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Microstructural Evolution by Cooperative Motion of Nano-grains

Research Project

Project/Area Number 10450240
Research Category

Grant-in-Aid for Scientific Research (B).

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic materials/Physical properties
Research InstitutionTokyo Institute of Technology

Principal Investigator

WAKAI Fumihiro  Materials and Structures Lab.Tokyo Institute of Technology Professor, 応用セラミックス研究所, 教授 (30293062)

Co-Investigator(Kenkyū-buntansha) AKATSU Takashi  Materials & Structures Lab.Tokyo Institute of Technology Lecturer, 応用セラミックス研究所, 講師 (40231807)
ENOMOTO Naoya  Kyushu Univ. Assoc.Professor, 工学研究院, 助教授 (70232965)
YASUDA Eiichi  Materials & Structures Lab.Tokyo Institute of Technology Professor, 応用セラミックス研究所, 教授 (70016830)
SHINODA Yutaka  Materials & Structures Lab.Tokyo Institute of Technology Research associate, 応用セラミックス研究所, 助手 (30323843)
Project Period (FY) 1998 – 2000
Project Status Completed (Fiscal Year 2000)
Budget Amount *help
¥12,600,000 (Direct Cost: ¥12,600,000)
Fiscal Year 2000: ¥3,500,000 (Direct Cost: ¥3,500,000)
Fiscal Year 1999: ¥4,100,000 (Direct Cost: ¥4,100,000)
Fiscal Year 1998: ¥5,000,000 (Direct Cost: ¥5,000,000)
Keywordscell structure / grain boundary motion / grain boundary energy / nanocrystalline / ceramics / 超塑性
Research Abstract

The characteristics of microstructural evolution by the cooperative motion of nanocrystalline ceramics were investigated in order to study the mechanical principles which are common to the deformation by cooperative motion of cell structure aggregate, for example, foams, cells and nanocrystalline ceramics. We studied the possibility for the prediction and the control of the microstructural evolution through constructing a three-dimensional topological model for computer. The results are summarized as follows,
1)The deformations of 3 mol%Y_2O_3-stabilized tetragonal ZrO_2 polycrystals(Y-TZP)and single crystal of ZrO_2 were studied as a model material for analyzing the characteristics of microstructural evolution by motion of nanocrystalline ceramics. The yield stress(240 MPa)of tetragonal single crystal was much larger than the flow stress of Y-TZP(20 MPa). It is concluded that the dislocation motion does not play an important role in superplasticity of Y-TZP.
2)Three dimensional simulation was conducted to study the dynamic topological transformation in superplasticity. The simulation clearly demonstrated that the deformation wad induced by grain boundary sliding, in which the grain switching is processes of formation of contact and separation of grains.
3)The topology of grain boundary network is modified by the motion of grain boundary which is drived by curvature of grain boundary. The three-dimensional simulation showed that the boundary network approached a steady structure. We demonstrated the topological correlations on the shapes of neighboring cells, the Aboav-Weaire law and the Neumann-Mullins law on the kinetics of grain growth. Furthermore, we proposed a new concept of grain growth based on the statistics of disappearing grains.

Report

(4 results)
  • 2000 Annual Research Report   Final Research Report Summary
  • 1999 Annual Research Report
  • 1998 Annual Research Report
  • Research Products

    (40 results)

All Other

All Publications (40 results)

  • [Publications] F. Wakai, Y. Shinoda, S.Ishihara and A. Dominguez-Rodriguez: "Topological transformation of grains in three-dimensional normal grain growth"J. Mater. Res.. 16[7]. 2136-2142 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] F. Wakai, Y. Shinoda, S. Ishihara and A. Dominguez-Rodriguez: "Statistics of grain disappearance in three-dimensional normal grain growth"Phil. Mag. B. 81. 517-524 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H. Ogawa, N. Sawaguchi and F. Wakai: "A Molecular dynamics study of large deformation of nanocrystalline materials"Mater. Sci. Forum. 257-259. 571-576 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] A. Munoz, F. Wakui and A. Dominguez-Rodriguez: "High Temperature plastic deformation of a tetragonal Y_2O_3-stabilized ZrO_2 single crystals"Scripta mater.. 44. 2551-2555 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] F. Wakui, N. Enomoto, and H. Ogawa: "Three-dimensional microstructural evolution in ideal grain growth - general statistics"Acta mater. 48. 1297-1311 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] F. Wakui: "Ceramics Superplasticity - New Properties from Atomic Level Processing"Mater. Res. Soc. Symp. Proc.. 601. 163-168 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] F. Wakui, N. Kondo and Y. Shinoda: "Ceramics Superplasticity"Current Opinion in Solid State and Materials Science. 4. 461-465 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H. Ogawa, N. Sawaguchi and F. Wakui: "A molecular dynamic study of plastic deformation of ceramics polycrystals at high temperature"Trans. Mater. Res. Soc. Japan. 24. 253-256 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] F. Wakui and H. Ogawa: "Movement of nanocrystalline grains in superplasticity"Key Eng. Mater.. 166. 153-156 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] F. Wakui, and H. Ogawa: "Geometrical Change of Grains in Superplasticity"Proc. Plasticity '99: 7th Int. Sym. Plasticity and Its Current Applications. 1045-1048 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H. Gu and F. Wakui: "Segregation and local structure at grain boundaries in SiO_2 doped tetragonal ZrO_2 polycrystalline materials"J. Mater. Syn. Process.. 6. 393-399 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] F.Wakai, Y.Shinoda, S.Ishihara and A.Dominguez-Rodriguez: "Topological transformation of grains in three-dimensional normal grain growth"J.Mater.Res.. 16[7]. 2136-2142 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] F.Wakai, Y.Shinoda, S.Ishihara and A.Dominguez-Rodriguez: "Statistics of grain disappearance in three-dimensional normal grain growth"Phil.Mag.. B81. 517-524 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Ogawa, N.Sawaguchi and F.Wakai: "A molecular dynamics study of large deformation of nanocrystalline materials"Mater.Sci.Forum. 257-259. 571-576 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] A.Munoz, F.Wakai and A.Dominguez-Rodriguez: "High temperature plastic deformation of a tetragonal Y_2O_3-stabilized ZrO_2 single crystals"Scripta mater.. 44. 2551-2555 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] F.Wakai, N.Enomoto and H.Ogawa: "Three-dimensional microstructural evolution in ideal grain growth-general statistics"Actamater.. 48. 1297-1311 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] F.Wakai: "Ceramics Superplasticity-New Properties from Atomic Level Processing"Mater.Res.Soc.Symp.Proc.. 601. 163-168 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] F.Wakai, N.Kondo, and Y.Shinoda: "Ceramics superplasticity"Current Opinion in Solid State and Materials Science. 4. 461-465 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Ogawa, N.Sawaguchi and F.Wakai: "A molecular dynamic study of plastic deformation of ceramic polycrystals at high temperature"Trans.Mater.Res.Soc.Japan. 24. 253-256 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] F.Wakai and H.Ogawa: "Geometrical change of grains in superplasticity"Proc.Plasticity '99 : 7^<thp> Int.Sym.Plasticity and Its Current Applications. 1045-1048 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Gu and F.Wakai: "Segregation and local structure at grain boundaries in SiO_2-doped tegtragonal ZrO_2 polycrystalline materials"J.Mater.Syn.Process.. 6. 393-399 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] F.WAKAI et al.: "Ceramics Superplasticity"Current Opinion on Solid State & Materials Science. 4. 461-465 (1999)

    • Related Report
      2000 Annual Research Report
  • [Publications] F.Wakai et.al.: "Three Dimensional Microstructural Evolution in 1deal Grain Growth-General Statistics"Acta mater.. 48. 1297-1311 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 若井史博: "流動するナノ世界"化学工業. 52[1]. 22-28 (2001)

    • Related Report
      2000 Annual Research Report
  • [Publications] 若井史博: "流動するナノ世界=スーパーセラミックスへの挑戦"源流. 3. 1-6 (2001)

    • Related Report
      2000 Annual Research Report
  • [Publications] 若井史博: "ナノ世界のセラミックス超塑性"マテリアルインテグレーション. 14[1]. 29-34 (2001)

    • Related Report
      2000 Annual Research Report
  • [Publications] F.Wakai et al.: "Fabrication of Nanograined Silicon Carbide gy Ultrahigh-Pressure Hot Isostatic Pressing"J.Am.Ceram.Soc.. 82・3. 771-773 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] F.Wakai et al.: "Detection of Boron Segregation to Grain Boundaries in Silicon Carbide by Spatially Resolved Electron Energy-Loss Spectroscopy"J.Am.Ceram.Soc.. 82・2. 469-472 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] F.Wakai et al.: "Change in Stress Sensitivity and Activation Energy during Superplastic Deformation of Silicon Nitride"Mater.Sci.Engn.. A268. 141-146 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] F.Wakai et al.: "Superplasticity of Silicon Carbide"J.Am.Ceram.Soc.. 82[10]. 2916-2918 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] F.Wakai et al.: "A Molecular Dynamic Study of Plastic Deformation of Ceramics Polycrystals at High Temperature"Trans Mater.Res.Soc.Japan. 24[2]. 253-256 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Ed.J.Bill,F.Wakai and F.Aldinger: "Precursor Derived Ceramics"Wiley-VCH. 298 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] E.Yasuda,F.Wakai,L.M.Manocha,Y.Tanabe: "Time Dependent Mechanical Response of Engineering Caramics"Trans Tech Publication. 160 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] F.Wakai et al.: "Indentation Cracks in Superplastically Deformed Silicon Nitride Consisting of Strongly Aligned Rod-shaped Grains" Mater.Sci.Eng.A244. 161-167 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] F.Wakai et al.: "Deformation Conditions of β-SiAION to Achieve Large Superplastic Flongation" J.Ceram.Soc.Japan. 106[10]. 1040-1042 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] F.Wakai et al.: "Geometrical Microstructural Development in Superplastic Silicon Nitride with Rod-Shaped Grains" J.Am.Ceram.Soc.81,[12]. 3227 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] F.WAKAI et al.: "Compressive Deformation of Liquid-phase Sintered Silicon Carbide at Flevated Temperature:" Superplasticity and Superplastic Forming 1998.247-256 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Hui GU and Fumihiro WAKAI: "Segregation and Local Structure at Grain Boundaries in SiO2-Doped Tetragonal ZrO2 Polycrystalline Materials" Materials Synthesis and Processing,Plenum. 9751-9757 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] F.WAKAI et al: "Ceramics Superplasticity" Proc.Special Symp.On Advanced Materials. 433-436 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] F WAKAI and Hiroshi OGAWA: "Geometrical Change of Grains in Superplasticity" Proc.Plasticity'99 : 7th Int.Sym.Plasticity and Its Current Applications.(Neat Press). 1045-1048 (1999)

    • Related Report
      1998 Annual Research Report

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Published: 1998-04-01   Modified: 2016-04-21  

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