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A STUDY ON ULTRA-HARD FILM FORMATION BY MACROPARTICLE ION BEAM WITH HIGH ENERGY

Research Project

Project/Area Number 10450119
Research Category

Grant-in-Aid for Scientific Research (B).

Allocation TypeSingle-year Grants
Section一般
Research Field Electronic materials/Electric materials
Research InstitutionKYOTO UNIVERSITY

Principal Investigator

TAKOKA Gikan  Dept.of Eng., Kyoto Univ.Assoc.Prof., 工学研究科, 助教授 (90135525)

Co-Investigator(Kenkyū-buntansha) MATSUO Jiro  Dept.of Eng., Kyoto Univ.Res.Assoc., 工学研究科, 助手 (40263123)
YAMADA Isao  Emeritus Prof., 名誉教授 (00026048)
Project Period (FY) 1998 – 2000
Project Status Completed (Fiscal Year 2000)
Budget Amount *help
¥13,100,000 (Direct Cost: ¥13,100,000)
Fiscal Year 2000: ¥1,500,000 (Direct Cost: ¥1,500,000)
Fiscal Year 1999: ¥5,200,000 (Direct Cost: ¥5,200,000)
Fiscal Year 1998: ¥6,400,000 (Direct Cost: ¥6,400,000)
Keywordsmacroparticle / fullerene / Argon cluster / multicollisions / high density irradiation / film formation / carbon film / クラスター / イオンビーム / Arクラスター / 非線形照射効果 / ビッカース硬度
Research Abstract

In this project, we have investigated on film formation by using macroparticles such as fullerene (C_<60>) and Argon cluster ions. Also, we have studied on an interaction between ion beams and a solid surface. It was found that irradiation of macroparticles has unique characteristics such as multicollisons, high density irradiation, etc., which deviate significantly from monomer ion irradiation. Films prepared by this method exhibited Vickers hardness value of 5,000 kg/mm^2 and no hydrogen inclusion. These films exhibited good properties of hardness, adhesion and wear resistance, compared with a typical value of 3,000 kg/mm^2 for films prepared by other methods. High density irradiation on a solid surface with high energetic macroparticles was capable to produce the phase modification from fullerene to diamond-like-carbon with high hardness and very smooth surface, which was also clarified by the computer simulation based on molecular dynamic simulation. Furthermore, deposition on substrates with high thermal expansion coefficients such as steel, iron and other materials was studied, and it was capable to apply to the films for industrial use.

Report

(4 results)
  • 2000 Annual Research Report   Final Research Report Summary
  • 1999 Annual Research Report
  • 1998 Annual Research Report
  • Research Products

    (22 results)

All Other

All Publications (22 results)

  • [Publications] I.Yamada, J.Matsuo: "Ultra-Hard DLC Formation at Low Temperature by Gas Cluster Ion Beam Assisted Deposition"Mass and Charge Transport in Inorganic Materials : Fundamentals to Devices. 957-964 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] I.Yamada, J.Matsuo, G.H.Takaoka: "DLC Film Formation by Ar Cluster Ion Beam Assisted Deposition"Nuclear Instruments and Methods in Physics Research B. (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] J.Matsuo, G.H.Takaoka, I.Yamada: "STM Observation of a Si Surface Irradiated with a Single Ar Cluster Ion"Nuclear Instruments and Methods in Physics Research B. (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] J.Matsuo, G.H.Takaoka, I.Yamada: "Ar Cluster Ion Bombardment Effects on Semiconductor Surfaces"Proceedings of 2000 MRS Fall Meetings. (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] J.Matsuo, G.H.Takaoka: "Size Dependence of Damage Formation by Cluster Ion Impact"Proceedings of 2000 MRS Fall Meetings. (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] I.Yamada,J.Matsuo: "Ultra-Hard DLC Formation at Low Temperature by Gas Cluster Ion Beam Assisted Deposition"Mass and Charge Transport in Inorganic Materials : Fundamentals to Devices. 957-964 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] I.Yamada,J.Matsuo,G.H.Takaoka: "DLC Film Formation by Ar Cluster Ion Beam Assisted Deposition"Nuclear Instruments and Methods in Physics Research B. (発表予定). (2001)

    • Related Report
      2000 Annual Research Report
  • [Publications] J.Matsuo,G.H.Takaoka,I.Yamada: "STM Observation of a Si Surface Irradiated with a Single Ar Cluster Ion"Nuclear Instruments and Methods in Physics Research B. (発表予定). (2001)

    • Related Report
      2000 Annual Research Report
  • [Publications] J.Matsuo,G.H.Takaoka,I.Yamada: "Ar Cluster Ion Bombardment Effects on Semiconductor Surfaces"Proceedings of 2000 MRS Fall Meetings. (発表予定). (2001)

    • Related Report
      2000 Annual Research Report
  • [Publications] J.Matsuo,G.H.Takaoka: "Size Dependence or Damage Formation by Cluster Ion Impact"Proceedings of 2000 MRS Fall Meetings. (発表予定). (2001)

    • Related Report
      2000 Annual Research Report
  • [Publications] I.Yamada: "Surface Processing with Ionized Cluster Beams: Computer Simulation"Nuclear Instruments and Methods in Physics Research B. Vol.153. 199-208 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] J.Matsuo,I.Yamada: "Optical Thin Film Formation by Gas Cluster Ion Beam Assisted Deposition"Applications of Accelerators in Research and Industry. 409-412 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] J.Matsuo,I.Yamada: "Oxide Film Deposition by Gas-Cluster Ion Assisted Deposition"Applications of Accelerators in Research and Industry. 425 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] J.Matsuo,I.Yamada: "Cluster Size Dependence of the Impact Process on a Carbon Substrate"Nuclear Instruments and Methods in Physics Research B. Vol.153. 264-269 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] J.Matsuo,I.Yamada: "Formation of Oxide Thin Films for Optical Applications by O_2 Cluster Ion Beam Assisted Deposition"Proceedings of the 12th International Conference on Ion Implantation Technology-IIT98. 1195-1198 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] J.Matsuo,I.Yamada: "Fullerene Ion (C60^^+) Implantation in GaAs (100) Substrate"Proceedings of the 12th International Conference on Ion Implantation Technology-IIT98. 1203-1206 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] I.Yamada: "Gas Cluster Ion Beams for Processing New Materials" Physics of Clusters. No.3. 74-85 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] I.Yamada: "Progress,Demands and Prospects for Advanced Ion Beam Processing" Materials Chemistry and Physics. Vol.54. 5-14 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] J.Matsuo,G.Takaoka,I.Yamada: "Indium Oxide Film Fomation by O_2 Cluster Ion-Assisted Deposition" Materials Chemistry and Physics. Vol.54. 258-261 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] J.Matsuo,I.Yamada: "Molecular Dynamics Simulation of a Carbon Cluster Ion Impacting on a Carbon Surface" Materials Chemistry and Physics. Vol.54. 139-142 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] J.Matsuo,I.Yamada: "Energy Dependence of a Single Trace Created by C_<60> Ion Impact" Materials Chemistry and Physics. Vol.54. 143-146 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] J.Matsuo,I.Yamada: "Angular Distributions of the Particles Sputterd with Ar Cluster Ions" Materials Chemistry and Physics. Vol.54. 262-265 (1998)

    • Related Report
      1998 Annual Research Report

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Published: 1998-04-01   Modified: 2016-04-21  

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