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Strong Solid Bases for Organic Synthesis

Research Project

Project/Area Number 10450301
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field 触媒・化学プロセス
Research InstitutionTokyo Institute of Technology

Principal Investigator

BABA Toshihide (1999)  Tokyo Institute of Technology, Graduate School o Science and Engineering, Associate Professor, 大学院・理工学研究科, 助教授 (50165057)

小野 嘉夫 (1998)  東京工業大学, 大学院・理工学研究科, 教授 (10016397)

Co-Investigator(Kenkyū-buntansha) SUZUKI Eiichi  Tokyo Institute of Technology, Graduate School o Science and Engineering, Associate Professor, 大学院・理工学研究科, 助教授 (90183417)
馬場 俊秀  東京工業大学, 工学部, 助教授 (50165057)
Project Period (FY) 1998 – 1999
Project Status Completed (Fiscal Year 1999)
Budget Amount *help
¥7,200,000 (Direct Cost: ¥7,200,000)
Fiscal Year 1999: ¥2,100,000 (Direct Cost: ¥2,100,000)
Fiscal Year 1998: ¥5,100,000 (Direct Cost: ¥5,100,000)
KeywordsBase catalysis / Strong solid base / Base strength / Organic synthesis / C-C bond formation / Si-C C-C bond formation / アニオン / アニソン / カルボアニオン / カリウムアミド / シリルアセチレン / ノーアルキン
Research Abstract

Active sites (centers) of solid-base play important roles of (1) the abstraction of protons from the reactants, (2) activation of reactants without proton abstraction and (3) cooperative action of acidic and basic sites. In present short review, the roles (1) and (2) were focused to understand the catalysis by strong solid-bases such as KNHィイD22ィエD2 on alumina and KF on alumina, respectively. The preparation and characterization of these catalysts were described. To extend utility of the strong solid-base catalysts, they were applied to various reactions including the isomerization of alkenes and alkynes, the dimerization of alkynes, Tishchenko reaction, and the formation of Si-C, Si-N and Si-O bonds.

Report

(3 results)
  • 1999 Annual Research Report   Final Research Report Summary
  • 1998 Annual Research Report
  • Research Products

    (25 results)

All Other

All Publications (25 results)

  • [Publications] E. Suzuki, Y. Ono: "Disproportionation of triethoxysilane over kF/AL_2O_3 and heat-treated hydrotalcite"Applied Catalysis General. 166. 419-424 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T. Baba, Y. Ono: "Catalytic Si-C bond formation by nucleophilic substitution at silicon by benzyl anions generated over KNH_2 loaded on alumina"Catalysis Letters. 50. 83-85 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T. Baba, Y. Ono: "H-D Exchange between methane and deuteriated potassium amide supported on alumina"Journal of Chemical Society Faraday Transaction. 94. 451-456 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T. Baba, Y. Ono: "Metathesis of Silylalkynes and Cross-Metathesis of Silylalkyne and 1-Alkyne over Solid-Base"Journal of Catalysis. 176. 488-496 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T. Baba, Y. Ono: "Highly efficient self-condensation of benzaldehyde to benzyl benzoate over KF-loaded alumina"Journal of Nuclear Catalysis. 134. 171-177 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T. Baba, Y. Ono: "New si-C Bond Forming Reactions over Solid-base Catalysts"Catalysis Today. 44. 271-276 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T. Baba, A. kato, H. Yuasa, Y. Ono: "Metathesis of Siliylalkynes and Cross-Metathesis of siliylalkyne and 1-Alkyne over Solid-Base Catalysts"J. Catal.. 176. 488-494 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Haruhisa Handa, Toshihide Baba, Hisashi Sugisawa and Yoshio Ono: "Highly Efficient Self-condensation of Benzaldhyde to Benzyl Benzoate over KF-Loaded Alumina"J. Mol. Catal. A, Chemical. 134. 171-177 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Haruhisa Handa, Toshihide Baba, and Yoshio Ono: "H-D Exchange Reaction between Methane and Deuterated Potassium Amide Supported on Alumina"J. Chem. Soc., Faraday Trans.. 94. 541-454 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Toshihide Baba, Hiroko Yuasa, Haruhisa Handa, and Yoshio Ono: "Catalytic Si-C Bond Formation by Nucleophilic Substitution at Silicon by Benzyl Anions Generated over KNHィイD22ィエD2 Loaded on Alumina"Catal. Lett.. 50. 83-85 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Toshihide Baba, Satoru Hikita, Haruhisa Handa, and Yoshio Ono: "Catalytic Property of Europium Supported on Alumina from Its Ammoniacal Solution"Res. Chem. Intermediates. 24. 495-505 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Toshihide Baba, Akiko Kato, Hiroko Yuasa, Fumihiko Toriyama, Haruhisa Handa, and Yoshio Ono: "New Si-C Bond Forming Reactions over Solid-Base Catalysts"Catal. Today. 44. 271-276 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Toshihide Baba, Akiko Kato, Hiroko Yuasa, Fumihiko Toriyama, Haruhisa Handa, and Yoshio Ono: "Metathesis of Siliylalkynes and Cross-Metathesis of Siliylalkyne and 1-Alkyne over Solid-Base Catalysts"J. Catal.. 176. 488-494 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Haruhisa Handa, Yu-e Fu, Toshihide Baba and Yoshio Ono: "Characterization of Strong Solid Base by Test Reactions"Catal. Lett.. 59. 195-200 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Tomoko Yoshida, Tsunehiro Tanaka, Satohiro Yoshida, Toshihide Baba, Hirofumi Hinode and Yoshio Ono: "XAFS Analysis of Europium Species Supported on Alumina Oxide Surface"Appl. Surf. Sci.. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Toshihide Baba, Hisashi Kizuka, Haruhisa Handa and Yoshio Ono: "Reaction of Ketones or Aldehydes with 1-Alkynes over Solid-Base Catalysts"Appl. Catal. A, Gneral. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Haruhisa Honda,Yu-e Fu.,Toshihide BABA,Yosio ONO: "Characterization of Stnng Base by Test Reactions"Catal.Lett.. 59. 195-200 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Toshihide BABA,Hisashi Kizuka,Haruhisa Honda,Yoshio Ono: "Reactions of Kefones of Alderydes with 1-Alkynes over solid-Base Catalysts"Appl.Catal.A.General. (in press).

    • Related Report
      1999 Annual Research Report
  • [Publications] Yoshio ONO,Toshihide BABA: "Strong Base Catalysis"Catalysis…. (in press).

    • Related Report
      1999 Annual Research Report
  • [Publications] E,Suzuki Y.Ono: "Disproportionation of triethoxysilane over KF/Al_2O_3 and heat-treated hydrotalcite" Applied Catalysis General. 166. 419-424 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] T.Baba Y.Ono: "Catalytic Si-C bond formation by nucleophilic substitution at silicon by benzyl anions generated over KNH_2 loaded on alimina" Catalysis Letters. 50. 83-85 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] T.Baba Y.Ono: "H-D Exchange between methane and deuteriated potassium amide supported on alumina" Journal of Chemicul Society Faradoy Transaction. 94. 451-454 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] T,Baba Y.Ono: "Metathesis of Silylakynes and Cross-Metathesis of Silylalkyne and 1-Alkyne over Solid-Base Catalysts" Journal of Catalysis. 176. 488-494 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] T.Baba Y.Ono: "Highly efficient self-condensation of benzaldehyde to benzyl benzoate over KF-loaded alumina" Journal of Molecular Catalysis. 134. 171-177 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] T.Baba Y.Ono: "New Si-C Bond Forming Reactions over Solid-base Catalysts" Catalysis Today. 44. 271-276 (1998)

    • Related Report
      1998 Annual Research Report

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Published: 1998-04-01   Modified: 2016-04-21  

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