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THE FORMATION AND APPLICATION OF NOVEL MICROPOROUS COMPLEXES

Research Project

Project/Area Number 10554041
Research Category

Grant-in-Aid for Scientific Research (B).

Allocation TypeSingle-year Grants
Section展開研究
Research Field 機能・物性・材料
Research InstitutionKANAGAWA UNIVERSITY

Principal Investigator

MORI Wasuke  KANAGAWA UNIVERSITY FACULTY OF SCIENCE PROFESSER, 理学部, 教授 (60029709)

Co-Investigator(Kenkyū-buntansha) SEKI Kennji  OSKA GAS CO.LTD.RESEACH AND DEVELOPMENT PROJECT LEADER, 研究開発部, 主任研究員
TAKEDA Sadamu  HOKKAIDOU UNIVERSITY FACULTY OF SCIENCE PROFESSER, 理学部, 教授 (00155011)
NISHIMOTO Yuko  KANAGAWA UNIVERSITY FACULTY OF SCIENCE ASSISTANT PROFESSER, 理学部, 助手 (70241114)
Project Period (FY) 1998 – 2000
Project Status Completed (Fiscal Year 2000)
Budget Amount *help
¥14,700,000 (Direct Cost: ¥14,700,000)
Fiscal Year 2000: ¥3,000,000 (Direct Cost: ¥3,000,000)
Fiscal Year 1999: ¥4,900,000 (Direct Cost: ¥4,900,000)
Fiscal Year 1998: ¥6,800,000 (Direct Cost: ¥6,800,000)
Keywordsgas occlusion / microporous substance / trasition-metal dicarboxylates / ジカルボン酸錯体 / 細孔 / マイクロポアー物質 / 気体吸蔵 / 気体貯蔵 / ジカルボン酸銅(II) / 工業的利用
Research Abstract

The dinuclear transition-metal dicarboxylates (Cu(II), Mo(II), Ru(II,III) ) reversibly occlude a large amount of gases such as N_2, 0_2, Ar, and CH_4. It was concluded that the gas molecules are occluded in uniform micropores constracted by transition-metal complexes. The complexes are useful adsorbent for storing gases, and may be useful catalyst for chemical reactions.

Report

(4 results)
  • 2000 Annual Research Report   Final Research Report Summary
  • 1999 Annual Research Report
  • 1998 Annual Research Report
  • Research Products

    (75 results)

All Other

All Publications (75 results)

  • [Publications] S.Takamizawa,M.Furihata,S.Takeda,K.Yamaguchi,and W.Mori: "A Novel Inclusion Complex between Molybdenum (II) Fumarate and Poly (ethylene glycol)"Polymers for Advanced Technology. 11. 840-844 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] W.Mori,H.Hoshino,K.Horikawa,Y.Nishimoto,and S.Takamizawa: "Synthesis and gas occlusion of rhodium (II) benzoate bridged by nitrogen donor ligands"Molecular Crystals and liquid Crystals. 342. 193-198 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Takamizawa,T.Ohmura,K.Yamaguchi,and W.Mori: "Synthesis and gas-occlusion properties of ruthenium (II, III) dicarboxylate bridged by halogen atoms"Molecular Crystals and liquid Crystals. 342. 199-204 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Takamizawa,W.Mori,Y.Yokomichi,Y.Kitagawa,T.Maruta,T.Kawakami,Y.Yoshioka,and K.Yamaguchi: "Molecular Simulations of Argon, Nitrogen, and Hydrogen Adsorption in Microporous Complexes"Molecular Crystals and liquid Crystals. 342. 258-290 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] T.Kawakami,S.Takamizawa,Y.Kitagawa,W.Mori,K.Yamaguchi and K.Katsumata: "Theoretical Studies on Radical Spin Arrangements in the Cavity of Microporous Complexes",, Mol.Cryst.Liq.Cryst., 343, (2000)."Molecular Crystals and liquid Crystals. 343. 215-220 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] W.Mori and S.Takamizawa: "Microporous Materials of Metal Carboxylates"Journal of Solid State Chemistry. 152. 120-129 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Takamizawa,M.Furihata,S.Takeda,K.Yamaguchi,and W Mori: "Synthesis and Characterization of a Novel Inclusion Complexes between Microporous Moybdenum (II) Dicarboxylates and Organic Polymers"Macromolecules. 33. 6222-6227 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Kamiguchi,T.Saito,and W.Mori: "Magnetic properties of the octahedral chromium chalcogenide cluster complexes [Cr_6Se_8(PEt_3)_6], [Cr_6Se_8(H)(PEt_3)_6], and [Cr_6Se_8(H)(PEt_3)_6]"Bulletin of Chemical Society of Japan. 73. 2487-2491 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Emori,M.Nakashima,and W.Mori: "Magneto-structural correlations in phenooxo-bridged metal (II) compounds..Magnetic properties of (R_4N)_2[Co_2Cl_4(4-XC_6H_4O)_2(X=H, CH_3; R=CH_3, C_2H_5)"Bulletin of Chemical Society of Japan. 73. 81-84 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] K.Asano,Y.Miyazaki,W.Mori,K.Nakatani,O.Kahn,and M.Sorai: "Calorimetric and magnetic studies on a ferromagnetic phase trasition of the metaiassembled complex MnCu(obbz)・H_2O"Bulletin of Chemical Society of Japan. 73. 885-893 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Ohtsu,Y.Shimazaki,A.Odani,O.Yamauchi,W.Mori,S.Itoh,and S.Fukuzumi,: "Synthesis and chracterization of imidazolate-bridged dinuclear complexes as active site model of Cu,Zn-SOD,"Journal of American Chemical Society. 122. 5733-5741 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tanaka,K.Mashima,M.Nishino,S.Takeda,W.Mori,K.Tani,K.Yamaguchi,and A.Nakamura: "Unique Axial interaction of a Quadruply-Bonded Cr(II)-Cr(II) with Two Pt(II) Atoms in the Linearly Aligned Pt-Cr-Cr-Pt Supported by Four 6-Diphenylphosphino-2-pyridinate Ligands"Bulletin of Chemical Society of Japan. 74. 67-75 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Mimura, T.Matsuo, N.Matsumoto, S.Takamizawa, W.Mori, and N.Re: "Bis[(methanol){N-salicylidene-N^1-(2-phenylimidazol-4-ylmethylidene)-1,3 propanediaminato}nickel (II)] Bridged by Di-μ-phenoxo Moiety and the Deprotonated Imidazolate-Bridged Cyclic-Tetranuclear Complex."Bull.Chem.Soc.. 71. 1831-1837 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Mori, M.Nakano, H.Tamura, Gen-etsu Matsubayashi, and W.Mori: "Paramagnetic Organocobalt (III) Dithiolate complex : Crystal Structure and Magnetic Property of [Co (η^5-C_5Me_5)(C_3S_5) Br]."Chem.Lett.. 729-730 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Takamizawa, K.Yamaguch, W.Mori: "The gas-occlusion properties of dicalboxylate (fumarate, trans-trans-muconate and terephthalate) ruthenium (II) dinucler complexes."Inorg.chem.Comm.. 1. 177-178 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Takamizawa, W.Mori, M.Furihata, S.Takeda, and K.Yamaguchi: "Synthesis and gas-occlusion properties of dinuclear molybdenum (II) dicarboxylate (fumarate, trans-trans-muconate pyridine-2,5-dicarboxylate, and trans-1,4-cvclohexanedicarboxylate)"Inorg.Chim.Scta.. 283. 268-274 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Y.Hosokawa, H.Yamane, Y.Nakao, K.Matsumoto, S.Takamizawa, W.Mori, S.Suzuki, H.Kimoto: "Synthesis, structure and characterizition if dinuclear nickel (II) complexes containing the derivatives of N, N, N', N'-tetrakis [(2-benzimidazolyl)methyl]-2-hydroxy-1,3-diaminopropane and an acetate or a propoinatc ion"Inorg.Chim.Acta.. 283. 118-123 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Hirotsu, M.Kojima, W.Mari, and Y.Yoshikawa: "Steric control of polynuclear manganese complexes by the use of tripodal tetradentate ligand"Bull.Chem.Soc.Japan.. 71. 2873-2884 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Y.Nishida, A.Yatani, Y.Nakao, J.Taka, S.Kashino. W.Mori, and S.Suzuki: "The formation of a hydrogencarbonato-bridged dinuclear copper (II) complex by fixation and activation of atmospheric C0_2"Chem.Lett.. 135-136 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Hirotsu, M.Kojima, W.Mori, and Y.Yoshikawa: "Heteronuclear FeIIIMnIIFeIII and homonuclear FeIIIFeIIIFeIII complexes with a tripodal tetra dentate ligand"Chem.Lett.. 229-230 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] W.Mori, H.Hoshino, Y.Nishimoto, and S.Takamizawa: "Synthesis and gas occlusion of new micropore substance rhodium (II) carboxylates bridged by pyrazine"Chem.Lett.. 331-332 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] R.Nukada, W.Mori, S.Takamizawa, M.Mikuriya, M.Handa, and H.Naono: "Microporous structure of a chain compound of copper (II) benzoate bridged by pyrazine"Chem.Lett.. 367-368 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Maekawa, S.Kitagawa, Y.Nakao, S.Sakamoto, A.Yatani, W.Mori, S.Kashino, and M.Munakata: "Synthesis, crystal structures and autoreduction behavior of antiferromagnetically coupled dicopper (II) oximato complexes"Chim.Acta.. 293. 20-29 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Emori, M.Nakashima, and W.Mari: "Magneto-structural correlations in phenooxo-bridged metal (II) compounds. Magnetic properties of (R_4N)_2[C0_2Cl_4(4-XC_6H_4O)_2(X=H, CH_3 ; R=CH_3, C_2H_5)"Bull.Chem.Soc.. 73. 81-84 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] K.Asano, Y.Miyazaki, W.Mori, K.Nakatani, O.Kahn, and M.Sorai: "Calorimetric and magnetic studies on a ferromagnetic phase trasition of the metal-assembled complex MnCu (obbz) H_2O"Bull.Chem.Soc.. 73. 885-893 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Ohtsu, Y.Shimazaki, A.Odani, O.Yamauchi, W.Mori, S.Itoh, and S.Fukuzumi: "Synthesis and chracterization of imidazolate-bridged dinuclear complexes as active site models of Cu, Zn-SOD"J.Am.Chem.Soc.. 122. 5733-5741 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] W.Mari, S.Takamizawa: "Microporous materials of metal carboxylates"J.Solid State Chemistry. 153. 120-129 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] W.Mori, H.Hoshino, K.Horikawa, Y.Nishimoto, and S.Takamizawa: "Synthesis and gas occlusion of rhodium (II) benzoate bridged by pyrazine derivatives"Mol.Cryst.Liq.Cryst.. 342. 193-198 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Takamizawa, T.Ohmura, K.Yamaguchi, and W.Mori: "Synthesis and gas-occlusion properties of ruthenium (II, III) dicarboxylates (fumarate, trans, trans-muconate and terephthalate) bridged by halogen atoms"Mol.Cryst.Liq.Cryst.. 342. 199-204 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Taksmizawa, W.Mori, Y.Yokomichi, Y.Kitagawa, T.Muruta, T.Kawakami, Y.Yoshioka, and K.Yamaguchi: "Molecular simulation of argon, nitrogen, and hysrogen adosorption in microporous complexes, S.Taksmizawa, W.Mori, Y.Yokomichi, Y.Kitagawa, T.Muruta. T.Kawakami.Y.Yoshioka"Mol.Cryst.Liq.Cryst.. 342. 285-290 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] T.Kawakami, S.Takamizawa, Y.Kitagawa, F.Matsuoka, T.Maruta, W.Mori, K.Yamaguchi: "Theoretical studies on radical spin arrangements in the cavity of nanoporous complexes"Mol.Cryst.Liq.Cryst.. 343. 215-220 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Takamizawa, M.Furihata, S.Takada, K.Yamagychi, and W.Mori: "Synthesis and characterization of novel inclusion compexes between microporous molybdenum (II) dicarboxylatea and organic polymers"Macromolecules. 33. 6222-6227 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Kamiguchi, T.Saito, amd W.Mori: "Magnetic properties of the octahedral chromium chalcogenide cluster complexes [Cr_6Se_8 (PEt_3)_6], [Cr_6Se_8 (H)(PEt_3)_6], and[Cr_6S_8 (H)(PEt_3)_6]"Bull.Chem.Soc.Jpn.. 73. 2487-2491 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Takamizawa, M.Furihata, S.Takeda, K.Yamaguchi, and W.Mori: "A novel inclusion complex between molybdenum (II) fumarate and poly (ethylene glycol) : first supramolecule formation between a microporous complex and an organic polymer"Polym.Adv.Techmol.. 11. 840-844 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Emori, K.Obata, and W.Mori: "Magnetic characterization of di-μ-hydroxobis (ethylenediamine-N, N-diacetato) dichromium (III). Magneto-structural corrilations in hydroxo-bridged chromium (III) complexes"ITE Letters on Batteries, New Technologies & Medicine. 1 Cl. 938 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] M.Tanaka, K.Mashima, M.Nishino, S.Takeda, W.Mori, K.Tani, K.Yamaguchi, and A.Nakamura: "Uniqe axial interaction of a quadruply-bonded Cr (II) -Cr (II) with two Pt (II) atoms in the limearly alegned Pt-Cr-Cr-Pt supported by four 6-diphenylphosphino-pyridomate ligands"Bull.Chem.Soc.Jpn.. 74. 67-75 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Seki, K., Takamizawa, S., Mori, W.: "Characterization of Microporus Copper (II) Dicarboxylates (Fumarate, Terephthalate, and trans-1,4-Cyclohexanedicarboxylate) by Gas Adsorption"Chem.Lett.. (in press.).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Takamizawa,M.Furihata,S.Takeda,K.Yamaguchi,and W.Mori: "A Novel Inclusion Complex between Molybdenum(II) Fumarate and Poly(ethyleneglycol)"Polymers for Advanced Technology. 11. 840-844 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] W.Mori,H.Hoshino,K.Horikawa,Y.Nishimoto, and S.Takamizawa: "Synthesis and gas occlusion of rhodium (II) benzoate bridged by nitrogen donor ligands"Molecular Crystals and liquid Crystals. 342. 193-198 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] S.Takamizawa,T.Ohmura,K.Yamaguchi,and W.Mori: "Synthesis and gas-occlusion properties of ruthenium(II, III) dicarboxylate bridged by halogen atoms"Molecular Crystals and liquid Crystals. 342. 199-204 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] S.Takamizawa,W.Mori,Y.Yokomichi,Y.Kitagawa,T. Maruta,T.Kawakami,Y.Yoshioka,and K.Yamaguchi: "Molecular Simulations of Argon, Nitrogen, and Hydrogen Adsorption in Microporous Complexes"Molecular Crystals and liquid Crystals. 342. 258-290 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] T.Kawakami,S.Takamizawa,Y.Kitagawa,W.Mori,K.Yamaguchi and K.Katsumata: "Theoretical Studies on Radical Spin Arrangements in the Cavity of Microporous Complexes"Molecular Crystals and liquid Crystals. 343. 215-220 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] W.Mori and S.Takamizawa: "Microporous Materials of Metal Carboxylates"Journal of Solid State Chemistry. 152. 120-129 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] S.Takamizawa,M.Furihata,S.Takeda,K.Yamaguchi,and W.Mori: "Synthesis and Characterization of a Novel Inclusion Complexes between Microporous Moybdenum(II) Dicarboxylates and Organic Polymers"Macromolecules. 33. 6222-6227 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] S.Kamiguchi,T.Saito,amd W.Mori: "Magnetic properties of the octahedral chromium chalcogenide cluster complexes [Cr_6Se_8(PEt_3)_6], [Cr_6Se_8(H)(PEt_3)_6], and[Cr_6S_8(H)(PEt_3)_6]"Bulletin of Chemical Society of Japan. 73. 2487-2491 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] S.Emori,M.Nakashima,and W.Mori: "Magneto-structural correlations in phenooxo-bridged metal(II) compounds.. Magnetic properties of(R_4N)_2[Co_2Cl_4(4-XC_6H_4O)_2(X=H,CH_3; R=CH_3,C_2H_5)"Bulletin of Chemical Society of Japan. 73. 81-84 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] K.Asano,Y.Miyazaki,W.Mori,K.Nakatani,O.Kahn,and M.Sorai: "Calorimetric and magnetic studies on a ferromagnetic phase trasition of the metai-assembled complex MuCu(obbz)・H_2O"Bulletin of Chemical Society of Japan. 73. 885-893 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] H.Ohtsu,Y.Shimazaki,A.Odani,O.Yamauchi,W.Mori,S.Itoh,and S.Fukuzumi,: "Synthesis and chracterization ofimidazolate-bridged dinuclear complexes as active site models ofCu,Zn-SOD,"Journal of American Chemical Society. 122. 5733-5741 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] M.Tanaka,K.Mashima,M.Nishino,S.Takeda,W. Mori,K.Tani,K.Yamaguchi,and A.Nakamura: "Unique Axial interaction of a Quadruply-Bonded Cr(II)-Cr(II) with Two Pt(II) Atoms in the Linearly Aligned Pt-Cr-Cr-Pt Supported by Four 6-Diphenylphosphino-2-pyridinate Ligands"Bulletin of Chemical Society of Japan. 74. 67-75 (2001)

    • Related Report
      2000 Annual Research Report
  • [Publications] S. Takamizawa, M. Furihata, S. Takeda, K. Yamaguchi, and W. Mori: "A Novel Inclusion Complex between Molybdenum(II) Fumarate and Poly(ethylene glycol)"Polymers for Advanced Technology. (in press).

    • Related Report
      1999 Annual Research Report
  • [Publications] W. Mori, H. Hoshino, K. Horikawa, Y. Nishimoto, and A. Takamizawa: "Synthesis and Gas Occlusion of Rhodium(II) Benzoate Bridged by Nitrogen donor Ligands"Molecular Crystals and Liquid Crystals. (in press).

    • Related Report
      1999 Annual Research Report
  • [Publications] S. Takamizawa, T. Ohmura, K. Yamaguchi, and W. Mori: "Synthesis and Gas-occlusion Properties of Dicarboxylate Ruthenium(II,III) Bridged by Halogen atoms"Molecular Crystals and Liquid Crystals. (in press).

    • Related Report
      1999 Annual Research Report
  • [Publications] S. Takamizawa, W. Mori, Y. Yokomichi, Y. Kitagawa, T. Maruta, T. Kawakami, Y. Yoshioka, and K. Yamaguchi: "MM, MC and MD Calculation of Gas Adsorption in the Cavity of Microporous Complexes"Molecular Crystals and Liquid Crystals. (in press).

    • Related Report
      1999 Annual Research Report
  • [Publications] T. Kawakami, S. Takamizawa, Y. Kitagawa, W. Mori, K. Yamaguchi and K. Katsumata: "Theoretical Studies on Radical Spin Arrangements in the Cavity of Microporous Complexes"Molecular Crystals and Liquid Crystals. (in press).

    • Related Report
      1999 Annual Research Report
  • [Publications] W. Mori and S. Takamizawa: "Microporous Materials of Metal Carboxylates"Journal of Solid State Chemistry. (in press).

    • Related Report
      1999 Annual Research Report
  • [Publications] R.Nukada, W.Mori, S.Takamizawa, M.Mikuriya, and H.Naono.: "Microporous structure of a chain compound of copper(II) benzoate bridged by pyrazine." Chem.Lett.in press. (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] W.Mori, H.Hoshino, Y.Nishimoto, and S.Takamizawa.: "Synthsis and gas occlusion of new micropore substance rhodium(II) carboxylates bridged by pyrazine." Chem.Lett.in press. (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] Y.Nishida, A.Yatani, Y.Nakao, J.Taka, S.Kashino, W.Mori, and S.Suzuki.: "The formation of a hyrogencarbonato-bridged dinuclear copper(II) complex by fixation and activation of atmospheric CO_2." Chem.Lett.135-136 (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] M.Hirotsu, M.Kojima, W.Mori, and Y.Yoshikawa: "Steric control of polynuclear manganese complexes by the use of tripodal tetradentate ligand." Bull.Chem.Soc.Japan. 71. 2873-2884 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Y.Hosokawa, H.Yamane, Y.Nakao, K.Matsumoto, S.Tamizawa, W.Mori, S.Suzuki, H.Kimoto: "Synthsis, structure and characterizition of dinuclear nickel(II) complexes containing thederivatives of N, N, N', N'-tetrakis[(2-benzimidazolyl)methyl]-2-hydroxy-1,3-diaminopropane and an acetate or a propoinate ion." Inorg.Chem.Acta. 283. 118-123 (1998)

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      1998 Annual Research Report
  • [Publications] S.Takamizawa, W.Mori, M.Furihata, S.Takeda, and K.Yamaguchi: "Synthesis and gas occlusion properties of dinuclear molybdenum(II) dicarboxylate (fumarate, trans-trans-muconate, pyridin-2,5-dicarboxylate, and trans-1,4-cyclohexanedicarboxylate)." Inrog.Chem.Acta. 283. 268-274 (1998)

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      1998 Annual Research Report
  • [Publications] T.Minamisono, T.Ohtsubo, K.Sato, S.Takeda, S.Fukuda, T.Izumikawa, M.Tanigaki, T.Miyake, T.Yamaguchi, N.Nakamura, H.Tanji, K.Matsuta, M.Fukuda, and Y.Nojiri: "“Quadrupole Moment of the Proton Rich b-Emitting Nucleus 12N"," Phys.Lett.B. 420. 31-36 (1998)

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      1998 Annual Research Report
  • [Publications] C.Benedict, U.Langer, H.H.Limbach, H.Ogata, and S.Takeda: "“Observation of Thermal Tautomerism of Thermochromic Salicylydeneaniline Derivatives in the Solid State by 15N-CP/MAS NMR down to Clyogenic Temperature"" Ber.Bunsengesr.Phys.Chem.102. 335-339 (1998)

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      1998 Annual Research Report
  • [Publications] H.Huang, T.Sakurai, H.Monjushiro, S.Takeda,: "Magnetic Studies of the Trinuclear Center in Laccase and Ascorbate Oxidase approached by EPR Spectroscopy and Magnetic Susceptibility"," Biochim.Biophys.Acta,. 1348. 160-170 (1998)

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      1998 Annual Research Report
  • [Publications] K.Sato, S.Takeda, S.Fukuda, T.Minamisono, M.Tanigaki, T.Miyake, Y.Maruyama, K.Matsuta, M.Fukuda, Y.Nojiri,: "“FT-NMR Detection of 45Sc, 49Yi and 93Nb in TiO2 Sibgle Crystal"" Z.Naturforsch.53a. 549-551 (1998)

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      1998 Annual Research Report
  • [Publications] Minamisono, T.; Sato, K.; Akai, H.; Takeda, S.; Maruyama, Y.; Matsuta, K.; Fukuda, M.; Miyake, T.; Morishita, A.; Izumikawa, T.; Nojiri,Y.: "“Electric quadrupole interactions of the short-lived b-emitter 12N in insulator crystals (12N implanted in single crystal TiO2)"," Z.Naturforsch., A:Phys.Sci.53. 293-300 (1998)

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      1998 Annual Research Report
  • [Publications] S.Takeda, T.Inabe, C.Benedict, U.Langer, H.H.Limbach,: "“Proton Dynamics in Interacting Hydrogen Bonds in the Solid State: Proton Tunneling in the NHO Hydrogen Bonds of N, N'-Di(2-hydroxy-1-Naphthylmethylene)-p-Phenylenediamine"" Ber.Bunsenges.Phys.Chem.102. 1358-1369 (1998)

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      1998 Annual Research Report
  • [Publications] Tanigaki, M.; Takeda, S.; Matsuta, K.; Matsumoto, Y.; Minamisono, T.; Akai, H.; Sato, K.; Miyake, T.; Maruyama, Y.; Morishita, A.; Fukuda, M.; Norjiri, Y.: "“NMR detection of oxygen isotopes in TiO2 single crystal"," Z.Naturforsch., A: Phys.Sci.,. 53. 305-308 (1998)

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      1998 Annual Research Report
  • [Publications] G.Maruta, S.Takeda, R.Imachi, T.Ishida, T.Nogami, K.Yamaguchi,: "“Solid State High Resolution 1H and 2H NMR Stydies of the Electron Spin Density Distribution and Mechanism of the Magnetic Interaction of Hydrogen-Bonded Organic Ferromagnetic Compound 4-Hydroxyimino-TEMPO"" J.Am.Chem.Soc.121. 424-431 (1999)

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      1998 Annual Research Report
  • [Publications] R.Imamura, K.Matsui, S.Takeda, J.Ozaki and A.Oya,: "“A new role for phosphorous in graphaitization of phenolic resin"" Carbon. 37. 261-267 (1999)

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      1998 Annual Research Report
  • [Publications] G.Maruta, S.Takeda, K.Yamaguchi, K.Ueda, T.Sugimoto,: "Solid State High Resolution NMR Studies of Electron Spin Densities in Charge-Transfer Complex-Based Organic Ferromagnets"" Synth.Metals. (in press.). (1999)

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      1998 Annual Research Report
  • [Publications] S.Takeda, G.Maruta, K.Terasawa, N.Fukuda, K.Yamaguchi,: "“Local Magnetic Structure of Layered Compounds Cu2(OD)3X with Exchangeable Acid Anion X Studied by Solid State High Resolution Deuterium NMR"" Mol.Crys.Liq, Cryst.(in press.). (1999)

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      1998 Annual Research Report
  • [Publications] G.Maruta, S.Takeda, A.Yamaguchi, T.Okuno, K.Awaga, K.Yamaguchi,: "“Magic Angle Spinning 1H-NMR Study of the Spin Density Distribution of Pyrodyl Nitronyl Nitroxides in the Crystalline Phase"," Mol.Crys.Liq, Cryst.(in press.). (1999)

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      1998 Annual Research Report
  • [Publications] A.Oda,T.Kawakami, G.Maruta, S.Takeda, W.Mori, K.Yamaguchi, M.M.Matsushita, T.Sugawara,: "“Theoretical Studies of Magnetic Interactions in 3', 5'-Dihydroxyphenyl Nitronyl Nitroxide Crystal"," Mol.Crys.Liq, Cryst.(in press.). (1999)

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      1998 Annual Research Report
  • [Publications] T.kawakami, A.Oda, S.Takeda, W.Mori, K.Yamaguchi,: "“Theoretical Studies on Magnetic Interaction in TMAO"," Mol.Crys.Liq, Cryst.(in press.). (1999)

    • Related Report
      1998 Annual Research Report

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Published: 1998-04-01   Modified: 2016-04-21  

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