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Conversion of waste fish meat to bio-degradable plastics poly lactic acid by sub-critcal water oxidation

Research Project

Project/Area Number 10480147
Research Category

Grant-in-Aid for Scientific Research (B).

Allocation TypeSingle-year Grants
Section一般
Research Field 環境保全
Research InstitutionOsaka Prefecture University

Principal Investigator

YOSHIDA Hiroyuki  Osaka Prefecture Univ., Chem.Eng., Professor, 工学研究科, 教授 (50081360)

Co-Investigator(Kenkyū-buntansha) TERASHIMA Masaaki  Osaka Prefecture Univ., Chem.Eng., Associate Prof., 大学院・工学研究科, 助教授 (30172092)
SHIGETA Takeshiro  Osaka Prefecture Univ., Chem.Eng., Instructor, 大学院・工学研究科, 助手 (20316011)
Project Period (FY) 1998 – 2000
Project Status Completed (Fiscal Year 2000)
Budget Amount *help
¥12,300,000 (Direct Cost: ¥12,300,000)
Fiscal Year 2000: ¥1,600,000 (Direct Cost: ¥1,600,000)
Fiscal Year 1999: ¥3,400,000 (Direct Cost: ¥3,400,000)
Fiscal Year 1998: ¥7,300,000 (Direct Cost: ¥7,300,000)
Keywordssub-critcal water / recombinant protein / fish entrail / lactic acid / amino acid / phosophoric acid / conversion to resource / DHA / 加水分解 / 魚腸骨 / イオン交換樹脂 / 有機酸 / 吸着分離 / 資源化技術 / 廃魚肉 / 超臨界水 / 生分解性プラスチック
Research Abstract

Production of various organic substances from fish bone, fish head, fish meat and fish entrails by sub-critical water hydrolysis was studied. Optimal reaction was determined for each product. Adsorption equilibrium and mass transfer of organic acid in ion exchange resins (DIAION WA30 and highly porous chitosan resin) were also studied. The following significant results were obtained from the research on conversion of waste fish meat, entrails, and bones.
(1) From 100 ton fish bone, 0.64 ton of phosphoric acid, 0.44 ton of lactic acid was extracted by 5 min reaction at 473 K.Then, 25 ton of bone, 1.7 ton of pyroglutamic acid, 0.8 ton of alanine, 0.8 ton of glycine, 0.5 ton of cystine, and 1.8 ton of oil were obtained by sub-critical water hydrolysis at 543 K for 20 min. From 100 ton of fish head, 1.5 ton of bone, 0.23 ton of pyroglutamic acid, 0.07 ton of phosphoric acid, 4.9 ton of oil, and 0.2 ton of fat were obtained.
(2) Oil contained valuable and expensive unsaturated fatty acids such as DHA and EPA.
(3) Since optimal reaction temperature depends on the type of products, an integrated process which produce different product successively at different reaction temperature can be established.
(4) Adsorption isotherm of lactic acid for DIAION WA30 ion exchanger and that for chitosan bead were well explained by Langmuir equation.
(5) Intra-particle diffusion of lactic acid was explained parallel transport by solid-phase and macropore diffusion. Since adsorption rate of the chitosan bead was much larger than that of the DIAION WA30, the chitosan bead was favorable for separation of organic acids.

Report

(4 results)
  • 2000 Annual Research Report   Final Research Report Summary
  • 1999 Annual Research Report
  • 1998 Annual Research Report
  • Research Products

    (36 results)

All Other

All Publications (36 results)

  • [Publications] H.Yoshida and W.Takatsuji: "Parallel transport of an organic acid by solid-phase and macropore diffusion in a weakly basic ion exchanger"Ind.& Eng.Chem.Res.. 39・4. 1074-1079 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Yoshida and W.Takatsuji: "Adsorption of H_3PO_4, NaH_2PO_4, Na_2HPO_4, and Na_3PO_4 on strongly basic ion exchanger"Proc.of the Second Pacific Basin Conference on Adsorption Science and Technology. 698-702 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Yoshida and M.Atarashi: "Conversion of entrails of fish waste to variable resources by sub-critical water hydrolysis"Proc.of Joint Sixth International Symposium on Hydrothermal Reaction & Fourth International Conference on Solvo-Thermal Reactions. 136 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Yoshida,Y.Takahashi and M.Terashima: "Reaction kinetics in production of oil, proteins, organic acids and amino acids from fish meat by sub-critical water hydrolysis"Proc.of Joint Sixth International Symposium on Hydrothermal Reaction & Fourth International Conference on Solvo-Thermal Reactions. 202 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] 吉田弘之,重田武史郎,岡本織江: "PEIキトサン樹脂によるピログルタミン酸の吸着"日本吸着学会・日本溶媒抽出学会連合年会要旨集. 80 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] 吉田弘之,重田武史郎: "魚あらの亜臨界水加水分解によるDHA、EPAの生成"化学工学会第33回秋季大会講演要旨集. U121 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Yoshida and W.Taktsuji: "Parallel transport of an organic acid by solid-phase and macropore diffusion in a weakly basic ion exchanger"Ind.& Eng.Chem.Res.. 1074-1079 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Yoshida and W.Takatsuji: "Adsorption of H_3PO_4, NaH_2PO_4, Na_2HPO_4, and Na_2PO_4 on strongly basic ion exchanger"Proc.of the Second Pacific Basin Conference on Adsorption Science and Technology. 698-702 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Yoshida and M.Atarashi: "Conversion of entrails of fish waste to variable resources by sub-critical water hydrolysis"Proc.of Joint Sixth International Symposium on Hydrothermal Reaction & Fourth International Conference on Solvo-Thermal Reactions. 136 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Yoshida, Y.Takahashi, and M.Terashima: "Reaction kinetics in production of oil, proteins, organic acids and amino acids from fish meat by sub-critical water hydrolysis"Proc. of Joint Sixth International Symposium on Hydrothermal Reaction & Fourth International Conference on Solvo-Thermal Reactions. 202 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Yoshida, T.Shigeta, and O.Okamoto: "Adsorption of pyroglutamic acid on PEI chitosan resin"Proc.of Joint Meeting of Japan Adsorption Society and Japan Solvent Extraction Society. 80 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Yoshida and T.Shigeta: "Production of DHA and EPA from fish entrail by subcritical water hydrolysis"Proc.of Autamn Meeting of Society of Chemical Engineers Japan. U121 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Yoshida and W.Takatsuji: "Parallel Transport of an Organic Acid by Solid-Phase and Macropore Diffusion in a Weakly Basic Ion Exchanger."Ind.& Eng.Chem.Res.. 39・4. 1074-1079 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] H.Yoshida and W.Galinada: "Adsorption of H_3PO_4, NaH_2PO_4, Na_2HPO_4, and Na_3PO_4 on Strongly Basic Exchanger."Proc.Of the Second Pacific Basin Conference on Adsorption Science and Technology. 698-702 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] H.Yoshida and M.Atarashi: "Conversion of Entrails of Fish Waste to Variable Resources by Sub-Critical Water Hydrolysis."Proc.of Joint Sixth International Symposium on Hydrothermal Reactions & Fourth International Conference on Solvo-Thermal Reactions. 136 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] H.Yoshida,Y.Takahashi,and M.Terashima: "Reaction Kinetics in Production of Oil, Proteins, Organic Acids and Amino Acids from Fish Meat by Sub-Critical Water Hydrolysis."Proc.of Joint Sixth International Symposium on Hydrothermal Reactions & Fourth International Conference on Solvo-Thermal Reactions. 202 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 吉田弘之,重田武史郎,岡本織江: "PEIキトサン樹脂によるピログルタミン酸の吸着"日本吸着学会・日本溶媒抽出学会連合年会要旨集. 80 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 吉田弘之,重田武史郎: "魚あらの亜臨界水加水分解によるDHA,EPAの生成"化学工学会第33回秋季大会講演要旨集. U121 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] H. Yoshida et al.: "Production of Organic Acids and Amino Acids from Fish Meat by Sub-Critical Water Hydrolysis"Biotechnol. Prog.. 15, No.6. 1090-1094 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] H. Yoshida et al.: "Removal of Salt and Organic Acids from Solution Used to Season Salted Japanese Apricots (Ume) by Electrodialysis, Precipitation and Adsorption"J. Bioscience and Bioengineering. 88, No3.. 348-351 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] H. Yoshida et al.: "Parallel Transport of Organic Acid by Solid Phase and Macropore Diffusion in Weakly Basic Ion Exchanger"第5回日韓分離技術国際シンポジウム(ソウル)要旨集. 609-612 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] H. Yoshida et al.: "Highly Selective Adsorption of Glutamic Acid on Polyaminated Highly Porous Chitosan Resin: Equilibria in Binary Component System"第5回日韓分離技術国際シンポジウム(ソウル)要旨集. 626-629 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] H. Yoshida: "Output/Input Database and Conversion Technology"International Conference on Zero Emissions in Industrialized Society Abstract Book (Tokyo,Japan). 2-2-1-2-2-17 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] H. Yoshida(invited): "Clustering of Production Processes and Developments of Network Technologies"ゼロエミッション国際シンポジウム要旨集(豊橋). 15-18 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 吉田弘之: "いま「共生」の時代へ 五つのキーワード ゼロエミッション 生産現場に求められる資源・環境との共存"化学. 54, No.1. 24-26 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 吉田弘之: "特集 ゼロエミッションを目指す産業システム 亜臨界水加水分解による魚あらの高速高度資源化"化学工業. 50, No.2. 145-149 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 吉田弘之: "亜臨界水加水分解による魚あらのゼロエミッション型資源化技術"Jasco Report, 超臨界最新技術特集. 第3号. (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 吉田弘之: "トピックス 亜臨界水加水分解による魚あらの高速高度資源化"BSE 特研ニュース. 9, No.1. (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 吉田弘之: "展望 ゼロエミッション型産業社会"ウルトラクリーンテクノロジー. 11, No.5. 302-303 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 吉田弘之: "産業と行政 ゼロエミッションを目指した産業間ネットワーク"バイオサイエンスとインダストリー. 57, 10. 704-707 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 吉田弘之(分担): "化学工学便覧 改定六版 13 吸着・イオン交換"化学工学会編 丸善. 1339 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 吉田弘之(分担): "基礎化学工学"化学工学会編 培風館. 308 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 吉田弘之(分担): "最新吸着技術便覧 -プロセス・材料・設計-"エヌ・ティー・エス. 867 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] H.Yoshida et al.: "Adsorption of Organic Acids on Polyaminated Highly Porous Chitosan: Equilibria." Ind.Eng.Chem.Res.37, No.4. 1300-1309 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] H.Yoshida et al.: "Adsorption of Organic Acids on Weakly Basic Ion Exchanger: Equilibria for Binary Systems." AIChE J.44, No.5. 1216-1221 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 吉田弘之: "業種を越えた生産プロセスのネットワーク形成によるゼロエミッション化の検討" 環境科学会誌. 11・2. 243 (1998)

    • Related Report
      1998 Annual Research Report

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Published: 1998-04-01   Modified: 2016-04-21  

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