| Project/Area Number |
10355033
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| Research Category |
Grant-in-Aid for Scientific Research (A).
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| Allocation Type | Single-year Grants |
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| Section | 展開研究 |
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| Research Field |
工業分析化学
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| Research Institution | KYUSHU UNIVERSITY |
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Principal Investigator |
IMASAKA Totaro Faculty of Engineering, KYUSHU UNIVERSITY, Prof., 大学院・工学研究院, 教授 (30127980)
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| Co-Investigator(Kenkyū-buntansha) |
NODA Hiroshi Shimadzu Co., Department of Environmental Instrumentation, Manager of Technology, 環境計測事業部, 技術部係長
HIRAKAWA Yasuyuki Faculty of Engineering, KYUSHU UNIVERSITY, Res.Assoc., 大学院・工学研究院, 助手 (80238344)
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| Project Period (FY) |
1998 – 2000
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| Project Status |
Completed (Fiscal Year 2000)
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| Budget Amount *help |
¥30,700,000 (Direct Cost: ¥30,700,000)
Fiscal Year 2000: ¥3,000,000 (Direct Cost: ¥3,000,000)
Fiscal Year 1999: ¥12,700,000 (Direct Cost: ¥12,700,000)
Fiscal Year 1998: ¥15,000,000 (Direct Cost: ¥15,000,000)
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| Keywords | Suersonic Jet Spectrometry / Multiphoton Ionization / Mass Spectrometry / Chlorinated Aromatic Hydrocarbons / Dioxins / Polyvinylchloride / On-line Analysis / Real-Time Analysis / 多光子イオン化法 / 質量分析法 / 塩素置換芽香施化合物 / ポリ塩化ビュル / ポリ塩化ビニリヂン / 環境分析 |
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| Research Abstract |
We developed an analytical instrument for sensitive real-time monitoring of dioxins and investigated basic researches using this analytical instrument.
The lifetimes of the electronic excited state of aromatic hydrocarbons containing many chlorine atoms such as dioxins are shortened by a spin-orbit interaction. As a result of this, the efficiency of multiphoton ionization is substantially reduced. In order to overcome this problem, it is necessary to use a laser whose pulsewidth is similar to the lifetime of the analyte molecule. This expectation was confirmed from both sides of theory and experiment. In this work, we developed a distributed-feedback dye laser having a picosecond pulsewidth and confirmed that a high ionization efficiency was obtained using this laser.
In order to improve the sensitivity in dioxin analysis, it is desirable to use a mass spectrometer which allows efficient detection of ions induced by multiphoton ionization. A new type of mass spectrometer was designed in
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this study and performance expected was calculated using a SIMION software. We also constructed this mass spectrometer and confirmed experimentally to have sufficient performance for sensitive detection of dioxins and their precursors.
In this work, we measured thermally decomposed ploducts of polyvinylchloride by supersonic jet spectrometry. It was found that no dioxin precursors are formed from polyvinylchloride, while a precursor of chlorobenzene is formed as a major product from chlorinated polyvinylchloride (polyvinylidene). We also investigated the reaction mechanism of dioxins induced from chlorophenols in the absence and presence of a catalyst of FeCl_3. An unexpected isomer of dioxin was found, which was formed through the "Smile Rearrangement". Real-time monitoring of s pecific isomer is difficult using a conventional mass spectrometer, and hence we could demonstrate the advantage of supersonic jet/multiphoton ionization/mass spectrometry over conventional mass spectrometry.
Our proposal entitled, "Development of analytical instrument for on-line real-time monitoring of dioxins" was accepted by NEDO in the period of 2000-2002. The analytical instrument developed is scheduled to be commercialized from 2003. Less
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