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Effect of stress on grain boundary sulfidation of heat resistant alloys

Research Project

Project/Area Number 10305052
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Material processing/treatments
Research InstitutionHOKKAIDO UNIVERSITY

Principal Investigator

NARITA Toshio  Hokkaido Univ. Grad. School of Eng., Professor, 大学院・工学研究科, 教授 (60001252)

Co-Investigator(Kenkyū-buntansha) KUROKAWA Kazuya  Hokkaido Univ., Grad. School of Eng., Assoc. Professor, 大学院・工学研究科, 助教授 (00161779)
Project Period (FY) 1998 – 2001
Project Status Completed (Fiscal Year 2001)
Budget Amount *help
¥32,170,000 (Direct Cost: ¥31,300,000、Indirect Cost: ¥870,000)
Fiscal Year 2001: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2000: ¥4,100,000 (Direct Cost: ¥4,100,000)
Fiscal Year 1999: ¥3,600,000 (Direct Cost: ¥3,600,000)
Fiscal Year 1998: ¥20,700,000 (Direct Cost: ¥20,700,000)
KeywordsFe-25Cr alloy / Cr_2O_3 / Crack / Creep / Secondary creep rate / Ar atmosphere / 973K / 加速腐食 / 粒界腐食 / スケールの破壊 / 強度強化 / 亜硫酸ガス / 応力・歪み極性 / スケールの密着性 / 酸化 / 硫化 / スケール破壊 / ステンレス鋼 / クロム酸化物 / 粒界すへり / 耐熱材料 / 結晶粒界 / 硫化腐食 / タービン / ボイラー / サーボパルサー
Research Abstract

A 0.1 μm thick Cr_2O_3 scale formed on an Fe-25Cr alloy in Ar at 973K for 7.2 ks, and then constant loads of 30-40 MPa were applied at 973K in Ar to the specimen. During creep deformation of the specimen the scale cracked at the end of the third creep stage at the grain boundaries, and then propagated into inner grains in the third creep stage. Cracks arrayed perpendicular to the stress loading direction and inter-crack spacings in the grain boundaries on the specimen are shorter than that of in the inner grains. Strain rate in each area is estimated. Inter-crack spacings (L) have power law relations with the creep rate of specimens (ε') as a form of L ∝ (ε')^n. Strain rate exponentη is estimated as -0.44 for the alloy grain boundaries and -0.22 for the alloy grains in this study.

Report

(5 results)
  • 2001 Annual Research Report   Final Research Report Summary
  • 2000 Annual Research Report
  • 1999 Annual Research Report
  • 1998 Annual Research Report
  • Research Products

    (18 results)

All Other

All Publications (18 results)

  • [Publications] 孫一領, 成田敏夫: "Cracking behavior of Cr2O3 scale formed on Fe-25Cr alloy at 973K in Ar atmosphere"Oxidation of Metals. (発表予定).

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] 孫一領, 成田敏夫: "Corrosion behavior of Fe-25CR alloy in N2-0.1%SO2 atmosphere at 973K under Mechanical Loading"Oxidation of Metals. (発表予定).

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] II Ryoung Sohn, Toshio Narita: "Cracking behavior of Cr2O3 scale formed on Fe-25Cr alloy in Ar Ar at 973K under mechanical loading"Oxidation of Metals, o be submitted.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] 高橋英徳, 鴨田秀一, 林重成, 成田敏夫: "Fe-Cr-C合金表面近傍Cr炭化物の分解に及ぼす温度及び雰囲気の影響"材料と環境. 50巻10号. 472-476 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] 鳴海雅稔, 于志明, 田海啓司, 成田敏夫: "プラズマ溶射CoNiCrAIY/YSZ皮膜の1173Kと1273Kにおける大気中酸化挙動"材料と環境. 50巻 10号. 466-471 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] 于志明, 田海啓司, 成田敏夫: "遮熱コーティング皮膜の1173K ; 硫黄分圧10^<-0.6>Pにおける硫化腐食挙動"材料と環境. 50巻 8号. 376-379 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] H.Takahashi, Y.Miyakoshi, S.kamota, T.Narita: "The intergranular corrosion mechanism of Fe-26Cr-13Ni heat resistant cast steel in waste incineration environments"Proceedings of HTCP2000 in Rusutusu. 1. 565-561 (2000)

    • Related Report
      2001 Annual Research Report
  • [Publications] 福本倫久, 前田滋, 林重成, 成田敏夫: "Fe-1.5mass%Si 合金の高温初期酸化に対する温度と水蒸気の影響"鉄と鋼. 86巻 8号. 526-533 (2000)

    • Related Report
      2001 Annual Research Report
  • [Publications] 高橋英徳, 宮越康樹, 鴨田秀一, 林重成, 成田敏夫: "耐熱鋳鋼SCH2の廃棄物焼却炉内における高温腐食挙動"材料と環境. 49巻 7号. 426-430 (2000)

    • Related Report
      2001 Annual Research Report
  • [Publications] Cheng.Fang: "Sulfidation properties of Ni-20Cr and Ni-13.5Co-20Cr Alloys at 873K under Low Sulfur pressures"Oxidation of Metals. 53 5/6. 597-617 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Cheng.Fang: "Phase Diagram of the Ni-Cr-S System at 873K between 10^<-4> and 10^<-8>Pa"Oxidation of Metals. 54 1/2. 163-171 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Toshio Narita: "Sulfidation processing and Cr addition to improve oxidation resistance of TiAl intermetallics in air at 1173K"Intermetallics. 8 4. 371-379 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Takeshi Izumi: "Sulfidation properties of TiAl-2at%X(X=V, Fe, Co, Cu, Nb, Mo, Ag and W)alloys at 1173K and 1.3Pa sulfur pressure"Intermetallics. 8 8. 891-901 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 福本倫久: "Fe-1.5mass%Si合金の高温初期酸化に対する温度と水蒸気の影響"鐡と鋼. 86 8. 526-533 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 林重成 成田敏夫: "Fe-低 Al 合金の1073Kにおける内部酸化挙動に及ぼす Al 濃度の影響"日本金属学会誌. 63・9. 1204 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 泉岳志 大笹憲一 成田敏夫: "硫化処理 TiAl 合金の耐酸化性に及ぼす第3元素添加の影響"耐熱金属材料第123委員会研究報告. 40・2. 181 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 高橋英徳 宮腰康樹 鴨田秀一 成田敏夫: "廃棄物焼却炉環境における耐熱鋳鋼SCH13の粒界腐食機構"材料と環境. 48・9. 583 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 八鍬浩 宮坂松甫 成田敏夫: "N2-H2-H2S 雰囲気における Ni 基超合金の高温硫化挙動"材料と環境. 48・5. 299 (1999)

    • Related Report
      1999 Annual Research Report

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Published: 1998-04-01   Modified: 2016-04-21  

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