites and Mesoporous Molecular Sieves"Catal. Today. 45. 221-227 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 原田 賢: "クラスターイオンビーム法による酸化チタン光触媒の調製とその液相光触媒反応活性"触媒. 40. 478-481 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Hirotsugu MISHIMA: "Selective Catalytic Reduction of NO with NH3 over Natural Zeolites and Its Application to Stationary Diesel Engine Exhaust"Appl. Catal. B-Environ.. 19. 119-126 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Hiroyasu NISHIGUCHI: "Phosphrescence and Photochemical Properities of Benzophenone Included in Alkali Metal cation-Exchanged ZSM-5 Zeolites"Res. Chem. Intermed. 24. 849-858 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Hiromi YAMASHITA: "Characterization of Titanium-Silicon Binary Oxide Catalysts Prepared by the Sol-Gel Method and Their Photocatalytic Reactivity for the Liquid Phase Oxidation of 1-Octanol"J. Phys. Chem. B. 102. 5870-5875 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] N. U. Zhanpeisov: "Cluster Quantum Chemical ab Initio Study on the Interaction of NO Molecules with Highly Dispersed Titanium Oxides Incorporated into Silicalite and Zeolites"J. Phys . Chem. B. 102. 6915-6920 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Stanislaw DZWIGAJ: "Probing Different Kinds of Vanadium Species in the Vsib Zeolite by Diffuse Reflectance UV-Visible and Photoluminescence Spectroscopies"J. Phys. Chem. B. 102. 6309-6312 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Shu. Guo. Zhang: "Characterization of V-oxide/ZSM-5 Zeolite Catalysts Prepared by the Solid-State Reaction and Their Photocatalytic Reactivity : In Situ Photoluminescene, XAFS, ESR, FT-IR, and UV-VIS Investigation"J. Phys. chem. B. 102. 5590-5594 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] N. U. Zhanpeisov: "Interaction of Molecules with a Copper-Containing Zeolite ; A Theoretical Ab Intio Study"J. Mol. Struct.(Theochem). 454. 201-207 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 安保正一: "光触媒と環境浄化"クリーン関西. 87. 15-23 (1998)

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      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 松岡雅也: "可視光照射下でのゼオライト細孔内における炭化水素の選択的酸化反応"化学と工業. 51. 1790 (1998)

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      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 山下弘巳: "イオンビームを利用する酸チタン光触媒/活性炭素繊維系の創製"炭素. 185. 296-298 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Masaru. HARADA: "Preparation of Titanium Oxide Photocatalysts Loaded on Activated Carbon by an Lonized Cluster Beam Method and Their Photocatalytic for the Degradation of 2-Propanol Diluted in Water"Z. Phys. Chem.. (in press). (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Jinlong. Zhang: "Fluorescence Properties of 2,5-Bis(4-(diethlamino)phenyl)-1,3,4-oxadiazole Molecules Encapsulated in SiO2 and Si-Ti Binary Oxide Matrixes by the Sol-Gel Method"Langmuir. 15. 77-82 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Sinya. HIGASHIMOTO: "Investigation of the Local Structure of Vanadium Silicalite Catalyst(VS-1) Using XAFS. FT-IR and Photoluminescence Spectroscopic Methods"Jpn. J. Appl. Phys.. (in press). (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Masakazu ANPO: "Design and Cevelopment of Unique Titanium Oxide Photocatalysts Capable of Operating under Visible Light Irradiation by an Advanced Metal Ion-implantation Method"Stud. Surf. Sci. Catal. 121. 104-105 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Masakazu ANPO: "Generation of Superoxide Ions at Oxide Surfaces"Topics in Catal.. 8. 189-198 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Masakazu ANPO: "Characterization of the Local Structure of the Vanadium Silicalite (VS-2) Catalyst and Its Photocatalytic Reactivity for the Decomposition of NO into N2 and O2"J. Phys. Chem.. 103. 9295-9301 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Masakazu ANPO: "The Adsorption Activation of CO Molecules on ZrO2 Catalysts Having Low Coordinated Surface Sites"Res. Chem. Intermed.. 25. 1-12 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 安保 正一: "イオン注入による酸化チタン光触媒の可視光化"表面科学. 20. 60-65 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 安保 正一: "酸化チタンや酸化バナジウム種を含有するゼオライト光触媒の構築とその上でのNoxの光触媒分解反応"Eco Industry. 4. 11-19 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Hiromi YAMASHITA: "Characterization of Metal Ion-implanted Titanium Oxide Photocatalysts Operating under Visible Light Irradiation"J. Synchrotron Rad.. 6. 451-452 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Hiromi YAMASHITA: "Characterization and Photocatalytic Reactivities of Cr-Mesoporous Molecular Sieves"J. Synchrotron Rad.. 6. 453-454 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Hiromi YAMASHITA: "Photoluminescence Properties and Photocatalytic Reactivities of the Cr-and V-HMS Mesoporous Zeolite Catalysts"Proc. 12th Intern. Zeolite Conf.. 667-672 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] J. L. ZHANG: "Fluorescence Properties of 2,5-Bis(4-diethylamino)phenyl)-1,3,4-oxadiazole Molecules Encapsulated in SiO2 and Si-Ti Binary Oxide Matrices by the Sol-Gel Method"Langmuir. 15. 77-82 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Tsunehiro FUJII: "Effect of Transition Metals on the Photoinduced Proton Transfer from Anthrone to 9-Anthrol in Glasses Prepared by the Sol-el Method"J. Photochem. Photobio, A : Chem. 125. 58-91 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Akihiro FURUBE: "Charge Carrier Dynamics of Standard TiO2 Catalysts Revealed by Femtosecond Diffuse Reflectance Spedtroscopy"J. Phys . Chem.. 103. 3120-3127 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Keita IKEUE: "Photocatalytic Reduction of CO2 with H2O on Titanium Oxide Prepared within the FSM-16" Mesoporous Zeolites"Chem. Lett.. 1135-1136 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Masaru HARADA: "Preparation of Titanium Oxide Photocatalysts Loaded on Activated Carbon and their Photocatalytic Reactivity for the Degradation of 2-Propanol"Res. Chem. Intermed.. 25. 757-768 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Masaru HARADA: "Prepartion of Titanium Oxide Photocatalysts Loaded on Activated Carbon by an Ionized Cluster Beam Method and Their Photocatalytic Reactivities"Z. Phys. Chem.. 213. 59-65 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] D. R. PARK: "Photocatalytic Oxidation of Ethylene to CO2 anda H2O on Ultrafine Powdered TiO2 Photocatalysts in the Presenceof O2 and H2O"J. Catal.. 185. 114-119 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Shinya HIGASHIMOTO: "Investigation of the Local Structure of Vanadium Silicalite catalyst (VS-1) Using XAFS, FT-IR anda Photoluminescence Spectroscopic Methods"Jpn. J. Appl. Phys.. 38. 47-50 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 山下 弘巳: "酸化チタン光触媒の調製と環境浄化・太陽光利用への応用"ケミカルエンジニアリング. 18. 930-939 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Masakazu Anpo: "Protecting the Environment"Ed. BHR Group, England. 14 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 安保正一: "機能性材料化学"朝倉書店. 22 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 安保正一: "触媒化学基礎講座 「遷移金属酸化物触媒」"触媒学会関西地区編. 10 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 安保正一: "イオン注入による酸化チタン光触媒の可視光化 (表面科学)"日本表面科学会 (印刷中). (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 安保正一: "「表面・界面光化学反応の基礎」 季刊化学総説"学会出版センター. 11 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 山下弘巳: "「ゼオライト細孔内の光化学過程と光触媒反応」 季刊化学総説"学会出版センター. 10 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 安保正一: "可視光利用を目指した第二世代酸化チタン光触媒 (季刊化学総説)"学会出版センター (印刷中). (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Masakazu ANPO: "Advances in Catalysis"Applications of Photoluminescence Techniques to the Characterization of Solid Surfaces in Relation to Adsorption, Catalysis, and Photocatalysis. 50 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] H.Ymamshita, S.Kawasaki, M.Takeuchi, Y.Fujii, Y.Ichihashi, Y.Suzuki, S.E.Park, J.S.Chang, J.W.Yoo and M.Anpo: "Photocatalytic Reduction of CO2 with H2O on Ti/Si Binary Oxide Catalysts Prepared by the Sol-Gel Method"Stud.Surf.Sci.Catal.. 114. 561-564 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M.Anpo, H.Yamashita, Y.Fujii, Y.Ichihashi, S.G.Zhang, D.R.Park, S.Ehara, S.E.Park, J.S.Chang and J.W.Yoo: "Photocatalytic Reduction of CO2 with H2O on Titanium Oxide Anchored within Zeolites"Stud.Surf,Sci.Catal.. 114. 177-182 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] J.S.Chang, S.E.Park, M.S.Park, M.Anpo and H.Yamashita: "Oxidative Dehydrogenation of Ethylbenzene with Carbon Dioxide over ZSM-5-Supported Iron Oxide Catalysts"Stud.Surf.Sci.Catal.. 114. 387-390 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] S.E.Park, J.S.Chang, M.S. Park, M.Anpo and H.Yamashita: "CO2 Behavior on Supported KNiCa Catalyst in the Carbon Dioxide Reforming of Methane"Stud.Surf.Sci.Catal.. 114. 395-398 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M.Anpo, Y.Ichihashi, M.Takeuchi and H.Yamashita: "Design of Unique Titanium Oxide Photocatalysts by an Advanced Metal Ion-implantation Method and Photocatalytic Reactions under Visible Light Irradiation"Res.Chem.Intermed.. 24. 143-149 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] S.G Zhang, M.Ariyuki, S.Higashimoto, H.Yamashita and M.Anpo: "The Photoluminescence Property and Photocatalytic Reactivity of the V-HMS Mesoporous Zeolite : Pore Size Effect on the Photocatalytic Properties"Microporous Mater.. 621-627 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M.Anpo, M.Matsuoka, K.Hano, H.Mishima, H.Yamashita and H.Patterson: "The Relationship between the Local Structure of Copper (I) Ions on Cu+/Zeolite Catalysts and Their Photocatalytic Reactivities for the Decomposition of NOx into N2 and O2 at 275K"Coord,Chem,Rev.. 171. 175-184 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] H.Nishiguchi, S.Okamoto, M.Nishimura, H.Yamashita and M.Anpo: "Phosphorescence and Photochemical Properties of Benzophenone Included in Alkali Metal Cation-Exchanged ZSM-5 Zeolites"Res.Chem.Intermed.. 24. 849-858 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] H.Yamashita, S.Kawasaki, Y.Ichihashi, M.Harada, M.Takeuchi, M.Anpo, G.Stewart, M.A.Fox, C.Louis and M.Che: "Characterization of Titanium-Silicon Binary Oxide Catalysts Prepared by the Sol-Gel Method and Their Photocatalytic Reactivity for the Liquid Phase Oxidation of 1-Octanol"J.Phs.Chem.B. 102. 5870-5875 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] N.U.Zhanpeisov, M.Matsuoka, H.Mishima, H.Yamashita and M. Anpo: "Cluster Quantum Chemical ab Initio Study on the Interaction of NO Molecules with Highly Dispersed Titanium Oxides Incorporated into Silicalite and Zeolites"J.Phys.Chem.B. 102. 6915-6920 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] S.Dzwigaj, M.Matsuoka, R.Frank, M.Anpo and M.Che: "Probing Different Kinds of Vanadium Species in the VSib Zeolite by Diffuse Reflectance UV-Visible and Photoluminescence Spectroscopies"J.Phis.Chem.B. 102. 6309-6312 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] S.G.Zhang, S.Higashimoto, H.Yamashita and M.Anpo: "Characterization of V-oxide/ZSM-5 Zeolite Catalysts Prepared by the Solid-State Reaction and Their Photocatalytic Reactivity : In Situ Photoluminescence, XAFS, ESR, ET-IR, and UV-VIS Investigation"J.Phys.Chem. B. 102. 5590-5594 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] N.U.Zhanpeisov, M.Matsuoka, H.Mishima, H.Yamashita and M.Anpo: "Interaction of NO Molecules with a Copper-Containing Zeolite ; A Theoretical Ab Initio Study"J.Mol.Strct. (Theochem). 454. 201-207 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] H.Yamashita, M.Harada, Y.Ichihashi, M.Anpo, T.Hirao, N.Itoh and N.Iwamoto: "Preparation of Titanium Oxide Photocatalysts Anchored on Porous Silica Glass by a Metal Ion-Implantation Method and Their Photocatalytic Reactivities for the Degradation of 2-Propanol Diluted in Water"J.Phys.Chem.B. 102. 10707-10711 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] H.Yamashita, S.Kawasaki, Y.Ichihashi, M.Takeuchi, M.Harada and M.Anpo: "Characterization of Ti/Si Binary Oxides Prepared by the Sol-GelMethod and Their Photocatalytic Properties : The Hydrogenation and Hydrogenolysis of CH3CCH with H2O"Korean J.Chem.Eng.. 15. 491-495 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] S.C.Moon, H.Mametsuka, E.Suzuki and M.Anpo: "Stoichiometric Decomposition of Pure Water over Pt-Loaded Ti/B Binary Oxide under UV-Irradiation"Chem.Lett.. 117-118 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] W.Cho, Y.Beak, D.R.Park, Y.C.Kim and M.Anpo: "The Conversion of Natural Gas to Higher Hydrocarbons Using a Microwave Plasma and Catalysis"Res.Chem.Intermed.. 24. 55-66 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M.Anpo, H.Yamashita, K.Ikeue, Y.Fujii, S.G.Zhang, Y.Ichihashi, D.R.Park, Y.Suzuki, K.Koyano and T.Tatsumi: "Photocatalytic Reduction of CO2 with H2O on Ti-MCM-41 and Ti-MCM-48 Mesoporous Zeolite Catalysts"Catal.Today. 44. 327-332 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] H.Yamashita, Y.Fujii, Y.Ichihashi, S.G.Zhang, K.Ikeue, D.R.Park, K.Koyano, T.Tatsumi and M.Anpo: "Selective Formation of CH3OH in the Photocatalytic Reduction of CO2 with H2O on Titanium Oxides Highly Dispersed within Zeolites and Mesoporous Molecular Sieves"Catal.Today. 45. 221-227 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] H.Mishima, K.Hashimoto, T.Ono and M.Anpo: "Selective Catalytic Reduction of NO with NH3 over Natural Zeolites and Its Application to Stationary Diesel Engine Exhaust"Appl.Catal.B-Environ.. 19. 119-126 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M.Anpo, Y.Ichihashi, M.Takeuchi and H.Yamashita: "Design and Development of Unique Titanium Oxide Photocatalysts Capable of Operating under Visible Light Irradiation by an Advanced Metal Ion-Implantation Method"Proc.3rd Tokyo Conf.on Adv.Catal.Sci.and Tech.. (Tokyo). 104-105 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M.Anpo, Y.Ichihashi, M.Takeuchi and H.Yamashita: "Design of Unique Titanium Oxide Photocatalysts by and Advanced Metal Ion-implantation Method And Photocatalytic Reactions under Visible Light Irradiation"Proc.Frontiers and Tasks of Catal.towards the Next Century. (Kyoto). 143-149 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] H.Yamashita, A.Tanaka, M.Nishimura, K.Koyano, T.Tatsumi and M.Anpo: "Photochemical Properties of Rhodamine-B Dye Molecules Included within Mesoporous Molecular Sieves"Proc.1st Intern.Symp.on Mesoporous Molecular Sieves. (Baltimore). 551-558 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M.Anpo, H.Yamashita and Y.Ichihashi: "Design and Development of Unique Titanium Oxide Photocatalysts to Operate under Visible Light Irradiation Using an Advanced Metal Ion-Implantation Method"Pros.1st NIMC Intern.Symp.on Photoreact.Control and Photofunctional Mater.. (Tsukuba, Japan). 145-151 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M.Matsuoka, S.Higashimoto and M.Anpo: "Investigation of the Local Structure of Vanadium Silicalite Catalysts and Their Photocatalytic Activities for NO Decomposition"Proc.of the 17th Intern.Conf.on Catal., the Taniguchi Foundation. (Kobe, Japan). 37-40 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M.Anpo: "Applications TiO2 Photocatalyst to Better Our Environment"Protecting the Environment, Ed.BHR Group, England. 75-88 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M.Anpo and S.C.Moon: "The Adsorption and Activation of CO Molecules on ZrO2 Catalysts Having Low Coordinated Surface Sites"Res.Chem.Intermed.. 25. 1-12 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M.Anpo, M.Che, B.Fubini, E.Garrone, E.Giamello and M.C.Paganini: "Generation of Superoxide Ions at Oxide Surfaces"Topics in Catal.. 8. 189-198 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T.Fujii, N.Tanaka, K.Kodaira, Y.Kawai, H.Yamashita and M.Anpo: "Effect of Transition Metals on the Photoinduced Proton Transfer from Anthrone to 9-Anthrol in Glasses Prepared by the Sol-Gel Method"J.Photochem.Photobio.A : Chem.. 125. 58-91 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] A.Furube, T.Asahi, H.Masuhara, H.Yamashita, M.Anpo: "Charge Carrier Dynamics of Standard TiO2 Catalysts Revealed by Femtosecond Diffuse Reflectance Spectroscopy"J.Phys.Chem.B. 103. 3120-3127 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] H.Yamashita, Y.Ichihashi, M.Takeuchi, S.Kishiguchi and M.Anpo: "Characterization of Metal Ion-implanted Titanium Oxide Photocatalysts Operating under Visible Light Irradiation"J.Synchrotron Rad.. 6. 451-452 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] H.Yamashita, M.Ariyuki, S.Higashimoto, S.G.Zhang, J.S.Chang, S.E.Park, J.M.Lee, Y.Matsumura and M.Anpo: "Characterization and Photocatalytic Reactivities of Cr-HMS Mesoporous Molecular Sieves"J.Synchrotron Rad.. 6. 453-454 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] S.Higashimoto, M.Matsuoka, H.Yamashita and M.Anpo: "Investigation of the Local Structure of Vanadium Silicalite Catalyst (VS-1) Using XAFS, FT-IR and Photoluminescence Spectroscopic Methods"Jpn.J.Appl.Phys.. 38-1. 47-50 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M.Anpo, S.G.Zhang, S.Higashimoto, M.Matsuoka, H.Yamashita, Y.Ichihashi, Y.Matsumura and Y.Souma: "Characterization of the Local Structure of the Vanadium Silicalite (VS-2) Catalyst and Its Photocatalytic Reactivity for the Decomposition of NO into N2 and O2"J.Phys.Chem.. 103. 9295-9301 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] K.Ikeue, H.Yamashita and M.Anpo: "Photocatalytic Reduction of CO2 with H2O on Titanium Oxide Prepared within the FSM-16 Mesoporous Zeolites"Chem.Lett.. 1135-1136 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M.Harada, M.Honda, H.Yamashita and M.Anpo: "Preparation of Titanium Oxide Photocatalysts Loaded on Activated Carbon and Ionized Cluster Beam Method and their Photocatalytic Reactivity for the Degradation of 2-Propanol Diluted in Water"Res.Chem.Intermed.. 25. 757-768 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M.Harada, A.Tanii, H.Yamashita and M.Anpo: "Preparation of Titanium Oxide Photocatalysts Loaded on Activated Carbon by an Ionized Cluster Beam Method and their Photocatalytic Reactivities for the Degradation of 2-Propanol Diluted in Water"Z.Phys.Chem.. 213. 59-65 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M.Anpo, Y.Ichihashi, M.Takeuchi and H.Yamashita: "Design and Development of Unique Titanium Oxide Photocatalysts Capable of Operating under Visible Light Irradiation by an Advanced Metal Ion-implantation Method"Science and Technology in Catalysis. 305-310 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] J.L.Zhang, M.Matsuoka, H.Yamashita and M.Anpo: "Fluorescence Properties of 2,5-Bis(4-(diethylamino)phenyl)-1,3,4-oxadiazole Molecules Encapsulated in SiO2 and Si-Ti Binary Oxide Matrices by the Sol-Gel Method"Langmuir. 15. 77-82 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] D.R.Park, J.L.Zhang, K.Ikeue, H.Yamashita and M.Anpo: "Photocatalytic Oxidation of Ethylene to CO2 and H2O on Ultrafine Powdered TiO2 Photocatalysts in the Presence of O2 and H20"J.Catal.. 185. 114-119 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M.Anpo, M.Takeuchi, S.Kishiguchi and H.Yamashita: "Preparation of Unique Titanium Oxide Photocatalysts Capable of Operating under Visible Light Irradiation by an Advanced Metal Ion-implantation Method"Hyoumenkagaku. 20. 60-65 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T.Takewaki, S.J.Hwang, H.Yamashita and M.E.Davis: "Synthesis of *BEA-Type Molecular Sieves Using Mesoporous Materials as Reagents"Microporous and Mesoporous Materials. 32. 265-278 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M.Anpo, S.Kishiguchi, K.Ikeue and M.Takeuchi: "Design and Development of Second-Generation Titanium Oxide Photocatalysis able to Operate Under Visible Light Irradiation by Applying an Advanced Metal Ion-Implantation Method"Proc.7th Korea-Japan Symp.on Catal.. (Kwangju). 18-19 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] N.U.Zhanpeisov, H.Yamashita, H.Mishima, M.Matsuoka and M.Anpo: "Interaction of NO Molecules with Highly Dispersed Titanium Oxides Incorporated into Silicalite and Zeolite Cavities : A Theoretical Ab Initio Study"Proc.12th Intern.Zeolite Conf.. (Baltimore). 473-480 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] H.Yamashita, M.Ariyuki, S.Higashimoto, M.Anpo, J.S.Chang, S.E.Park and J.M.Lee: "Photoluminescence Properties and Photocatalytic Reactivities of the Cr- and V-HMS Mesoporous Zeolite Catalysts"Proc.12th Intern.Zeolite Conf.. (Baltimore). 667-672 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M.Anpo, M.Takeuchi, H.Yamashita, T.Hirao, N.Itoh and N.Iwamoto: "The Design and Development of TiO2 Thin Film Photocatalysts which Work under Visible Light Irradiation by the Application of Ion Engineering Techniques"Proc.4th Intern.Conf.on Ecomater.. (Gifu). 333-336 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] J.Zhang, M.Matsuoka, H.Yamashita and M.Anpo: "Characteristic Properties of the Fluorescence Spectra of 2,5-Bis(4-(diethylamino)phenyl)-1,3,4-oxadiazole Molecules Doped SiO2 and Si/Ti Binary Oxide Matrices by the Sol-Gel Method"The Fourth International Symposium on Functional Dyes. 107(Osaka). (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] M.Anpo: "Applications of Photoluminescence Techniques to the Characterization of Solid Surfaces in Relation to Adsorption, Catalysis, and Photocatalysis"Advances in Catalysis, eds, W.O.Haag, B.C.Gates and H.Knozinger (Academic Press) London. 44. 119-257 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Masakazu ANPO: "Design and Development of Unique Titanium Oxide Photocatalysts Capable of Operating under Visible Light Irradiation by an Advanced Metal Ion-implantation Method"Stud. Surf. Sci. Catal.. 121. 104-105 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Masakazu ANPO: "Generation of Superoxide Ions at Oxide Surfaces"Topics in Catal.. 8. 189-198 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Masakazu ANPO: "Characterization of the Local Structure of the Vanadium Silicalite (VS-2) Catalyst and Its Photocatalytic Reactivity for the Decomposition of NO into N2 and O2"J. Phys. Chem.. 103. 9295-9301 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Masakazu ANPO: "The Adsorption and Activation of CO Molecules on ZrO2 Catalysts Having Low Coordinated Surface Sites"Res. Chem. Intermed.. 25. 1-12 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 安保 正一: "イオン注入による酸化チタン光触媒の可視光化"表面科学. 20. 60-65 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 安保 正一: "酸化チタンや酸化バナジウム種を含有するゼオライト光触媒の構築とその上でのNOxの光触媒分解反応"Eco Industry. 4. 11-19 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Hiromi YAMASHITA: "Characterization of Metal Ion-implanted Titanium Oxide Photocatalysts Operating under Visible Light Irradiation"J. Synchrotron Rad.. 6. 451-452 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Hiromi YAMASHITA: "Characterization and Photocatalytic Reactivities of Cr-HMS Mesoporous Molecular Sieves"J. Synchrotron Rad.. 6. 453-454 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Hiromi YAMASHITA: "Photoluminescence Properties and Photocatalytic Reactivities of the Cr- and V-HMS Mesoporous Zeolite Catalysts"Proc. 12th Intern. Zeolite Conf.. 667-672 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] J. L. ZHANG: "Fluorescence Properties of 2, 5-Bis(4-(diethylamino)phenyl)-1, 3, 4-oxadiazole Molecules Encapsulated in SiO2 and Si-Ti Binary Oxide Matrices by the Sol-Gel Method"Langmuir. 15. 77-82 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Tsunehiro FUJII: "Effect of Metals on the Photoinduced Proton Transfer from Anthrone to 9-Anthrol in Glasses Prepared by the Sol-Gel Method"J. Photochem Photobio. A: Chem. 125. 58-91 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Akihiro FURUBE: "Charge Carrier Dynamics of Standard TiO2 Catalysts Revealed by Femtosecond Diffuse Reflectance Spectroscopy"J. Phys. Chem.. 103. 3120-3127 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Keita IKEUE: "Photocatalytic Reduction of CO2 with H2O on Titanium Oxide Prepared within the FSM-16" Mesoporous Zeolites"Chem. Lett.. 1135-1136 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Masaru HARADA: "Preparation of Titanium Oxide Photocatalysts Loaded on Activated Carbon and their Photocatalytic Reactivity for the Degradation of 2-Propanol"Res. Chem. Intermed.. 25. 757-768 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Masaru HARADA: "Preparation of Titanium Oxide Photocatalysts Loaded on Activated Carbon by an Ionized Cluster Beam Method and their Photocatalytic Reactivities"Z. Phys. Chem.. 213. 59-65 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] D. R. PARK: "Photocatalytic Oxidation of Ethylene to CO2 and H2O on Ultrafine Powdered TiO2 Photocatalysts in the Presence of O2 and H2O"J. Catal.. 185. 114-119 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Shinya HIGASHIMOTO: "Investigation of the Local Structure of Vanadium Silicalite Catalyst (VS-1) Using XAFS, FT-IR and Photoluminescence Spectroscopic Methods"Jpn. J. Appl. Phys.. 38. 47-50 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 山下 弘巳: "酸化チタン光触媒の調製と環境浄化・太陽光利用への応用"ケミカルエンジニアリング. 18. 930-939 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Masakazu ANPO: "Advances in Catalysis"Applications of Photoluminescence Techniques to the Characterization of Solid Surfaces in Relation to Adsorption, Catalysis, and Photocatalysis. 138 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Sang.Chul.MOON: "Stoichiometric Decomposition of Pure Water over Pt-Loaded Ti/B Binary Oxide under UV-Irradiation" CHem.Lett.117-118 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Hiromi YAMASHITA: "Photocatalytic Reduction of CO2 with H2O on Ti/Si Binary Oxide Catalysis Prepared by the Sol-Gel Method" Stud.Surf.Sci.Catal.114. 561-564 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Masakazu ANPO: "Photocatalyic Reduction of CO2 with H2O on Titanium Oxide Anchored within Zeolites" Stud.Surf.Sci.Catal.114. 177-182 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Masakazu ANPO: "Design of Unique Titanium Oxide Photocatalysts by an Advanced Metal Ion-implantation Method and Photocatalyic Reactions under Visble Light Irradiation" Res.Chem.Intermed.24. 143-149 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Shu.Guo.Zhang: "The Photoluninescence Property and Photocatalytic Reactivity of the V-HMS Mesoporous Zeolite : Pore Size Effect on the Photocatalyic Properties" Microporous Mater.621-627 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Masakazu ANPO: "The Relationship between the Local Structure of Copper (1) Ions on Cu+/Zeolite Catalysts and Their Photocatalyic Reactivities for the Decomposition of NOx into N2 and O2 at 27.5K" Coord.Chem.Rev.171. 175-184 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Hiroyasu NISHIGUCHI: "Phosphorescence and Photochemical Properties of Benzophenone Included in Alkali Metal Cation-Exchanged ZSM-5 Zeolies" Res.Chem.Intermed. 24. 849-858 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Hiromi YAMASHITA: "Characterization of Titanium-Silicon Binary Oxide Catalysts Prepared by the Sol-Gel Method and Thier Photocatalytic Reactivity for the Liquid Phase Oxidation of 1-Octanol" J.Phys.Chem.B. 102. 5870-5875 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] N.U.Zhanpeisov: "Cluster Quantum Chemical ab Initio Study on the Interaction of NO Molecules with Highly Dispersed Titanium Oxides Incorporated into Silicalite and Zeolites" J.Phys.Chem.B. 102. 6915-6920 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Stanislaw DZWIGAL: "Probing Different Kinds of Vandium Species in the VSib Zeolite by Diffuse Refiectance UV-Visible and Phoioluminescence Spectroscopics" J.Phys.Chem.B. 102. 6309-6312 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Shu.Guo.Zhang: "Characterization of V-oxide/ZSM-5 Zeolite Catalysts Prepared by the Solid-State Reaction and Their Photocatalyic Reactivity : In Situ Photoluminescence, XAFS, ESR, FT-IR, and UV-VIS Investigation" J.Phys.Chem.B. 102. 5590-5594 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] N.U.Zhanperisov: "Interaction of NO Molecules with a Copper-Containing Zeolite ; A Theoretical Ab Initio Study" J.Mol.Struct.(Theochem). 454. 201-207 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Hiromi YAMASHITA: "Proparation of Tianium Oxide Photocatalysts Anchored or porous Silica Glass by a Metal Ion-Implantation Method and Their Photocatalytic Reactivites for the Degradation of 2-Propanol Diluted in Water" J.Phys.Chem.B. 102. 10707-10711 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Hiromi YAMASHITA: "Characterization of Ti/Si Binary Oxides Prepared by the Sol-Gel Method and Their Photocatalytic Properties : The Hydrogenation and Hydrogenolysis of CH3CCH with H2O" Korean J.Chem.Eng.15. 491-495 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Masakazu ANPO: "Photocatalytic Reduction of CO2 with H2O on Ti-MCM-41 and Ti-MCM-48 Mesoporous Zeolite Catalysts" Catal.Today. 44. 327-332 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Hiromi YAMASHITA: "Selective Formation of CH3OH in the Photocatalytic Reduction of CO2 with H2O on Titanium Oxides Highly Dispersed within Zeolites and Mesoporous Molecular Sieves" Catal.Today. 45. 221-227 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 原田 賢: "クラスターイオンビーム法による酸化チタン光触媒の調整とその液相触媒反応活性" 触媒. 40. 221-227 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Hiromi YAMASHITA: "Selective Catalytic Reduction of NO with NH3 over Natural Zeolites and Its Application to Stationary Diesel Engine Exhaust" Appl.Catal.B-Environ.19. 119-126 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 安保正一: "光触媒と環境浄化" クリーン関西. 87. 15-23 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 松岡雅也: "可視光照射下でのゼオライト細孔内における炭化水素の選択的酸化反応" 化学と工業. 51. 1790 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 山下弘巳: "イオンビームを利用する酸化チタン光触媒/活性炭素繊維系の創製" 炭素. 185. 296-298 (1998)

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      1998 Annual Research Report
  • [Publications] Masaru.HARADA: "Preparation of Titanium Oxide Photocatalysts Loaded on Acivated Carbon by an Ionized Cluster Beam Method and Their Photocatalytic Reactivites for the Degradation of 2-Propanol Dilued in Water" Z.Phys.Chem.(In press). (1998)

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      1998 Annual Research Report
  • [Publications] Jinlong.Zhand: "Fluorescence Propertes of 2,5-Bis(4-(diethylamino)phenyl)-1,3,4-oxadiazolc Molecules Encapsulated in SiO2 and Si-Ti Binary Oxide Matrixes by the Sol-Gel Method" Langmuir. 15. 77-82 (1998)

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      1998 Annual Research Report
  • [Publications] Sinya.HIGASHIMOTO: "Investigation of the Local Structure of Vanadium Silicalite Catalyst (VS-1) Using XAPS, FT-IR and Photoluminescence Spectroscopic Methods" Jpn.J.Appl.Phys.(In press). (1998)

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      1998 Annual Research Report
  • [Publications] Masakazu Anpo: "Protecting the Environment" Ed.BHR Group, England, 14 (1998)

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      1998 Annual Research Report
  • [Publications] 安保正一: "機能性材料化学" 朝倉書店, 22 (1998)

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      1998 Annual Research Report
  • [Publications] 安保正一: "「表面・界面光化学反応の基礎」季刊化学総説" 学会出版センター, 11 (1998)

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      1998 Annual Research Report
  • [Publications] 山下弘巳: "「ゼオライト細孔内の光化学過程と光触媒反応」季刊化学総説" 学会出版センター, 10 (1998)

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      1998 Annual Research Report
  • [Publications] 安保正一: "触媒化学基礎講座" 触媒学会関西地区編, 10 (1998)

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      1998 Annual Research Report
  • [Publications] 安保正一: "イオン注入による酸化チタン光触媒の可視光化(表面科学)(印刷中)" 日本表面科学会, (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 安保正一: "可視光利用を目指した第二世代酸化チタン光触媒(季刊化学総説)(印刷中)" 学会出版センター, (1998)

    • Related Report
      1998 Annual Research Report

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Published: 1998-04-01   Modified: 2021-09-01  

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