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Metal-assembled Complexes -Chemisty Based on Inorganic-Organic Hybrid Electronic Structures-

Research Project

Project/Area Number 10149101
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionTohoku University

Principal Investigator

ITO Tasuku  Tohoku University, Graduate School of Science, Department of Chemistry, Professor, 大学院・理学研究科, 教授 (90007328)

Co-Investigator(Kenkyū-buntansha) YAMAGUCHI Kizashi  Osaka University, Graduate School of Science, Departmen of Chemistry, Professor, 大学院・理学研究科, 教授 (80029537)
YAMAMOTO Takakazu  Tokyo Institute of Technology, Research Laboratory of Resources Utilization, Professor, 資源化学研究所, 教授 (10016743)
OKAWA Hisashi  Kyusyu University, Faculty of Science, Deparment of Chemistry, Professor, 大学院・理学研究院, 教授 (00037219)
KITAGAWA Susumu  Kyoto University, Department of Synthetic Chemistry and Biochemistry, Professor, 大学院・工学研究科, 教授 (20140303)
KATO Reizo  The Institute of Physical and Chemical Research, Chief Scientist, Head, 主任研究員 (80169531)
Project Period (FY) 1998 – 2002
Project Status Completed (Fiscal Year 2002)
Budget Amount *help
¥226,100,000 (Direct Cost: ¥226,100,000)
Fiscal Year 2002: ¥3,000,000 (Direct Cost: ¥3,000,000)
Fiscal Year 2001: ¥32,000,000 (Direct Cost: ¥32,000,000)
Fiscal Year 2000: ¥15,300,000 (Direct Cost: ¥15,300,000)
Fiscal Year 1999: ¥45,800,000 (Direct Cost: ¥45,800,000)
Fiscal Year 1998: ¥130,000,000 (Direct Cost: ¥130,000,000)
Keywordspolynuclear complexes / cluster complexes / mixed valence / molecular magnet / porous solid / supramolecular complex / molecular conductor / metal complex assemblage / 金属クラスター錯体
Research Abstract

The purpose of this priority area was to design, through rational methods and supported by theoretical studies, metal-assembled complexes and important next generation materials with phenomena typical of metal complexes induced by light, charge or spin. The project was carried out by as many as 119 members over a period of four years. Some of the remarkable results are mentioned below.
1. Creation of novel compounds which show interesting properties and functionalities : a) Molecular magnets including a ferrimagnet which has the highest critical temperature (T_c = 71 K) among the structurally determined complexes and a tetrairon(II) cubane complex which acts as a single molecule magnet ; b) Functionalized complexes such as a 3D porpous solid which can absorb a higher amount of methane gas than zeolites and a halide-bridged pseudo 1D chain complexes exhibiting third order nonlinear optical properties ; c) Supramolecular complexes including a nano-sized platinum chain complex of which the … More association and dissociation reactions are controllable by solvent and temperature ; d) Molecular based conductors including the first known single-component molecular superconductors and metal complexes having both ferromagnetism and metal-based conductivity.
2. Discovery of novel phenomena : a) Determination of the rate of rapid electron transfer from observed peak coalescence in the infrared spectrum of a metal complex ; b) Various photo-induced phase transition phenomena including a photo-induced spin transition and a photo-induced charge transition ; c) Determination of a new type of phase transision induced by charge transfer.
3. Development of metal-assembling methods and multi-functionalization : a) Functionalization of metal complexes in a mixed valence state via photon or proton response ; b) Assembly of metal complexes on the surface of solids and nano-particles, or on an interface.
4. Theoretical calculation : Development of a novel hybrid DFT (HDFT) method which is effective for theoretical calculations involving metal complexes. Less

Report

(6 results)
  • 2002 Annual Research Report   Final Research Report Summary
  • 2001 Annual Research Report
  • 2000 Annual Research Report
  • 1999 Annual Research Report
  • 1998 Annual Research Report
  • Research Products

    (120 results)

All Other

All Publications (120 results)

  • [Publications] 伊藤 翼: "A Helical Metal-Metal Bonded Chain via the Pt→Ag Dative Bond"J. Am. Chem. Soc.. 123. 743-744 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] 大川尚士: "[Mn(en)]_3[Cr(CN)_6}_2・4H_2O : A Three-dimensional Dimetallic Ferrimagnet (Tc=69 K) sith A Defective Cubane Unit"Angew. Chem. Int. Ed.. 38. 1795-1798 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] 山本隆一: "Molecylar Alignment of Head-to-Rail-Type Poly(3-hexylthiophene-2,5-diyl) and Related Polymers and Compounds on Substrates"J. Polym. Sci. Part B : Polym. Phys.. 39. 1713-1718 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] 山口 兆: "Theoretical Studies of Magnetic Interactions in Mn(II)(hfac)_2{di(4-pyridyl)phenylcarbene} and Cu(II)(hfac)_2{di(4-pyridyl)phenylcarbene}"J. Am. Chem. Soc.. 124. 450-461 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] 加藤礼三: "Synthesis and Properties of Novel Donor-Tupe Metal-Dithiolene Complexes Based on 5,6-dithydro-1,4-dioxin-2,3-dithiol(edo) Ligand"J. Mater. Chem.. 11. 2131-2141 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] 北川 進: "Formation of a One-Dimensional Array of Oxygen in a Microporous Metal-Organic Solid"Science. 298. 2358-2361 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] T. Yamaguchi, F. Yamazaki, and T. Ito: "A Helical Metal-Metal Bonded Chain via the Pt →Ag Dative Bond"J. Am. Chem. Soc.. 123. 743-744 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] M. Ohba, N. Usuki, N. Fukita, and H. Okawa: "[Mn(en)]_3[Cr(CN)_6]_2・4H_2O : A Three-dimensional Dimetallic Ferrimagnet (Tc=69 K) sith A Defective Cubane Unit"Angew. Chem. Inst. Ed.. 38. 1795-1798 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] T. Yamamoto, H. Kokubo, and T. Morilita: "Molecylar Alignment of Head-to-Rail-Type Poly(3-hexylthiophene-2,5-diyl) and Related Polymers and Compounds on Substrates"J. Polym. Sci. Part B : Polym. Phys.. 39. 1713-1718 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Y. Takano, Y. Kitagawa, T. Onishi, Y .Yoshioka, K. Yamaguchi, N. Koga, and H. Iwamura: "Theoretical Studies of Magnetic Interactions in Mn(II)(hfac)_2{di(4-pyridyl)phenylcarbene} and Cu(II)(hfac)_2{di(4-pyridyl)phenylcarbene}"J. Am. Chem. Soc.. 124. 450-461 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] E. Watanabe, M. Fujiwara, J. Yamamura, and R. Kato: "Synthesis and Properties of Novel Donor-Tupe Metal-Dithiolene Complexes Based on 5,6-dithydro-1,4- dioxin-2,3-dithiol(edo) Ligand"J. Mater. Chem.. 11. 2131-2141 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] R Kitaura, S. Kitagawa. Y. Kubota, T. C. Kobayashi, K. Kindo, Y. Mita, A. Matsuo, M. Kobayashi, H. -C. Chang, T. C. Ozawa, M. Suzuki, M. Sakata, and M. Takata: "Formation of a One-Dimensional Array of Oxygen in a Microporous Metal-Organic Solid"Science. 298. 2358-2361 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] 伊藤 翼: "Zinc(II) Slides on a Ligand Surface : The X-ray Structure and Dynamic Behavior in Solution of [Zn(H2L)(tacn)]"Angew.Chem.Int.Ed.. 41. 2076-2078 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] 伊藤 翼: "Synthesis, Structure, and Ferromagnetic Behavior of Decacopper(II) Cluster Complex Supported by Hexaanionic p-tert-butylthiacalix[6]arene"J.Am.Chem.Soc.. 124. 11274-11275 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] 伊藤 翼: "High-Spin Wheel of a Heptanuclear Mixed-Valent Fe^<II,III> Complex"Angew.Chem.Int.Ed.. 42. 223-225 (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] 大川 尚士: "Structures and Magnetism of Cyanide-bridged Bimetallic Compounds : Design of Complex-based Magnetic Materials"Bull.Chem.Soc.Jpn.. 75. 1191-1203 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] 加藤 礼三: "Unique Structural and Physical Properties of Ni(dmit)_2 Anion Salts Characterized by Short Te…S Contacts, where dmit= 1,3-dithiole-2-thione-4,5-dithiolate"J.Chem.Soc.Dalton Trans.. 3763-3770 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] 北川 進: "Framework Engineering by Anion and Porous Functionalities of Cu(II)/4,4'-bpy Coordination Polymers"J.Am.Chem.Soc.. 124. 2568-2583 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] 伊藤翼: "Zinc(II) Slides on a Ligand Surface : The X-ray Structure and Dynamic Behavior in Solution of [Zn(H_2L)(tacn)]"Angew.Chem.Int.Ed.. 41(印刷中). (2002)

    • Related Report
      2001 Annual Research Report
  • [Publications] 伊藤翼: "Syntheses, Structures, and Propeties of Trinuclear Complexes [M(bpca)_2(M'(hfac)_2}_2], Constructed with the Complexed Bridging Ligand [M(bpca)_2] (M, M' = Ni(II), Mn(II) ; Cu(II), Mn(II) ; Fe(II), Mn(II) ; Ni(II), Fe(II) ; and Fe(II), Fe(II) ; Hbpca = Bis(2-pyridylcarbonyl)amine, Hhfac = Hexafluoroacetylacetone]"Inorg.Chem.. 41. 507-512 (2002)

    • Related Report
      2001 Annual Research Report
  • [Publications] 伊藤翼: "A Helical Metal-Metal Bonded Chain via the Pt → Ag Dative Bond"J.Am.Chem.Soc.. 123. 743-744 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] 伊藤翼: "Comproportionation Reaction and Hindered Rotation of Coordinated Pyridine Ring in Acetate Bridged Tetraplatinum(II) Cluster Having Pyridine Derivative Ligands in the Cluster Plane"Chem.Eur.J.. (印刷中). (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] 伊藤翼: "Tetra-and Trinuclear Platinum(II) Cluster Complexes"Adv.Inorg.Chem.. 52. 205-248 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] 伊藤翼: "Experimental and Theoretical Studies on Ferromagnetically Coupled Metal Complexes with Imino Nitroxides"Inorg.Chem.. 40. 5518-5525 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] 大川尚士: "Trinuclear Cu^<II>Mn^<II>Cu^<II> Complex of An Oxamide/Dioxime Ligand and Extension to a Bimetallic Magnetic Compound"J.Chem.Soc., Dalton Trans.. 2001. 64-70 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] 大川尚士: "Tetranuclear Mixed-Metal Cu^<II>_2M^<II>_2 Complexes Derived from a Phenol-based Macrocyclic Ligand Having tow N(amine)_2O_2 and N(imine)_2O_2 Metal-Binding Sites"Inorg.Chem.. 40. 3739-3744 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] 大川尚士: "Synthesis, Charaterization and Activation of Thermally Stable μ-12-Peroxodiiron(III) Complex"Inogr.Chem.. 40. 4821-4822 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] 大川尚士: "Three-Dimensional Bimetallic Ferromagnets (Mn(L)]_3[Cr(CN)_6]_2-nH_2O (L=en, N=4 ; L=glya, n=2.5) and Relevance to a Prussian Blue Analogue Mn_3[Cr(CN)_6]_2 -12H_2O"J.Solid State Chem.. 159. 328-335 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] 山本隆一: "Cationic Arylpalladium Complexes with Chelating diamine Ligands, [PdAr(N-N)(solv)] BF4(N-N = N, N, N', N'-tetrametthylethylenediamine, 22'-bipyridine, 4, 4' -dimethyl'2.2'-bipyridine). Preparation, Intermolecular Coupling of the Aryl Ligands, and Insertion of Alkyne and Allen into the Pd-C bond"Organometallics. 20. 1087-1101 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] 山本隆一: "Piezochromic Behavior of Regioregular Poly(3-hexylthiophene-2, 5-diyl) and Poly(5, 8-dihexadecyloxyanthraquinone-1, 4-diyl)"Polymer. 42. 6673-6675 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] 山本隆一: "Organometallic Syntheses of Head-tohead Poly(3-hexylthiophene) and a Related Polymer with a Spacinf Non-subsituted Thiophene Unit. Colloidal Solution of the Polymers"Macromol.Chem.Phys.. 202. 1031-1034 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] 山本隆一: "Molecylar Alignment of Head-to-Rail-Type Poly(3-hexylthiophene-2, 5 -diyl) and Related Polymers and Compounds on Substrates"J.Polym.Sci.Part B : Polym.Phys.. 39. 1713-1718 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] 山口兆: "Theoretical Studies of Magnetic Interactions in Mn(II)(hfac)_2{di(4-pyridyl)phenylcarbene } and Cu(II)(hfac)_2 { di(4-pyridyl)phenylcarbene }"J.Am.Chem.Soc.. 124. 450-461 (2002)

    • Related Report
      2001 Annual Research Report
  • [Publications] 山口兆: "Third-order Nonlinear Optical Properties of Fractal-and Nonfractal-structures Oligomers Modeled after Dendron Parts in Cayley-tree-type Dendrimers"J.Chem.Phys.. 115. 6780-6784 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] 山口兆: "Theoretical Study of the Magnetic Interaction for M-O-N Type Metal oxides. Comparison of Broken-Symmetry Approaches"Polyhedorn. 20. 1177-1184 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] 山口兆: "Size-dependency of Polarizabilities of Fractal-and Nonfractal-structured Oligomers Modeled after Dendron Parts in Cayley-tree-type Dendrimers"J.Chem.Phys.. 115. 1052-1059 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] 加藤礼三: "Development of Molecular Conductors Derived from Metal Dithiolene Complexes"Synth.Met.. 120. 675-678 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] 加藤礼三: "Synthesis and Properties of Novel Donor-Tupe Metal-Dithiolene Complexes Based on 5, 6-dithydro-1, 4-dioxin-2, 3-dithiol(edo) Ligand"J.Mater.Chem.. 11. 2131-2141 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] 北川進: "New Molecular Assemblies of Redox Isomers, [Cr^<III>(X_4SQ)_<3-n>(X_4Cat)_n]^<-n> X-ray Crystal Structuers and Physical Properties"Inorg.Chem.. 40. 146-156 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] 北川進: "A New Class of Cyclic Hexmer : [Co_6L_6]^<24->(H_6L = hexaazatriphenylene hexacarboxylic acid)"Angew.Chem.Int.Ed.. 40. 3817-3819 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] 北川進: "Unprecedented Mixed^Charged State in a Supramolecular Assembly of Ligand-based Mixed-valence Redox Isomers"Angew.Chem.Int.Ed.. 41(印刷中). (2002)

    • Related Report
      2001 Annual Research Report
  • [Publications] 北川進: "Novel Pillared-Layer Coordination Polymer Network with Hysteretic Sorption"Angew.Chem.Int.Ed.. 41(印刷中). (2002)

    • Related Report
      2001 Annual Research Report
  • [Publications] 伊藤翼: "Unusual Redox State Dependent Fermi Resonances in the Infrared Spectra of Trinuclear Ruthenium Clusters with Isocyanide Ligands"Inorg.Chem.. 39. 2696-2698 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 伊藤翼: "A Strongly Coupled Mixed Valence State between Ru_3 Clusters. Intramolecular Electron Transfer on the Infrared Vibrational Time Scale in a Pyrazine (pz) Bridged dimer of Triruthenium Clusters, [{Ru_3 (μ-O)(μ-CH_3CO_2)_6(CO)(abco)}_2(μ-pz)](abco=1-azabicyclo[2,2,2]octane"Bull.Chem.Soc.Jpn.. 73. 1205-1212 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 伊藤翼: "Mixed-Valent Heptairon Complex with a Ground-State Spin of S=12/2 Constructed from a Triiron Cluster Ligand"Angew.Chem.Int.Ed.. 39. 230-233 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 伊藤翼: "Superparamagnetic Behavior in an Alkoxo-Bridged Iron (II) Cube"J.Am.Chem.Soc.. 122. 12602-12603 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 伊藤翼: "Rational Construction of Chiral Octanuclear Metallacycles Consisting of Octahedral Co^<III>, Square-Planar Pd^<II>, and Linear Au^I or Ag^I Ions"Angew.Chem.Int.Ed.. 39. 4098-40101 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 伊藤翼: "A Helical Metal-Metal Bonded Chain via the Pt→Ag Dative Bond"J.Am.Chem.Soc.. 123. 743 (2001)

    • Related Report
      2000 Annual Research Report
  • [Publications] 大川尚士: "A Mixed-metal Cu^<II>_2Ni^<II>_2 Complex Derived from A Phenol-based Heterotetranucleating Macrocyclic Ligand"Chem.Commun.. 4. 817-818 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 大川尚士: "Bimetallic Dioxygen Complexes Derived from 'End-off' Compartmental Ligands"Coord.Chem.Rev.. 105-129 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 大川尚士: "Bimetallic Dioxygen Complexes Derived from 'End-off' Compartmental Ligands"Coord.Chem.Rev.. 200-202 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 大川尚士: "A Heterodinuclear Co^<II>Cu^I Complex with 'Co (salen)' in A Macrocyclic Framework. Oxygenation Studies in Comparison with Analogous Cu^<II>Cu^I and Co^<II>Pb^<II> Complexes"Inorg.Chem.. 39. 4520-4526 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 大川尚士: "Trinuclear Cu^<II>M^<II>Cu^<II> Complexes of an Oxamide/Dioxime Ligand and Extension to A Bimetallic Magnetic Compound"J.Chem.Soc., Dalton Trans.. 1. 64-70 (2001)

    • Related Report
      2000 Annual Research Report
  • [Publications] 大川尚士: "Dinuclear Zinc Complexes of Phenol-based 'End-off' Compartmental Ligands : Synthesis, Structures and Phosphatase-Like Activity"Bull.Chem.Soc.Jpn.. 74. 85-95 (2001)

    • Related Report
      2000 Annual Research Report
  • [Publications] 山本隆一: "New Information on Linear and Stiff π-Conjugated Poly (pyridine-2,5-diyl)"J.Polym.Sci. : B,Polym.Phys.. 38. 1348-1351 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 山本隆一: "π-Conjugated Polymers Prepared by Organometallic Polycondensation and Metal Complexes of the Polymers"Polym.Adv.Tech.. 11. 658-664 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 山本隆一: "Synthesis and Properties of Europium Complex of Poybenzimidazole Containing N-Eu Bond"Mol.Cryst.Liq.Cryst.. 342. 57-62 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 山本隆一: "Poly (pyridine-2,5-diyl)-CuCl_2 Catalyst for Synthesis of Dimethyl Carbonate by Oxidative Carbonylation of Methanol : Catalytic Activity and Corrosion Influence"J.Catalysis. 65. 123-126 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 山本隆一: "Synthesis and Chemical Properties of π-Conjugated Zinc Porphyrin Polymers with Arylene and Aryleneethynylene Groups between Zinc Porphyrin Units"Macromolecules. 33. 5688-5994 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 山口兆: "Quantum-phase and Information-entropy Dynamics of a Two-state Molecular System Interacting with Strongly Amplitude- and Phase- squeezed Fields"J.Chem.Phys.. 112. 2769-2780 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 山口兆: "Density Functional Study of Intramolecular Ferromagnetic Interaction Through μ-Phenylene Coupling Unit (II) : Examination of Functional Dependence"J.Chem.Phys.. 113. 10486-10504 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 山口兆: "Quantum Spin Dynamics by Path Integral Centroid Molecular Dynamics Method"Prog.Theoret.Phys.Suppl.. 138. 533-534 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 山口兆: "Ab initio Computations of Effective Exchange Integrals for H-H, H-He-H and Mn_2O_2 Complex. Comparison of Broken-Symmetry Approaches"Chem.Phys.Lett.. 319. 223-230 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 山口兆: "Theoretical Studies on Superconducting and Other Phases : Triplet Superconductivity, Ferromagnetism and Ferromagnetic Metals"Int.J.Quant.Chem.. 80. 721-732 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 加藤礼三: "N, N'-Dicyanobenzoquinonediimines (DCNQIs) : Structural and Physical Properties"Bull.Chem.Soc.Jpn.. 73. 515-534 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 加藤礼三: "Thermodynamical Study of (DMe-DCNQI) 2Cu System -Mechanism of Reentrant Metal-Insulator Transition-"J.Phys.Soc.Jpn.. 69. 1414-1422 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 加藤礼三: "Design, Preparation, and Characterzation of Novel ET Salts with Supramolecular Assembly -Sheet and Chain Structures Based on Difluorotetraiodobenzene-"Chem.Lett.. 8. 970-971 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 加藤礼三: "Magnetic Susceptibility of (DMe-DCNQI)_2Li_<1-x>CUx,"Solid State Communications. 114. 281-284 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 加藤礼三: "Conducting Properties of Assembled Metal Complexes"Mol.Cryst.Liq.Cryst.. 343. 1-8 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 北川進: "Allosteric Chirality Amplification in Zinc Bilinone Dimer"J.Am.Chem.Soc.. 122. 748-749 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 北川進: "New Methane Adsorbent of Porous Coordination Polymer,[Cu(SiF_6)(4,4'-bipyridine)_2]^n"Angew.Che, Int.Ed.Engl.. 39. 2081-2084 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 北川進: "Synthesis and Molecular Structure of the Amido-bridged Dinuclear rhodium Complex [Cp^*Rh{μ_2-(NH)_2C_<10>H_6-2,3}(μ_2-Cl)RhCp^*](Cp^*=η_5-C_5Me_5)"Mol.Cryst.Liq.Cryst.. 342. 1-6 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 北川進: "Novel Layered Structures Constructed from Metal (II)-Chloranilate Monomer Compounds"J.Chem.Soc.Dalton Trans.. 2409-2417 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 北川進: "New Molecular Assemblies of Redox Isomers,[CrIII (X4SQ)3-n(X4Cat)n]-n(X) Cl and Br, n)0,1, and 2), with Metallocenium Cations,[MIII Cp2]+(M) Co and Fe) : X-ray Crystal Structures and Physical Properties"Inorg.Chem. 40. 146-156 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 大川 尚士: "Teracopperassemblry Complexes Comprised of One Dimetallic and Two Monometallic Auxiliaries : Intramolecular Electron-Transfer Relevant to Multicopper Oxidases"Inorg. Chem.. 38. 1825-1830 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 大川 尚士: "Template Syntheses and Properties of Copper(II)-Lanthanide(III)Complexes of Phenol-Based Symmetric and Unsymmetric Dinucleating Macrocycles"Inorg. Chem.. 48. 1-13 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 大川 尚士: "Oxygenation of Heterodinuclear Di(m-phenoxo)CoIIMII(M=Mn, Fe, Co) Complexes Having 'Co(salen)' Entity in A Macrocyclic Framework"J. Chem. Soc., Dalton Trans.. 12. 2197-2203 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 大川 尚士: "Di(μ-phenoxo)CoIIMII(M=Mn, Co, Zn)Complexes with 'Co(salen)' Entity in Macrocyclic Framework : Core Structures and Neighboring MII Effect upon Oxygenation at the 'Co(salen)' Center"Inorg. Chem.. 38. 4038-4044 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 大川 尚士: "[Mn(en)]_3[Cr(CN)_6]_2・4H_2O : A Three-dimensional Dimetallic Ferrimagnet (Tc=69K) with A Defective Cubane Unit"Angew. Chem. Int. Ed.. 38. 1795-1798 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 大川 尚士: "Dinuclear and Tetanuclear Copper(II) Complexes with Bridging (N-N) Diazine Ligands : Variable Magnetic Topologies"J. Chem. Soc. Dalton Trans. 1. 69-77 (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] 山本 隆一: "Synthesis of Ru-and Os-Complexes of pi-Conjugated Oligomers of 2,2'-Bipyridine and 5,5-Bipyrimidine. Optical Properties and Catalytic Activity for Photoevolution of Hydrogen from Aqueous Media"Bull. Chem. Soc. Jpn.. 72. 1153-1162 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 山本 隆一: "Ni-Promoted Syntheses of New 3,3'-Dichloro-5,5'-bipyrazoles and Poly(bipyrazole-5,5'-diyl)s and Isolation of Nickel Complexes Relevant to the Synthesis"Bull. Chem. Soc. Jpn.. 72. 1629-1635 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 山本 隆一: "Preparation of pi-Conjugated Polymers Composed of Hydroquinone, π-Benzquinone, and π-Diacetoxyphenylene Units, Optical and Redox Properties of the Polymers"Macromolecules. 32. 8886-8896 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 山本 隆一: "1 : 2 Polycondensation of 3,3', 4,4'-Biphenyltetramine and 1.1'-Ferrocenedimethanol Catalyzed by Dichlorotris(triphenylphosphine)ruthenium(II) to Give Polybenzimidazole Containing Ferrocenylene Group"Bull. Chem. Soc. Jpn.. 72. 2557-2562 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 山本 隆一: "Control of Reductive Elimination and Acidolysis of Diarylnickel(II) Complexes by the Kind of Broensted Acid and the Presence of Oxygen"Chem, Lett.. 419-420 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 山本 隆一: "Theoretical Studics on Anomalous Phases in Molecular Systems with External Field : Possibility of Photo-Induced Superconductivity"Int. J. Quant. Chem.. 75. 549-561 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 山口 兆: "Formulation and Numerical Approach to Molecular System by the Green Function Method without the Born-Oppenheimer Approximation"J. Chem. Phys.. 111. 6171-6179 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 山口 兆: "Dynamics of Photon Phase and Information Entropy for a Two-state Molecular System Interacting with Amplitude- and Phase-squeezed Fields"J. Phys. Chem.. A103. 6036-6048 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 山口 兆: "Density Functional Study of Intermolecular Ferromagnetic Interaction Through μ-Phenylene Coupling Unit. III. Possibility of High Spin Polymer"J. Chem. Phys.. 111. 1309-1324 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 山口 兆: "Calculation of Frequency-Dependent First Hyperpolsaizabilities Using the Second-Order Moller-Plesset Perturbation Theory"J. Chem. Phys.. 110. 1720-1733 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 山口 兆: "Calculation of Frequency-Dependent Second Hyperpolsrizabilities for Electronic Field Induced Second Harmonic Generation in the Second-Order Moller-Plesset Perturbation Theory"J. Chem. Phys.. 111. 842-848 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 伊藤 翼: "A Short Platinum to Silver Dative Bond and its Application in the Construction of Extended Structures : Syntheses and Structures of Ag_2[Pt(ox)_2]・2H_2O and [Ag_2(H_2O]_2[Ag_2(CF_2SO_3)_4][Pt(acac)_2]_2"J. Chem. Soc., Dalton Trans.. 273-274 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 伊藤 翼: "Electron Transfer on Infrared Vibational Time Scale in the Mixed Valence State of 1,4-Pyrazinc and 4,4'-Bipyridine Bridged Ruthenium Cluster Complexes"J. Am. Chem. Soc.. 121. 4625-4632 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 伊藤 翼: "The First Examples of Platinum(II)-Cadmium(II) Bonds : The Role of Strong Field Ligands in Making Dative Pt-M bonds"J. Am. Chem. Soc.. 121. 7405-7406 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 伊藤 翼: "Syntheses and Properties of a Series of Oxo-Centered Triruthenium Complexes and Their Bridged Dimers with Isocyanide Ligands at Terminal and Bridging Positions"Inorg. Chem.. 38. 4070-4078 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 伊藤 翼: "Syntheses and Structures of Bridge and Chelate Isomers of Tetraplatinum(II) Cluster Complex with Diethydithiophosphate ion (Et_2dtp) at In-planc Sites. [Pt_4(CH_3COO)_4(Et_2dtp)_4]. And Their Mutual Isomerization via Cluster Core Rotation"J. Am. Chem. Soc.. 121. 10738-10742 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 伊藤 翼: "Cyanide-Bridged Iron-Copper Molecular Squares with Doublet and Quintet Spin Ground States"Inorg. Chem.. 38. 5686-5689 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 伊藤 翼: "Low Temperature Structural Studies in the Molecular β'-Pd(dmit)_2 Conductors"Phys. Rev.. B60. 3113-3119 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 加藤 礼三: "Two-band System : A Candidate for New Molecular Materials"Synth. Met.. 103. 2020-2023 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 加藤 礼三: "Conductive Copper Salts of 2,5-Disubstituted N,N'Dicyanobenzoquinonediimines (DCNOIs) : Structural and Physical Properties" (Accounts)"Bull, Chem. Soc. Jpn.. 73(in press). (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] 加藤 礼三: "Anomalous Rolr of Carbon and Nitrogen Isotopes in (DMe-DCNQI)_2Cu System"Synth. Met.. 102. 1749-1750 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 加藤 礼三: "Low Temperature X-ray Study of Purely One-dimensional Electronic System, Me_4X(CPDT-TCNO)_2(X=As, N)"Synth. Met.. 103. 2212-2213 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 伊藤翼: "Complexed Bridging Ligand,{M(bpca)_2}(M=Mn(II) or Fe(II):Hbpca=bis(2-pyridylcarbonyl)amine).as a Building Block for Linear Trinuclear Complexes" J.Chem.Soc.Dalton Trans.3351-3352 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 伊藤翼: "Self-assembling Tetranuclear Copper(II) Complex of a Bis-bidentate Schiff Base:Double-helical Structure Induced by Aromatic π…π and CH…π interactions" J.Chem.Soc.,Chem.Commun.63-64 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 伊藤翼: "Kinetic Study on the Substitution of Dimethylacetamide for the Terminal Aqua Ligands in the Trinoclear Chromium(III) Complexes [Cr_3(μ_3-O)(μ-RCO_2)_6(H_2O)_3]^+(R=H,CH_3,CH_3CH_2,CH_2Cl,CHCl_2,CH_3OCH_2,(CH_3)_3C,CH_2ClCCH_2,(CH_3CH_2)_2CH).Elucidation of the Mechanism from the Activation Volumes and the Sybstituent Effects of Bridging Carboxylate Ligands" Inorg.Chem.37. 3779-3784 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 伊藤翼: "A Short Platinum to Silver Dative Bond and its Application to the Construction of Extended Structures:Syntheses and Structures of Ag_2[Pt(ox)_2]・2H_2O and [Ag_2H_2O)]_2[Ag_2(CF_2SO_3)_4][Pt(acac)_2]_2" J.Chem.Soc.Dolton Trans.inpress (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 大川尚士: "Bimetallic Assemblies [Ni(L)_2]_3[Fe(CN)_6]X_2(L=en,tn:X=PF_6-,ClO_4-)with a 3-D Network Extended through Fe^<II>-CN-Ni^<II> Linkages." Inorg.Chem.37. 842-848 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 大川尚士: "Structure and Magnetic Properties of One-Dimensional PPh_4[Ni(pn)_2][M(CN)_6]・H_2O(M=Fe,Cr,Co)Bimetallic Assemblies." Inorg.Chem.37. 3349-3354 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 大川尚士: "Copper(II) Compounds Extended by 5-Carboxysalicylaldehyde and Its Schiff Bases: Interplay of Two Metal-Binding Sites and Intermolecular Stacking Contributing to Their Netwok and Bulk Structures." Bull.Chem.Soc.Jpn.71. 2365-2373 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 大川尚士: "Heterodinuclear Metal Complexes of Phenol-based Compartmental Macrocycles." Coord.Chem.Rev.174. 51-75 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 山本隆一: "Preparation of Poly(diphenylamine-4,4′-diyl)and Related Random Copolymers by Organometallic Polycondensation. Electrical,Electrochemical,and Optical Properties." Macromolecules. 31. 988-993 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 山本隆一: "Preparation of π-Conjugated poly(hydroquinone-2,5-diyl)and Poly(p-benzoquinone-2,5-diyl)and Their Electrochemical Behavior." Macromolecules. 31. 2683-2685 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 山本隆一: "New Type of Polymer Containing 1,1′-Ferrocenylene Unit in π-Conjugated Main Chain. Preparation and Redox Behavior." Inorg.Chim.Acta. 269. 310-312 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 山本隆一: "Extensive Studies on π-Stacking of Poly(3-alkylthiophene-2,5-diyls and Poly(4-alkylthiazole-2,5-diyl)s by Optical Spectgroscopy. NMR Analysis,Light Scattering Analyss,and X-ray Crystallography." J.Am.Chem.Soc.120. 2047-2058 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 山口兆: "Quantum Dynamics of Linear Molecular Aggregates." Int.J.Quantum.Chem.70. 77-87 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 山口兆: "Dependence of a Polarizability on Field Intensity and Size." J.Phys.Chem.A.102. 6807-6811 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 山口兆: "Quasiprobability Distribution Dynamics." Chem.Phys.Lett.295. 317-327 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 山口兆: "Electron-photon Field Dynamics." Chem.Phys.Lett.295. 328-336 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 加藤礼三: "A New Molecular Superconductor β′-Et_2Me_2P[Pd(dmit)_2]_2(dmit=2-thioxo-1,3-dithiole-4,5-dithiolate)." Solid State Commun.105. 561-565 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 加藤礼三: "Multicomponent Molecular Conductors with Supramolecular Assembly: Iodine-Containing Netural Molecules as Building Blocks." J.Am.Chem.Soc.120. 5905-5913 (1998)

    • Related Report
      1998 Annual Research Report

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Published: 1998-04-01   Modified: 2018-03-28  

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