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Studies on rarefied gas flow of radicals and surface reactions in a high-density plasma reactor

Research Project

Project/Area Number 10305016
Research Category

Grant-in-Aid for Scientific Research (A).

Allocation TypeSingle-year Grants
Section一般
Research Field Fluid engineering
Research InstitutionTOHOKU UNIVERSITY

Principal Investigator

NANBU Kenichi  Tohoku Univ., Inst.Fluid Sci., Prof., 流体科学研究所, 教授 (50006194)

Co-Investigator(Kenkyū-buntansha) YONEMURA Shigeru  Tohoku Univ., Inst.Fluid Sci., Research Asso., 流体科学研究所, 助手 (00282004)
SASAKI Hiroshi  Tohoku Univ., Inst.Fluid Sci., Research Asso., 流体科学研究所, 助手 (50006186)
近藤 修司  日本学術振興会, 特別研究員
川野 聡恭  東北大学, 流体科学研究所, 助教授 (00250837)
Project Period (FY) 1998 – 2000
Project Status Completed (Fiscal Year 2000)
Budget Amount *help
¥30,400,000 (Direct Cost: ¥30,400,000)
Fiscal Year 2000: ¥3,400,000 (Direct Cost: ¥3,400,000)
Fiscal Year 1999: ¥2,500,000 (Direct Cost: ¥2,500,000)
Fiscal Year 1998: ¥24,500,000 (Direct Cost: ¥24,500,000)
KeywordsInductively coupled plasma / Chlorine plasma / Etching / Radical flow / Wafer biasing / Surface reaction / PIC / MC method / DSMC method / 誘導結合型プラズマ / プラズマエッチング / モンテカルロ法 / ヘリカルコイル / Cl_2プラズマ
Research Abstract

We describe the theoretical and experimental results of this study.
1 Theoretical results
(1) The physical and chemical phenomena in an ICP reactor are analyzed using DSMC and PIC/MC methods.
The etch rate increases with increasing mass flow rate and the region of nonuniform etch rate becomes wider as the flow rate decreases.
The deviation of EEDF from the Maxwellian becomes small due to Coulomb collisions for smaller coil current.
(2) Etching of silicon wafer by chlorine gas in a CCP reactor is studied by use of a combined analysis of the DSMC and PIC/MC methods.
The etch rate is uniform in most of tea wafer. It shows a sharp rise near the wafer edge.
The electron density is two-order lower than the negative chlorine radical ion density in the afterglow of RF chlorine discharge plasma.
(3) We proposed a new useful particle modeling to simulate the ICP reactor. In this work, production and transport of plasma and radicals are calculated using this modeling. Our simulation and experiment show a good agreement with each other.
2 Experimental results
(1) We examined the argon plasma properties in an ICP reactor.
The electron density is in the region of 1×10^<10>〜1×10^<11> cm^3, electron temperature 4〜6eV, and plasma potential 35〜45V.
(2) We examined the silicon etching properties of cw discharge and pulsed discharge in the chlorine plasma. The results of the cw discharge are as follows :
The distribution of the etch rate is very uniform over the wafer surface.
The etch depth depends on the etching time linearly.
(3) The results of the pulsed discharge are as follows :
The etch rate increases with decreasing the duty ratio butit is saturated about 33% of duty ratio.
As the duty ratio decreases, the distribution of the etch rate becomes more nonuniform.

Report

(4 results)
  • 2000 Annual Research Report   Final Research Report Summary
  • 1999 Annual Research Report
  • 1998 Annual Research Report
  • Research Products

    (38 results)

All Other

All Publications (38 results)

  • [Publications] Kenichi Nanbu: "Direct Simulation Monte Carlo Analysis of Flows and Etch Rate in an Inductively Coupled Plasma Reactor."IEEE Trans.Plasma Sci.. Vol.27. 1379-1388 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Sigeru Yonemura: "Numerical Analysis of Electron Energy Distributions in Inductively Coupled Plasmas."4^<th> Int.Conf.Reactive Plasma and 16^<th> Symp.Plasma Processing. 165-166 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Kenichi Nanbu: "Direct Simulation Monte Carlo(DSMC) Modeling of Silicon Etching in Radio-Frequency Chlorine Discharge."Comput.Fluid Dynamics Journal. Vol.18. 257-265 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Kenichi Nanbu: "Detailed Structure of the Afterglow of Radio-Frequency Chlorine Discharge."Jpn.J.Appl.Phys.. Vol.38. L951-L953 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Kenichi Nanbu: "Probability Theory of Electron-Molecule, Ion-Molecule, Molecule-Molecule, and Coulomb Collision for Particle Modeling of Materials Processing Plasma and Gases."IEEE Trans.Plasma Sci.. Vol.28. 971-990 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Masakazu Shiozawa: "Particle Modeling of Plasma and Flow in an Inductively Coupled Plasma."Proc.of 22^<nd2> Int.Symp.on Rarefied Gas Dynamics. (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Masakazu Shiozawa: "Particle Modeling of Production and Transport of Plasma and Radicals in an Inductively-Couplod Chlorine Plasma Reactor."Proc.of Plasma Sci.Symp.and 18^<th> Symp.on Plasma Processing. 197-198 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Hiroshi Sasaki: "Basic Plasma Properties in a High-Density ICP Etching Apparatus."Proc.of 17^<th> Symp.on Plasma Processing. 125-128 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Hiroshi Sasaki: "Measurement of Plasma Parameters in an Inductively Coupled Plasma Reactor."Proc.of 22^<nd> Int.Symp.on Rarefied Gas Dynamics. (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Hiroshi Sasaki: "Etcging Properties of Silicon in Inductively-Coupled Chlorine Plasma."Proc.of Plasma Sci.Symp.and 18^<th> Symp.on Plasma Processing. 483-484 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Kenichi Nanbu: "Direct Simulation Monte Carlo Analysis of Flows and Etch Rate in an Inductively Coupled Plasma Reactor."IEEE Trans Plasma Sci.. Vol.27. 1379-1388 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Sigeru Yonemura: "Numerical Analysis of Electron Energy Distributions in Inductively Coupled Plasmas."4^<th> Int.Conf. Reactive Plasma and 16^<th> Symp.Plasma Processing. 165-166 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Kenichi Nanbu: "Direct Simulation Monte Carlo(DSMC) Modeling of Silicon Etching in Radio-Frequency Chlorine Discharge."Comput Fluid Dynamics Journal. Vol.18, No.2. 257-265 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Kenichi Nanbu: "Detailed Structure of the Afterglow of Radio-Frequency Chlorine Discharge."Jpn.J.Appl.Phys.. Vol.38. L951-L953 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Kenichi Nanbu: "Probability Theory of Electron-Molecule, Ion-Molecule, Molecule-Molecule, and Coulomb Collision for Particle Modeling of Materials Processing Plasma and Gases."IEEE Trans.Plasma Sci.. Vol.28. 971-990 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Masakazu Shiozawa: "Particle Modeling of Plasma and Flow in an Inductively Coupled Plasma."Proc.of 22^<nd> Int.Symp.on Rarefied Gas Dynamics. (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Masakazu Shiozawa: "Particle Modeling of Production and Transport of Plasma and Radicals in an Inductively-Coupled Chlorine Plasma Reactor."Proc.of Plasma Sci.Symp.and 18^<th> Symp.on Plasma Processing. 197-198 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Hiroshi Sasaki: "Basic Plasma Properties in a High-Density ICP Etching Apparatus."Proc.of 17^<th> Symp.on Plasma Processing. 125-128 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Hiroshi Sasaki: "Measurement of Plasma Parameters in an Inductively Coupled Plasma Reactor."Proc.of 22^<nd> Int.Symp.on Rarefied Gas Dynamics. (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Hiroshi Sasaki: "Etcging Properties of Silicon in Inductively-Coupled Chlorine Plasma."Proc.of Plasma Sci.Symp.. and 18^<th> Symp.on Plasma Processing. 483-484 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Kenichi Nanbu: "Comparison of Measured and Simulated Etch Rates in an Inductively-Coupled Plasma Reactor"American Physical Society Oct.. 24-27 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Kenichi Nanbu: "Comparison of Measured and Simulated Etch rates in an Inductively-Coupled Plasma Reactor"Bulltin of the American Physical Society. Vol.45. 12-13 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Kenichi Nanbu: "Probability Theory of Electron-Molecule, Ion-Molecule, Molecule-Molecole, and Coulomb Collision for Particle Modeling of Materials Processing Plasma and Gases"IEEETrans.Plasma Sci.. Vol.28. 971-990 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Masakazu Shiozawa: "Particle Modeling of Production and Transport of Plasma and Radicals in an Inductively-Coupled Chlorine Plasma Reactor"Proc.of Plasma Sci.Symp. and 18th Symp.on Plasma Processing. 197-198 (2001)

    • Related Report
      2000 Annual Research Report
  • [Publications] Masakazu Shiozawa: "Particle Modeling of Plasma and Flow in an Inductively Coupled Plasma"Proc.of 22nd Int.Symp.on Rarefied Gas Dynamics. (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Hiroshi Sasaki: "Etching Properties of Silicon in Inductively-Coupled Chlorine Plasma"Proc.of Plasma Sci.Symp.and 18th Symp.on Plasma Processing. 483-484 (2001)

    • Related Report
      2000 Annual Research Report
  • [Publications] Hiroshi Sasaki: "Measurement of Plasma Parameters in an Inductively Coupled Plasma Reactor"Proc.of 22nd Int.Symp.on Rarefied Gas Dynamics. (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 南部健一: "プロセスプラズマとガス流れの粒子シミュレーション"応用物理. 68巻,5号. 503-512 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] kenichi Nanbu: "Direct Simulation Monte Carlo (DSMC) Modeling of Silicon Etching in Radio-Frequency Chlorine Discharge"Comput. Fluid Dynamics Journal. Vol.8,No.2. 257-265 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] kenichi Nanbu: "Detailed Structure of the Afterglow of Radio-Frequency Chlorine Discharge"Jpn. J. Appl. Phys.. Vol.38. L951-L953 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] kenichi Nanbu: "Direct Simulation Monte Carlo Analysis of Flows and Etch Rate in an Inductively Coupled Plasma Reactor"IEEE.Trans. Plasma Science. Vol.27. 1379-1388 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Sigeru Yonemura: "Electron Energy Distributions in an Inductively Coupled Plasma Reactor"Proc. Of 21st Int. Symp .on Rarefied Gas Dynamics. Vol.2. 39-46 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Hiroshi Sasaki: "Basic Plasma Properties in a High-Density ICP Etching Apparatus"Proc. Of 17th Symp .on Plasma Processing. 125-128 (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] Kenichi Nanbu: "Monte Carlo Collision Simulation of Positive-Negative Ion Recombination for a Given Rate Constant" J.Phys.Soc.Jpn.67・4. 1288-1290 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Kazuki Denpoh: "Self-consistent Particle Simulation of Radio-Frequency CF_4Dis-charge with Implementation of All Ion-Neutral Reactive Collisions." J.Vacuum Sci.Technol.A. 16・3. 1201-1206 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Hiroshi Sasaki: "Detailed Measurements of Radial and Axial Structure of RF Glow Discharge." 4th Int.Conf.Reactive Plasmas & 16th Symp.Plasma Processing. 341-342 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Kenichi Nanbu: "Direct Simulation Monte Carlo Analysis of Flows and Etch Rate in a Model Inductively Coupled Plasma Reactor." 4th Int.Conf.Reactive Plasmas & 16th Symp.Plasma Processing. 249-250 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Sigeru Yonemura: "Numerical Analysis of Electron Energy Distributions in Inductively Coupled Plasmas." 4th Int.Conf.Reactive Plasmas & 16th Symp.Plasma Processing. 165-166 (1998)

    • Related Report
      1998 Annual Research Report

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Published: 1998-04-01   Modified: 2016-04-21  

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