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Dynamics of glass transitions probed by ultra-broadband spectroscopy

Research Project

Project/Area Number 10440115
Research Category

Grant-in-Aid for Scientific Research (B).

Allocation TypeSingle-year Grants
Section一般
Research Field 物性一般(含基礎論)
Research InstitutionUniversity of Tsukuba

Principal Investigator

KOJIMA Seiji  Institute of Materials Science, University of Tsukuba, Associate Professor, 物質工学系, 助教授 (90134204)

Project Period (FY) 1998 – 2000
Project Status Completed (Fiscal Year 2000)
Budget Amount *help
¥13,400,000 (Direct Cost: ¥13,400,000)
Fiscal Year 2000: ¥1,200,000 (Direct Cost: ¥1,200,000)
Fiscal Year 1999: ¥3,400,000 (Direct Cost: ¥3,400,000)
Fiscal Year 1998: ¥8,800,000 (Direct Cost: ¥8,800,000)
Keywordsboson peak / Raman scattering / relaxation / fragility / complex susceptibility / activation energy / glass / alcohol / ダイナミクス / 緩和 / 誘電分散 / 光散乱 / 広帯域 / 分光 / ガラス転移 / α-緩和 / β-緩和 / ホウ酸ガラス / ラマン分光
Research Abstract

The dynamical properties of glass transition have been studied by ultra broadband spectroscopt. The low-frequency thermal properties were studied by the modulated scanning calorimeter at 10-100mHz, and the grass transition temperatures were accurately determined. The dielectric properties in the frequency range from 1mHz to 10MHz was studied by impedance gain phase analyzer, and the α and slow β relaxation processes were studied in super-cooled liquid states. While in liquid states at high temperatures the two dielectric relaxation processes were studied by the time domain reflectmetry in the frequency range between 1MHz and 10GHz. In Brillouin scattering in the range 1GHz to 1000GHz, the fast relaxation or fast β-process was studied. The high-frequency vibrational properties were studied by Raman scattering in the range between 0.1THz and 100THz, the boson peak was studied in details. Thecorrelation between the fast process and the boson peak was discussed on the basis of the anharmonic model.

Report

(4 results)
  • 2000 Annual Research Report   Final Research Report Summary
  • 1999 Annual Research Report
  • 1998 Annual Research Report
  • Research Products

    (30 results)

All Other

All Publications (30 results)

  • [Publications] 小島誠治 他: "Fast relaxation, boson peak and fragility in modified borate glass"J.Chem.Phys.. 113. 6344-6352 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] 小島誠治 他: "Structural Relaxation by MDSC and Dielectric Spectroscopy"Thermochimica Acta. 352. 147-152 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] 小島誠治 他: "Broadband Dielectric Relaxation of Glass Transition in Dyhydroxyl"J.Mol.Crys. & Liq.Crys.. 322. 329-335 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] 小島誠治 他: "Boson Peak in Alkali Borate Glass"Physica.B. 263. 336-338 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] 小島誠治 他: "Dielectric Investigations of Glass Transition in Glass Forming Liquid"J.Thermal Analysis & Calorimetriy. 57. 687-693 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] 小島誠治 他: "Slow Dynamics in Glass-Forming Propylene Glycol"J.Korean Soc.phys.. 35. S1350-S1353 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Kojima, V.Novikov and M.Kodama: "Fast relaxation, boson peak and fragility in modified borate glass"J.Chem.Phys.. 113. 6344 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] I.S.Park and S.Kojima: "Glass transition and Structural Relaxation of Intermediate Liquids by MDSC and Dielectric Spectroscopy"Therm.Acta. 147. 352-353 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] I-S.Park, K.Saruta and S.Kojima: "Broadband Dielectric Relaxation of Glass Transition in the Intermediate Glass-Forming Dyhydroxyl Alcohols"J.Mol.& Liq.Crys.. 322. 329 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Kojima and M.Kodama: "Boson Peak in Alkali Borate Glass"Physica.B. 336. 263-264 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] I.S.Park, K.Saruta and S.Kojima: "Calorimetric and Dielectric Investigations of Glass Transition in Intermediate Glass Forming Liquid"J.Therm.Analy.& Cal.. 687. (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] I.S.Park, M.Mikami and S.Kojima: "Slow Dynamics in Glass-Forming Propylene Glycol Monomethyl Ether and its Oligomers"J.Korean Soc.Phys.. S1350. 35 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] 小島誠治 他: "Fast relaxation, boson peak and fragility in modified borate glass"J.Chem.Phys.. 113. 6344-6352 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 小島誠治 他: "Structural Relaxation by MDSC and Dielectric Spectroscopy"Thermochimica Acta. 352. 147-152 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 小島誠治 他: "Broadband Dielectric Relaxation of Glass Transition in Dyhydroxyl"J.Mol.Crys.& Liq.Crys.. 322. 329-335 (1999)

    • Related Report
      2000 Annual Research Report
  • [Publications] 小島誠治 他: "Boson Peak in Alkali Borate Glass"Physica.B. 263. 336-338 (1999)

    • Related Report
      2000 Annual Research Report
  • [Publications] 小島誠治 他: "Dielectric Investigations of Glass Transition in Glass Forming Liquid"J.Thermal Analysis & Calorimetriy. 57. 687-693 (1999)

    • Related Report
      2000 Annual Research Report
  • [Publications] 小島誠治 他: "Slow Dynamics in Glass-Forming Propylene Glycol"J.Korean Soc.. 35. S1350-S1353 (1999)

    • Related Report
      2000 Annual Research Report
  • [Publications] I.S.Park,K.Saruta and S.Kojima: "Calorimetric and Dielectric Investigations of Glass Transition"J.Thermal Analysis & Calorimetriy. 8. 687-693 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] S.Kojima and M.Kodama: "Boson Peak in Alkali Borate Glass"Physica.B. 263-264. 336-338 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] I.S.Park,M.Mikami,S.Kojima: "Dynamics of Liquid-Glass Transition in Propanol"AIP Conf.Proc.. 469. 306-309 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] I.S.Park,M.Mikami and S.Kojima: "Slow Dynamics in Glass-Forming Propylene Glycol Monomethyl"J.Korean Soc.. 35. S1350-S1353 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Y.Takagi,T.Yano and S.Kojima: "Temperature Dependence of Depolarized Spectra in n-propanol"Physica.B. 263-264. 306-309 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] I-S.Park,K.Saruta and S.Kojima: "Broadband Dielectric Relaxation of Glass Transition in the Intermediate"J.Mol.Crys.&Liq.Crys.. 322. 329-334 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] I.S.Park and S.Kojima: "“Broadband dielectric measurements of lower alcohols"" J.Korean Phys.Soc.32. S817-S820 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] G.Matsui and S.Kojima: "“Rapid Brillouin Scattering Measurement of Fast Relaxation Process"" Jpn.J.Appl.Phys.37. 2812-2814 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] M.Ahart and S.Kojima: "“Brillouin Scattering Study of Pressure Induced Glass Transition in Ethanol"" Jpn.J.Appl.Phys.36. 2803-2804 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] G.Matsui and S.Kojima: "“Dynamics of Relaxation Process of Glass Transition in Ethylene Glycol"" J.Non-Cryst.Solids. 235. 271-274 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] I-S.Park and S.Kojima: "“Dielectric relaxation and Calorimetric Measurements of Glass Transition"" J.Phys.Soc.Jpn.67. 4131-4138 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] I-S.Park and S.Kojima: "“Broadband Dielectric relaxation of Glass Transition in the Intermediate Glass"" J.Mol.Crys.& Liq.Crys.322. 329-335 (1999)

    • Related Report
      1998 Annual Research Report

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Published: 1998-04-01   Modified: 2016-04-21  

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