| Project/Area Number |
10304058
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| Research Category |
Grant-in-Aid for Scientific Research (A)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
機能・物性・材料
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| Research Institution | HOKKAIDO UNIVERSITY |
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Principal Investigator |
NAKAMURA Takayoshi Hokkaido Univ. Research Institute for Electronic Science, Professor, 電子科学研究所, 教授 (60270790)
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| Co-Investigator(Kenkyū-buntansha) |
INABE Tamotsu Hokkaido Univ. Faculty of Science, Professor, 大学院・理学研究所, 教授 (20168412)
AKUTAGAWA Tomoyuki Hokkaido Univ. Research Institute for Electronic Science, Research Associate, 電子科学研究所, 助手 (60271631)
HASEGAWA Tatsuo Hokkaido Univ. Research Institute for Electronic Science, Associate Professor, 電子科学研究所, 助教授 (00242016)
TAKEDA Sadamu Hokkaido Univ. Faculty of Science, Professor, 大学院・理学研究所, 教授 (00155011)
AWAGA Kunio Nagoya Univ. Faculty of Science, Professor, 大学院・理学研究科, 教授 (10202772)
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| Project Period (FY) |
1998 – 2001
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| Project Status |
Completed (Fiscal Year 2001)
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| Budget Amount *help |
¥34,810,000 (Direct Cost: ¥34,000,000、Indirect Cost: ¥810,000)
Fiscal Year 2001: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2000: ¥2,600,000 (Direct Cost: ¥2,600,000)
Fiscal Year 1999: ¥4,900,000 (Direct Cost: ¥4,900,000)
Fiscal Year 1998: ¥23,800,000 (Direct Cost: ¥23,800,000)
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| Keywords | Supramolecular Cations / Transition Metal Complexes / Ionic Conduction / Molecular Conductors / Crown Ethers / Band-filling Control |
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| Research Abstract |
We introduced supramolecular cations composed of inorganic cations and crown ethers into [Ni(dmit)2 crystals and developed novel molecular systems in which electronic condction and ionic conduction coexisted.We also regulated [Ni(dmit)_2]^- assemblies in the crystal utilizing supramolecular cation structures and revealed that we could control magnetic and electronic properties through the molecular-assembly control.
To develop nanometer-size materials and devices from molecular charge transfer complexes, we investigated the formation of molecular films of charge transfer complexes. Especially, we used Langmuir-Blodgett method and succeeded in forming single-component conducting films. In addition, we studied self-assembly monolayers in which TTF skeleton directly attached to gold surface. We found that when we apply the Langmuir-Blodgett method to macrocyclic TTF molecule that has ion-recognition ability, the molecules forms nanowire structures. Moreover, when we used mica substrates, the nanowires recognized ionic array of the surface and oriented specific directions. These results strongly indicate that the molecular charge transfer complexes are quite useful to developing future molecular electronic devices.
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