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Formation and Functions of Self-Assembled Molecular Systems of Supramolecular Ions and Inherent Electrons

Research Project

Project/Area Number 10304058
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field 機能・物性・材料
Research InstitutionHOKKAIDO UNIVERSITY

Principal Investigator

NAKAMURA Takayoshi  Hokkaido Univ. Research Institute for Electronic Science, Professor, 電子科学研究所, 教授 (60270790)

Co-Investigator(Kenkyū-buntansha) INABE Tamotsu  Hokkaido Univ. Faculty of Science, Professor, 大学院・理学研究所, 教授 (20168412)
AKUTAGAWA Tomoyuki  Hokkaido Univ. Research Institute for Electronic Science, Research Associate, 電子科学研究所, 助手 (60271631)
HASEGAWA Tatsuo  Hokkaido Univ. Research Institute for Electronic Science, Associate Professor, 電子科学研究所, 助教授 (00242016)
TAKEDA Sadamu  Hokkaido Univ. Faculty of Science, Professor, 大学院・理学研究所, 教授 (00155011)
AWAGA Kunio  Nagoya Univ. Faculty of Science, Professor, 大学院・理学研究科, 教授 (10202772)
Project Period (FY) 1998 – 2001
Project Status Completed (Fiscal Year 2001)
Budget Amount *help
¥34,810,000 (Direct Cost: ¥34,000,000、Indirect Cost: ¥810,000)
Fiscal Year 2001: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2000: ¥2,600,000 (Direct Cost: ¥2,600,000)
Fiscal Year 1999: ¥4,900,000 (Direct Cost: ¥4,900,000)
Fiscal Year 1998: ¥23,800,000 (Direct Cost: ¥23,800,000)
KeywordsSupramolecular Cations / Transition Metal Complexes / Ionic Conduction / Molecular Conductors / Crown Ethers / Band-filling Control
Research Abstract

We introduced supramolecular cations composed of inorganic cations and crown ethers into [Ni(dmit)2 crystals and developed novel molecular systems in which electronic condction and ionic conduction coexisted.We also regulated [Ni(dmit)_2]^- assemblies in the crystal utilizing supramolecular cation structures and revealed that we could control magnetic and electronic properties through the molecular-assembly control.
To develop nanometer-size materials and devices from molecular charge transfer complexes, we investigated the formation of molecular films of charge transfer complexes. Especially, we used Langmuir-Blodgett method and succeeded in forming single-component conducting films. In addition, we studied self-assembly monolayers in which TTF skeleton directly attached to gold surface. We found that when we apply the Langmuir-Blodgett method to macrocyclic TTF molecule that has ion-recognition ability, the molecules forms nanowire structures. Moreover, when we used mica substrates, the nanowires recognized ionic array of the surface and oriented specific directions. These results strongly indicate that the molecular charge transfer complexes are quite useful to developing future molecular electronic devices.

Report

(5 results)
  • 2001 Annual Research Report   Final Research Report Summary
  • 2000 Annual Research Report
  • 1999 Annual Research Report
  • 1998 Annual Research Report
  • Research Products

    (145 results)

All Other

All Publications (145 results)

  • [Publications] K.Ikegami: "Preparation of Langmuir-Blodgett Films Containing a Charge-Transfer Complex of Alkylated Dicyanoquinonediimine (DCNQI) and Copper"Jpn. J. Appl. Phys. 37. L550-L552 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T.Akutagawa: "Linear Pentaidodide in the Radical Cation Salt of Tetrathiafulvalene Bisannulated Macrocycle"Inorg. Chem.. 37. 2330-2331 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] H.Hasegawa: "A Highly Conducting Partially Oxidized Salt of Axially Substituted Phthalocyaninc. Structure and Physical Properties of TPP[Co(Pc)(CN)_2]_2 (TPP = tetraphenylphosphonium and [Co(Pc)(CN)_2] dicyano (phtalocyaninato)cobalt(III))"J. Mater. Chem. 8. 1567-1570 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T.Nakamura: "A Molecular Metal with an Ion-Conducting Channel"Nature. 394. 159-161 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T.Konuma: "Charge-Transfer Interactions and Nonlinear Optical Properties of Tetrathiafulvalene-based Langmuir-Blodgett Film"Thin Solid Film. 327-329. 348-352 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] K.Ikegami: "Possible Low-Temperature Phase Transition of Langmuir-Blodgett Films of a Charge-Transfer Complex Detected by ESR"Thin Solid Films. 327-329. 391-394 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T.Nakamura: "Electrical Conduction in Monolayers and LB films of BEDOTTF-C_<10>TCNQ / Arachidic Acid Mixed System"Thin Solid Films. 327-379. 450-453 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T.Nakamura: "Electrical Conduction in Monolayers and LB films of BEDOTTF-C_<10>TCNQ / Arachidic Acid Mixed System"Thin Solid Films. 327-329. 450-453 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T.Akutagawa: "Structures of Ni(dmit)_2 (dmit = 2-thioxo-1,3-ditiol-4,5-dithiolate) Salts of Lithium or Ammonium Included in Crown Ether Assemblies"Thin Solid Films. 327-329. 264-271 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T.Akutagawa: "Supramolecular Cation of Acyclic Polyether : Potassium (pentaethyleneglycoal) in Molecular Conductor of Nickel Dithiolate Salt"Chem. Commun. 2599-2600 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T.Fujinawa: "Unusual Electrical Properties of Neutral Mixed Stack Charge-Transfer Complexes of DAP-BRL (DAP = 1,6-Diaminopyrene, BRL p-Bromanil)"Bull. Ghem. Soc. Jpn.. 72. 21-26 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] N.Robertson: "Preparation and Structure of [Na,15-orown-5][Ni(mnt)_2]H_2O : the First [Ni(mnt)_2] Complex Containing a Supramolecular Counterion"J. Chem. Res.. 54-55 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T.Tamura: "A Clay-Metal Complex Ultrathin Film as Prepared by the Langmuir-Blodgett Technique"Chem. Lett.. 121-122 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] N.Robertson: "Preparation, Structure and Properties of [Na. cis-anti-cis-dicyclohexyl-18-crown-6][Ni(dmit)_2]_42Me_2CO"J. Mater. Chem. 9. 1233-1236 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T.Akutagawa: "Ion Cavities within NH_4^+(crown ether)[Ni(dmit)_2] Salts"Synthetic Metals. 102. 1747-1748 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] J.Kawamata: "Observation of Third-Order Nonlinear Optical Effects of Metallo-Dimethylglyoxima Complexes by Methods Using the Evanescent Wave"Nonlinear Optics. 22. 373-376 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] J.Kawamata: "Electrical and Nonlinear Optical Properties of Langmuir-Blodgett Films of Charge Transfer Complexes"Mol. Cryst. Liq. Cryst. 327. 83-86 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T.Yumoto: "Langmuir-Blodgett Films of BEDO-TTF-CF_3TCNQ"Synthetic Metals. 102. 1733-1734 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Y.Abe: "Electronic and Structural Properties of TTF Bisannulated 24-crown-8 Charge Transfer Complexes"Synthetic Metals. 102. 1599-1600 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] K.Ikegami: "Optical Characterization of Langmuir-Blodgett Films of AlkylDCNQI and AlkylDCNQI-Cu Complexes"Synthetic Metals. 102. 1615-1616 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T.Akutagawa: "Nonlinear Optical Properties of Langmuir-Blodgett Films of Pyrazine-based Dye Molecule"Nonlinear Optics. 22. 127-130 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T.Hasegawa: "Valance-Modulation-Induced Optical Nonlinearlity of Intermolecular Charge-Transfer Langmuir-Blodgett Films"Nonlinear Optics. 22. 143-146 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T.Akutagawa: "Crystal Structure and Optical Properties of Cation Radical Salts of Tetrathiafulvalene Tris-annulated Macrocycles"J. Mater. Chem.. 9. 2737-2743 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T.Akutagawa: "Tuning of Intramolecular π-π Overlap Mode of Tetrathiafulvalene bisannulated Macrocycles in the Open-Shell Electronic State"Chem. Lett.. 132-133 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] K.Ikegami: "Structural Change in Langmuir and Langmuir-Blodgett Films of AlkylDCNQI Induced by Charge-Transfer Reaction at the Air-Water Interface"J. Chem. Phys.. 112. 881-886 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] N.Takamatsu: "One-dimensional Antiferromangetic Chain in [Ni(dmit)_2]^-Salts of [K^+ or Rb^+ (4,13-diaza-18-crown-6) Supramolecular Cation"Inorg. Chem.. 39. 870-871 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T.Akutagawa: "M^+ (12crown-4) Supramolecular Cations (M^+ = Na^+, K^+, Rb^+ and NH_4^+) within Ni(dmit)_2 Molecular Conductor"Inorg. Chem.. 39. 2645-2651 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T.Akutagawa: "Co^<II>(15-crown-5) Magnetic Supramolecular Cation in [Ni(dmit)_2]^-π-spin System"J. Phys. Chem. 104. 5871-5873 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T.Nakamura: "Conducting Langmuir-Blodgett Films of Bis [bis(methylthio)tetrathiafulvalenedithiolate] -gold Complex"Chem. Lett. 134-135 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T.Akutagawa: "Tuning of Intramolecular π-π Overlap Mode of Tetrathiafulvalene bisannulated Macrocycles in the Open-Shell Electronic State"Chem. Lett.. 132-133 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] N.Takamatsu: "M^+(Crown Ether) Supramolecular Cations (M^+ = K^+,Rb^+,NH_4^+) for Controlling Magnetic Properties of Monovalent [Ni(dmit)_2] Salts"Mol. Cryst. Liq. Cryst.. 343. 163-168 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T.Hasegawa: "Mixed-Stack Organic Charge-Transfer Complexes with Intercolumnar Networks"Phys. Rev. B. 62. 10059-10066 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T.Akutagawa: "Crystal Structure of Tetrathiafulvalene Multiannulated Macrocycles in Open-Shell Electronic State"Mol. Cryst. Liq. Cryst. 349. 379-382 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T.Nakamura: "Conducting Langmuir-Blodgett Films of Bis [bis(methylthio)tetrathiafulvalenedithiolate] -gold Complex"Chem. Left. 134-135 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] S.Mikami: "Structure, optical and magnetic behaviour of meso-tetraphenylporphyrinatoiron(III) tetracyanoethenide, (Fe^<III>(TPP)]^+[TCNE]^-"J. Chew. Soc. Dalton Trans.. 448-455 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] L.Cronin: "Unique Structural Topologies Involving Metal-Metal and Metal-Sulphur Interactions : Salts of [Ni(dmit)_2]^<x-> with cis-anti-cis-dicyclohexyl-18-crown-6 Complexed Counterions"J. Chem. Soc. Dalton Trans.. 1347-1351 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] K.Sakai: "Partially-Oxidized Ni(dmit)_2 Salt with Copper Ions"Synthetic Metals. 120. 991-992 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T.Naito: "Peculiar Physical Properties of (ET)_3(MnCl_4)(TCE)"Synthetic Metals. 120. 877-878 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] S.Nishihara: "[Ni(dmit)_2]^-Salts of a Supramolecular Cation, Sc^+(12-crown-4)_2"Synthetic Metals. 121. 1806-1807 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T.Akutagawa: "Diversity in 1/2 spin arrangement of [Ni(dmit)_2]^-anions in divalent Ca^<2+>(crown ethers) supramolecular cation salts"J. Mater. Chem.. 11. 2118-2124 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T.Naito: "β^<11>-(ET)_3(MnCl_4)(1,1,2-C_2H_3Cl_3) (ET = bis(ethylenedithio)tetrathiafulvalene) ; A Pressure-Sensitive New Molecular Conductor with Localized Spins"J. Mater. Chem.. 11. 2221-2227 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T.Takahashi: "Structure and Electronic Properties of Bis [bis(methylthio)tetrathiafulvalenedithiolate] -Gold(III) Langmuir-Blodgett Films"Thin Solid Films. 393. 7-11 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T.Hasegawa: "Neutral-Ionic Phase Transition of (BEDT-TTF)(ClMeTCNQ) under Pressure"Phys. Rev. B. 64. 085106-085107 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T.Akutagawa: "Ion Channel Structures in M^+(18-Crown-6)[Ni(dmit)_2] Molecular Conductors"Chem. Eur J.. 7. 4902-4912 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] K.Shitagami: "Potassium (2,3,11,12-dibenzo-1,4,7,10,13,16-hexaoxocyclo-octadeca-2,11-diene) Bis(4,5-dimercapto-1,3-dithiole-2-thionato)nickel (III) (propanone)"Acta Crystallographica Section C. 57. 1271-1273 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] K.Shitagami: "An Infinite Supramolecular Array Structure in Metal Dithiolate Complexes : Crystal Structure of K(Dibenzo-18-crown-6)[M(dmit)_2](CH_3CN)_2 (M : Ni, Au)"Cryst. Eng. Commun. 52 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T.Akutagawa: "Handbook of Advanced Electronic and Photonic Materials"Supramolecular Aspects of Organic Conductors. 375 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T.Akutagawa: "Handbook of Advanced Electronic and Photonic Materials"Supramolecular Aspects of Organic Conductors. 375 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] K. Ikegami, T. Nakamura: "Preparation of Langmuir-Blodgett Films Containing a Charge-Transfer Complex of Alkylated Dicyanoquinonediimine (DCNQI) and Copper"Jpn. J. Appl. Phys.. 37. L550-L552 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T. Akutagawa, Y. Nezu, Y. Abe, T. Nakamura, A. Yamanaka, K. Inoue, T. Inabe, C. A. Christensen, J. Becher: "Linear Pentaidodide in the Radical Cation Salt of Tetrathiafulvalene Bisannulated Macrocycle"Inorg. Chem.. 37. 2330-2331 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] H. Hasegawa, T. Naito, T. Inabe, T. Akutagawa, T. Nakamura: "A Highly Conducting Partially Oxidized Salt of Axially Substituted Phthalocyanine. Structure and Physical Properties of TPP[Co(Pc)(CN)2]2 (TPP = tetraphenylphosphonium and [Co(Pc)(CN)2] = dicyano(phtalocyaninato)cobalt(III)"J. Mater. Chem.. 8. 1567-1570 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T. Nakamura, T. Akutagawa, K. Honda, A. E. Underhill, A. T. Coomber, R. H. Friend: "A Molecular Metal with an Ion-Conducting Channel"Nature. 394. 159-161 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T. Konuma, T. Akutagawa, T. Yumoto, T. Nakamura, J. Kawamata, K. Inoue, T. Nakamura, H. Tachibana, M. Matsumoto, H. Ikegami, S. Horiuchi, H. Yamochi, G. Saito: "Charge-Transfer Interactions and Nonlinear Optical Properties of Tetrathiafulvalene-based Langmuir-Blodgett Films"Thin Solid Films. 327-329. 348-352 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] K. Ikegami, S. Kuroda, T. Akutagawa, T. Konuma, T. Nakamura, M. Matsumoto, S. Horiuchi, H. Yamochi, G. Saito: "Possible Low-Temperature Phase Transition of Langmuir-Blodgett Films of a Charge-Transfer Complex Detected by ESR"Thin Solid Films. 327-329. 391-394 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T. Nakamura, T. Yumoto, T. Akutagawa, R. Azumi, H. Tachibana, M. Matsumoto, S. Horiuchi, H. Yamochi, G. Saito: "Electrical Conduction in Monolayers and LB films of BEDOTTF-C10TCNQ / Arachidic Acid Mixed System"Thin Solid Films. 327-329. 450-453 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T. Akutagawa, T. Nakamura, T. Inabe, A. E. Underhill: "Structures of Ni(dmit)2 (dmit = 2-thioxo- 1 ,3-ditiol-4,5-dithiolate) Salts of Lithium or Ammonium Included in Crown Ether Assemblies"Thin Solid Films. 331. 264-271 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T.Akutagawa, Y. Nezu, T. Hasegawa, K. Sugiura, T. Nakamura, T. Inabe, Y. Sakata, A. E. Underhill: "Supramolecular Cation of Acyclic Polyether: Potassium (pentaethyleneglycoal) in Molecular Conductor of Nickel Dithiolate Salt"J. Chem. Soc. Chem. Commun.. 2599-2600 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T. Fujinawa, H. Goto, T. Naito, T. Inabe, T. Akutagawa, T. Nakaumura: "Unusual Electrical Properties of Neutral Mixed Stack Charge-Transfer Complexes of DAP-BRL (DAP = 1,6-Diaminopyrene, BRL = p-Bromanil"Bull. Chem. Soc. Jpn.. 72. 21-26 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] N. Robertson, S. Roehrs, T. Akutagawa, T. Nakamura, A. E. Underhill: "Preparation and Structure of [Na.15-crown-5][Ni(mnt)2].H2O: the FIrst Ni(mnt)2]- Complex Containing a Supramolecular Counterion"J. Chem. Res.. 54-55 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] K. Tamura, H. Setsuda, M. Taniguchi, T. Nakamura, A Yamagishi: "A Clay-Metal Complex Ultrathin Film as Prepared by the Langmuir-Blodgett Technique"Chem. Lett.. 121-122 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] N. Robertson, T. Akutagawa, T. Nakamura, S. Roehrs, A. E Underhill: "Preparation, and Structure and Properties of [Na.cis-anti-cis-discyclohexyl-18-crown-6][Ni(dmit)2]4・2Me2CO"J. Mater. Chem.. 9. 1233-1236 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T. Nakamura, T. Yumoto, T Suzuki, T, Akutagawa, T. Hasegawa, H. Tachibana, M. Matsumoto, S. Horiuchi, H. Ikegami, H. Yamochi, G. Saito: "Electrical and Nonlinear Optical Properties of Langmuir-Blodgett Films of Charge Transfer Complexes"Mol. Cryst. Liq. Cryst.. 327. 83-86 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T. Nakamura, T. Akutagawa, T. Hasegawa, T. Kikukawa, T. Araiso, M. Higuchi, K. Hiratani: "Polymerization of pyrrole in microgravity"Synthetic Metals. 101. 78-79 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T. Yumoto, T. Akutagawa, T. Hasegawa, T. Nakamura, H. Ikegami, G. Saito: "Langmuir-Blodgett Films of BEDO-TTF・CF3TCNQ"Synthetic Metals. 102. 1733-1734 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Y. Abe, T. Akutagawa, T. Hasegawa, T. Nakamura, K. Sugiura, Y. Sakata, T. Inabe, C. A. Christensen, J. Becher: "Electronic and Structural Properties of TTF Bisannulated 24-crowns-8 Charge Transfer Complexes"Synthetic Metals. 102. 1599-1600 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] K. Ikegami, M. Lan, T. Nakamura: "Optical Characterization of Langmuir-Blodgett Films of AlkylDCNQI and AlkylDCNAQI-Cu Complexes"Synthetic Metals. 102. 1615-1616 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T. Akutagawa, T. Hasegawa, T. Nakamura, T. Inabe, K. Sugiura, Y. Sakata, A. E. Underhill: "Ion Cavities within NH4+(crown ether)[Ni(dmit)2]Salts"Synthetic Metals. 102. 1747-1748 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T. Akutagawa, T. Hasegawa, T. Nakamura, Y. Sasou, R. Kondo, S. Kagoshima, T. Mochida, G. Saito, Y. Iwasa: "Electronic Phase Transition of BEDT-TTF Based Mixed -Stack Charge-Transfer Complexes"Synthetic Metals. 103. 1804-1805 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T. Akutagawa, T. Hasegawa, T. Konuma, T. Nakamura, M. Matsuoka: "Nonlinear Optical Properties of Langmuir-Blodgett Films of Pyrazine-based Dye Molecule"Nonlinear Optics.. 22. 127-130 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T. Hasegawa, T. Akutagawa, T. Konuma, T. Nakamura, J. Kawamata, K. Inoue: "Valance-Modulation-Induced Optical Nonlinearlity of Intermolecular Charge-Transfer Langmuir-Blodgett Films"Nonlinear Optics.. 22. 143-146 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] J. Kawamata, M. Kiguchi, T. Nakamura, K. Inoue: "A New Method for Evaluating Third-Order Nonlinear Optical Efficiency of Powder Crystals"Nonlinear Optics.. 22. 349-352 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] J. Kawamata, T. Akutagawa, T. Hasegawa, T. Nakamura, K. Inoue, M. Kiguchi, G. Saito: "Observation of Tird-Order Nonlinear Optical Effects of Metallo-Dimethylglyoxime Complexes by Methods Using the Evanescent Wave"Nonlinear Optics.. 22. 373-376 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T. Akutagawa, Y. Abe, T. Hasegawa, T. Nakamura, T. Inabe, K. Sugiura, Y. Sakata, C. A. Chiristensen, J. Becher: "Crystal Structure and Optical Properties of Cation Radical Salts of Tetrathiafulvalene Tris-annulated Macrocycles"J. Mater. Chem.. 9. 2737-2742 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] K. Ikegami, M. Lan, T. Nakamura: "Structural Change in Langmuir and Langmuir-Blodgett Films of alkylDCNQI Induced by Charge-Transfer Reaction at the Air-Water Interface"J. Chem. Phys.. 112. 881-886 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T. Akutagawa, Y. Abe, T. Hasegawa, T. Nakamura, T. Inabe, C. A. Chiristensen, J. Becher: "Turning of Intermolecular π-π Overlap Mode of Tetrathiafulvalene bisannulated Macrocycles in the Open -Shell Electronic State"Chem. Lett.. 132-133 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] N. Takamatsu, T. Akutagawa, T. Hasegawa, T. Nakamura, T. Inabe, W. Fujita, K. Awaga: "One-dimensional Antiferromangetic Chain in [Ni(dmit)2]- Salts of [K+ or Rb+ (4,13-diaze-18-crown-6) Supramolecular Cation"Inorg. Chem.. 39. 870-871 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] K. Uesugi, I. Suemune, T. Hasegawa, T. Akutagawa, T. Nakamura: "Temperature Dependence of Band Gap Energies of GaAsN Alloys"Appl. Phys. Lett.. 76. 1285-1287 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T. Akutagawa, T. Hasegawa, T. Nakamura, S. Takeda, T. Inabe, K. Sngiura, Y. Sakata, A. E. Underhill: "M^+(12crown-4) Supramolecular Cations (M^+ = Na^+, K^+, Rb^+ and NH_4^+) within Ni(dmit)_2 Molecular Conductor"Inorg. Chem.. 39. 2645-2651 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T. Akutagawa, S. Nishihara, N. Takamatsu, T. Hasegawa, T. Nakamura, T. Inabe: "CO2^+ (15-crown-5) Magnetic Supramolecular Cation in [Ni(dmit)2]-π-spin System"J. Phys. Chem.. 104. 5871-5873 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Y. Abe, N. Takamatsu, T. Yumoto, T. Suzuki. T. Akutaeawa, T. Hasegawa, T. Nakamura, M. Higuchi, K. Hiratani: "Polymerization of Pyrrole under Microgravity Conditions"Space Forum. 6. 221-226 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] N. Takamatsu, T. Akutagawa, T. Hasegawa, T. Nakamura. T. Inabe, W. Fujita, K. Awaga: "M^+(Crown Ether) Supramolecular Cations (M^+ = K^+, Rb^+, NH_4^+) for Controlling Magnetic Properties of Monovalent [Ni(dmit)2] Salts"Mol. Cryst. Liq. Cryst.. 343. 163-168 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T. Hasegawa, T. Mochida, R. Kondo, S. Kagoshima, Y. Iwasa, T. Akutagawa, T. Nakamura, G. Saito: "Mixed-Stack Organic Charge-Transfer Complexes with Intercolumnar Networks"Phys. Rev. B.. 62. 10059-10066 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T. Akutawa, Y. Abe, T. Ohta, T. Hasegawa, T. Nakamura, C. A. Christensen, J. Becher: "Crystal Structure of Tetrathiafulvalene Multiannulated Macrocycles in Open-Shell Electronic State"Mol. Cryst. Liq. Cryst.. 349. 379-382 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] J. Kawamata, T. Akutagawa, T. Hasegawa, K. Inoue, T. Nakamura: "Nonlinear Optical Properties of the Langmuir-Blodgett Films of an Intermolecular Charge Transfer Complex"Nonlinear Optics.. 25. 425-430 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T. Nakamura, T. Takahashi, T. Yumoto, T. Akutagawa, T. Hasegawa: "Conducting Langmuir--Blodgett Films of Bis[bis(methylthio)tetrathiafulvalenedithiolate]-gold Complex"Chem. Lett.. 134-135 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Usuki, H. Okawa, T. Akutagawa, S. Nisihara, T. Nakamura, K. Iwasaki, N. Miyazaki, S. Hino, E. Asato, J. S. Miller, Y. Sakata: "Structure, optical and magnetic behavior of meso-tetraphenylporhyrinatoiron (III) tetracyanoethenide, [Fe^<III> (TPP)]^+[TCNE]-"J. Chem. Soc. Dalton Trans.. 448-455 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] L. Cronin, S. J. Clark, S. Parsons, T. Nakamura, N. Robertson: "Unique aaastructural Toopologies Involviing Metal-Metal and Metal-Sulphur Interactions: Salts of [Ni(dmit)_2]^<x-> with cis-anti-cis-dicyclohexyl-18-crown-6 Complexed Counterions"J. Chem. Soc. Dalton Trans.. 1347-1351 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] K. Sakai, T. Akutagawa, T. Hasegawa, T. Nakamura: "Partially-Oxidized Ni(dmit)2 Salt with Copper Ions"Synthetic Metals. 120. 805-806 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T. Hasegawa, R. Kondo, S. Kagoshima, Y. Iwasa, T. Mochida, T. Akutagawa, T. Nakamura: "Donor Acceptor Type Complexes of (BEDT-TTF)(TCNQ) Analogues: Peculiar Magnetic Transistion in (BEDO-TTF)(C12TCNQ)"Synthetic Metals.. 120. 991-992 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T. Naito, T. Inabe, K. Takeda, K. Awaga, T. Akutagawa, T. Hasegawa, T. Nakamura, T. Kakiuchi, H. Sawa, T. Yamamoto, H. Tajima: "Peculiar Physical Properties of (ET)3(MnCl4)(TCE)"Synthetic Metals.. 120. 877-878 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] S. Nishihara, T. Akutagawa, T. Hasegawa, T. Nakamura: "[Ni(dmit)2]-Salts of a Supramolecular Cation. Sc^+(12-crown-4)2"Synthetic Metals.. 121. 1806-1807 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T. Akutagawa, N. Takamatsu, K. Shitagami, T. Hasegawa, T. Nakamura, I. Inabe, W. Fujita, K. Awaga: "Diversity in 1/2 spin arrangement of [Ni(dmit)_2]^- anions in Divalent Ca^<2+> (crown ethers) supramolecular cation salts"J. Mater. Chem.. 11. 2118-2124 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T. Naito, T. Inabe, K. Takeda, K. Awaga, T. Akutagawa, T. Hasegawa, T. Nakamura, T. Kakiuchi, H. Sawa, T. Yamamoto, H. Tajima: "β'-(ET)_3(MnCl_4)(1,1,2-C_2H_3Cl_3) (ET = bis (ethylenedithio) tetrathiafulvalene) A Pressure-sensitive New Molecular Conductor with Localized Spins"J. Mater. Chem.. 11. 2221-2227 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T. Takahashi, K. Sakai, T. Yumoto, T. Akutagawa, T. Hasegawa, T. Nakamura: "Structure and Electronic Properties of Bis [bis(methylthio)tetrathiafulvalenedithiolate)-Gold(III) Langmuir-Blodgett Films"Thin Solid Films. 393. 7-11 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T. Hasegawa, T. Akutagawa, T. Nakamura, T. Naito, T. Inabe, T. Mochida, R. Kondo, S. Kagoshima, Y. Iwasa: "Neutral-Ionic Phase Transition of (BEDT-TTF)(ClMeTCNQ) under Pressure"Phys. Rev. B.. 64. 085106-1-085106-7 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T. Akutagawa, T. Hasegawa, T. Nakamura, S. Takeda, T. Inabe, K. Sugiura, Y. Sakata, A. E. Underhill: "Ion Channel Structures in M^+(18-Crown-6)[Ni(dmit)2] Molecular Conductors"Chem. Eur. J.. 7. 4902-4912 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] K. Shitagami, T. Akutagawa, T. Hasegawa, T. Nakamura, N. Robertson: "Potassium Bis(4,5-dimercapto-1,3-dithiole-2-thionato)nickelate (1,4,7,10,13,16-hexaoxa-2,3 : 11,12-dibenzocyclooctadeca-2,11-diene) Propanone Solvate"Acta Crystallographica Section C.. 57. 1271-1273 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] K. Shitagami, T. Akutagawa, T. Hasegawa, T. Nakamura, N. Nakamura, N. Robertson: "An Infinite Supramolecular Array Structure in Metal Dithiolate Complexes: Crystal Structure of K(Dibenzo-18-crown-6)[M(dmit)_2](CH_3CN)_2(M: Ni, Au)"Cryst. Eng. Commum.. 52. (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] S. Nishihara, T. Akutagawa, T. Hasegawa, T. Nakamura: "Formation of Molecular Spin Ladder Induced by Supramolecular Cation Structure"Chem. Commum.. 408-409 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T. Akutagawa, T. Ohta, T. Hasegawa, T. Nakamura, C. A. Christensen, J. Becher: "Formation of Oriented Molecular Nanowires on Mica Surface"Proc. Natl. Acad. Sci. USA. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T. Nakamura: "Conducting Langmuir-BlodgettFilms of Bis[bis(methylthio)tetrathiafulvalenedithiolate]-gold Complex"Chem. Lett. 134-135 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] S. Mikami: "Structure, optical and magnetic behaviour of meso-tetraphenylporphyrinatoiron(III) tetracyanoethenide, [Fe^<III>(TPP)]^+[TCNE]^<・->"J. Chem. Soc. Dalton Trans. 448-455 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] L. Cronin: "Unique Structural Topologies Involving Metal-Metal and Metal-Sulphur Interactions : Salts of [Ni(dmit)_2]^<k-> with cis-anti-cis-dicyclohexyl-18-crown-6 Complexed Counterions"J. Chem. Soc. Dalton Trans.. 1347-1351 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] K. Sakai: "Partially-Oxidized Ni(dmit)_2 Salt with Copper Ions"Synthetic Metals. 120. 991-992 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] T. Naito: "Peculiar Physical Properties of (ET)_3(MnCl_4)(TCE)"Synthetic Metals. 120. 877-878 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] S. Nishihara: "[Ni(dmit)_2]-Salts of a Supramoleculat Cation, Sc^+(12-crown-4)_2"Synthetic Metals. 121. 1806-1807 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] T. Akutagawa: "Diversity in 1/2 spin arrangement of [Ni(dmit)_2]^- anions in divalent Ca^<2+>(crown ethers) supramolecular cation salts"J. Mater. Chem.. 11. 2118-2124 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] T. Naito: "β^<11>-(ET)_3(MnCl_4)(1,1,2-C_2H_3Cl_3) (ET = bis(ethylenedithio)tetrathiafulvalene) ; A Pressure-Sensitive New Molecular Conductor with Localized Spins"J. Mater. Chem.. 11. 2221-2227 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] T. Takahashi: "Structure and Electronic Properties of Bis[bis(methylthio)tetrathiafulvalenedithiolate)-Gold(III)Langmuir-Blodgett Films"Thin Solid Films. 393. 7-11 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] T. Hasegawa: "Neutral-Ionic Phase Transition of (BEDT-TTF)(ClMeTCNQ) under Pressure"Phys. Rev. B. 64. 085106-1-085106-7 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] T. Akutagawa: "Ion Channel Structures in M^+(18-Crown-6)[Ni(dmit)_2] Molecular Conductors"Chem. Eur. J.. 7. 4902-4912 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] K. Shitagami: "Potassium(2,3,11,12-dibenzo-1,4,7,10,13,16-hexaoxocyclo-octadeca-2,11-diene) Bis(4,5-dimercapto-1,3-dithiole-2-thionato)nickel(III)(propanone)"Acta Crystallographica Section C. 57. 1271-1273 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] K. Shitagami: "An Infinite Supramolecular Array Structure in Metal Dithiolate Complexes : Crystal Structure of K(Dibenzo-18-crown-6)[M(dmit)_2](CH_3CN)_2(M : Ni, Au)"Cryst. Eng. Commun. 52 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] T. Akutagawa: "Handbook of Advanced Electronic and Photonic Materials,"Supramolecular Aspects of Organic Conductors. 375 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] K.Ikegami: "Structural Change in Langmuir and Langmuir-Blodgett Films of AlkylDCNQI Induced by Charge-Transfer Reaction at the Air-Water Interface"J.Chem.Phys.. 112. 881-886 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] N.Takamatsu: "One-dimensional Antiferromangetic Chain in [Ni (dmit)_2]^- Salts of [K^+ or Rb^+ (4, 13-diaza-18-crown-6) Supramolecular Cation"Inorg.Chem.. 39. 870-871 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] T.Akutagawa: "M^+ (12crown-4) Supramolecular Cations (M^+=Na^+, K^+, Rb^+ and NH_4^+) within Ni (dmit)_2 Molecular Conductor"Inorg.Chem.. 39. 2645-2651 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] T.Akutagawa: "Co^<II> (15-crown-5) Magnetic Supramolecular Cation in [Ni (dmit)_2]^-?-spin System"J.Phys.Chem. 104. 5871-5873 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] T.Nakamura: "Conducting Langmuir-Blodgett Films of Bis [bis (methylthio) tetrathiafulvalenedithiolate] -gold Complex"Chem.Lett. 134-135 (2001)

    • Related Report
      2000 Annual Research Report
  • [Publications] T.Akutagawa: "Tuning of Intramolecular π-π Overlap Mode of Tetrathiafulvalene bisannulated Macrocycles in the Open-Shell Electronic State"Chem.Lett. 132-133 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] N.Takamatsu: "M^+ (Crown Ether) Supramolecular Cations (M^+=K^+, Rb^+, NH_4^+) for Controlling Magnetic Properties of Monovalent [Ni (dmit)_2] Salts"Mol.Cryst.Liq.Cryst... 343. 163-168 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] T.Hasegawa: "Mixed-Stack Organic Charge-Transfer Complexes with Intercolumnar Networks"Phys.Rev.B. 62. 10059-10066 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] T.Akutagawa: "Crystal Structure of Tetrathiafulvalene Multiannulated Macrocycles in Open-Shell Electronic State"Mol.Cryst.Liq.Cryst. 349. 379-382 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] T.Akutagawa: "Supramolecular Aspects of Organic Conductors"Handbook of Advanced Electronic and Photonic Materials,. 3. 267-301 (2000)

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      2000 Annual Research Report
  • [Publications] T. Fujinawa: "Unusual Electrical Properties of Neutral Mixed Stack Charge-Transfer Complexes of DAP-BRL (DAP=1,6-Diaminopyrene, BRL=p-Bromanil)"Bull. Chem. Soc. Jpn.. 72. 21-26 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] N. Robertson: "Preparation and Structure of [Na. 15-crown-5][Ni(mnt)_2]H_2O : the First [Ni(mnt)_2]^- Complex Containing a Supramolecular Counterion"J. Chem. Res.. 54-55 (1999)

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      1999 Annual Research Report
  • [Publications] K. Tamura: "A Clay-Metal Complex Ultrathin Film as Prepared by the Langmuir-Blodgett Technique"Chem. Lett.. 121-122 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] N. Robertson: "Preparation, Structure and Properties of [Na.cis-anti-cis-dicyclohexyl-18-crown-6][Ni(dmit)_2]_4・2Me_2CO"J. Mater. Chem. 9. 1233-1236 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] T. Akutagawa: "Ion Cavities within NH_4^+ (crown ether) [Ni(dmit)_2] Salts"Synthetic Metals. 102. 1747-1748 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] J. Kawamata: "Observation of Third-Order Nonlinear Optical Effects of Metallo- Dimethylglyoxime Complexes by Methods Using the Evanescent Wave"Nonlinear Optics. 22. 373-376 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] T. Nakamura: "Electrical and Nonlinear Optical Properties of Langmuir-Blodgett Films of Charge Transfer Complexes"Mol. Cryst. Liq. Cryst. 327. 83-86 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] T. Yumoto: "Langmuir-Blodgett Films of BEDO-TTF・CF_3TCNQ"Synthetic Metals. 102. 1733-1734 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Y. Abe: "Electronic and Structural Properties of TTF Bisannulated 24-crown-8 Charge Transfer Complexes"Synthetic Metals. 102. 1599-1600 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] K. Ikegami: "Optical Characterization of Langmuir-Blodgett Films of AlkylDCNQI and AlkylDCNQI-Cu Complexes"Synthetic Metals. 102. 1615-1616 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] T. Akutagawa: "Nonlinear Optical Properties of Langmuir-Blodgett Films of Pyrazine-based Dye Molecule"Nonlinear Optics. 22. 127-130 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] T. Hasegawa: "Valance-Modulation-Induced Optical Nonlinearity of Intermolecular Charge-Transfer Langmuir-Blodgett Films"Nonlinear Optics. 22. 143-146 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] T. Akutagawa: "Crystal Structure and Optical Properties of Cation Radical Salts of Tetrathiafulvalene Tris-annulated Macrocycles"J. Mater. Chem.. 9. 2737-2742 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] T. Akutagawa: "Tuning of Intramolecular π-π Overlap Mode of Tetrathiafulvalene bisannulated Macrocycles in the Open-Shell Electronic State"Chem. Lett.. 132-133 (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] K. Ikegami: "Structural Change in Langmuir and LB Films of AlkylDCNQI Induced by Charge-Transfer Reaction at the Air-Water Interface"J. Chem. Phys.. 112. 881-886 (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] T.Akutagawa: "Linear Pentaidodide in the Radical Cation Salt Tetrathiafulvalene Bisannulated Macrocycle" Inorg.Chem.37. 2330-2331 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] H.Hasegawa: "A Highly Conducting Partially Oxidized Salt of Axially Substituted Phthalocyanine" J.Mater.Chem.8. 1567-1570 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] T.Nakamura: "A Molecular Metal with an Ion-Conducting Channel" Nature. 394. 159-161 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] T.Akutagawa: "Structures of Ni (dimit)_2 (dmit=2-thioxo-1,3-ditiol-4,5-dithiolate) Salts of Lithium or Ammonium included in Crown Ether Assemblies" Thin Sold Films. 331. 264-271 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] T.Akutagawa: "Supramolecular Cation of Acyclic Polyether : Potassium (pentaethyleneglycoal) in Molecular Conductor of Nickel Dithiolate Salt" J.Chem.Soc.Chem.Commun.2599-2600 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] N.Robertson: "Preparation,Structure and Properties of [Na.dis-anti-cis-dicyclohexyl-18-crown-6][Ni (dimit)_2]_4 (acetone)_2" J.Mater.Chem.(in press).

    • Related Report
      1998 Annual Research Report

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Published: 1998-04-01   Modified: 2016-04-21  

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