| Project/Area Number |
10149104
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| Research Category |
Grant-in-Aid for Scientific Research on Priority Areas (A)
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| Allocation Type | Single-year Grants |
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| Review Section |
Science and Engineering
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| Research Institution | Tokyo Institute of Technology |
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Principal Investigator |
YAMAMOTO Takakazu Tokyo Institute of Technology, Chemical Reources Laboratory, Professor, 資源化学研究所, 教授 (10016743)
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| Co-Investigator(Kenkyū-buntansha) |
KITAGAWA Hiroshi University of Tsukuba, Department of Chemistry, Associate Professor, 化学系, 助教授 (90234244)
YAMASHITA Masahiro Tokyo Metropolitan University, Department of Chemistry, Professor, 大学院・理学研究科, 教授 (60167707)
MUNAKATA Megumu Kinki University, Department of Chemistry, Professor, 理工学部, 教授 (80090942)
HASHIMOTO Kazuhito The University of Tokyo, Research Center for Advanced Science and Technology, Professor, 先端科学技術研究センター, 教授 (00172859)
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| Project Period (FY) |
1998 – 2001
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| Project Status |
Completed (Fiscal Year 2002)
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| Budget Amount *help |
¥86,700,000 (Direct Cost: ¥86,700,000)
Fiscal Year 2001: ¥17,000,000 (Direct Cost: ¥17,000,000)
Fiscal Year 2000: ¥17,500,000 (Direct Cost: ¥17,500,000)
Fiscal Year 1999: ¥38,500,000 (Direct Cost: ¥38,500,000)
Fiscal Year 1998: ¥13,700,000 (Direct Cost: ¥13,700,000)
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| Keywords | Metal-assembled complex / Dimensional structure / Conductivity / Optical properties / Magnetism / Transition metal complex / Electrochemical response / Polymer-metal complex / 一次元構造 / 銀錯体 / 10族遷移金属錯体 / パイ共役錯体 / 電子・光機能 / ニッケル錯体 / パラジウム錯体 / 光機能 / ポリポルフィリン / 白金錯体 / 触媒作用 |
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| Research Abstract |
We have carried out research for rational control of dimensional structures of metal-assembled complexes. The complexes were prepared with combination between metals such as silver, palladium, platinum, copper, cobalt, iron, gold, ruthenium and nickel and ligands such as halogen, bisthienylethenes, pyrenes, cyano group, cyclopentadienyls and amines. The prepared metal complexes had 3-, 2-, and one-dimensionally controlled structures, and their chemical and physical properties and their chemical and physical functions were studied. In order to prepare these metal complexes, new ligands were synthesized.
Electrically conducting, o
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