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Application of Interface Deoxidization Method for the Non-Volatile Memory with Next Generation Structure

Research Project

Project/Area Number 10555220
Research Category

Grant-in-Aid for Scientific Research (B).

Allocation TypeSingle-year Grants
Section展開研究
Research Field Inorganic materials/Physical properties
Research InstitutionOsaka Prefecture University

Principal Investigator

ITO Taichiro  Osaka Prefecture University, Professor, 工学研究科, 教授 (10081366)

Co-Investigator(Kenkyū-buntansha) KAMISAWA Akira  ローム(株), VLSI開発研究所, 部長代理(研究職)
ASHIDA Atsushi  Osaka Prefecture University, Assistant Professor, 大学院・工学研究科, 助手 (60231908)
FUJIMURA Norifumi  Osaka Prefecture University, Associate Professor, 大学院・工学研究科, 助教授 (50199361)
Project Period (FY) 1998 – 2000
Project Status Completed (Fiscal Year 2000)
Budget Amount *help
¥11,200,000 (Direct Cost: ¥11,200,000)
Fiscal Year 2000: ¥1,400,000 (Direct Cost: ¥1,400,000)
Fiscal Year 1999: ¥1,600,000 (Direct Cost: ¥1,600,000)
Fiscal Year 1998: ¥8,200,000 (Direct Cost: ¥8,200,000)
KeywordsYMnO_3 / Y_2O_3 / Si capacitor / Ferroelectric FET / ferroelectric memory / interface deoxidization method / epitaxial structure / 界面還元修飾 / MFIS-FET / 強誘電体トランジスタ / 強誘電体不揮発性メモリー / YMnO3 / Y2O3 / トランジスタ型
Research Abstract

A semiconductor based non-volatile memory with ferroelectric layer has relatively fast read/write speed like DRAM and SRAM and has been expected instead of Flash memory. Low integrated divices have been already commercialized. Such devices that are called FeRAM use electric charge accumulated in ferroelectric layer for memory operation. On the other hand, ferroelectric gate FET is expected for the new generation because scaling law used in the semiconductor field can be applied for the memory structure and it can be used for highly integrated devices with low power consumption. However, there had not been good candidate materials for such a device. In this project, the material design was done as a first step. YMnO_3/Y_2O_3/Si was selected as one of the best candidates and experiments pointed out some issues. By using interface deoxidization method, we succeeded in obtaining epitaxially grown YMnO_3/Y_2O_3/Si capacitors without any SiO_2 layer at the Y_2O_3/Si interface that deteriorates the dielectric properties of the capacitor. By optimizing the deposition conditions, we have succeeded in obtaining YMnO_3/Y_2O_3/Si capacitors with the retention time to be over 10000 sec.

Report

(4 results)
  • 2000 Annual Research Report   Final Research Report Summary
  • 1999 Annual Research Report
  • 1998 Annual Research Report
  • Research Products

    (63 results)

All Other

All Publications (63 results)

  • [Publications] T.Shimura, N.Fujimura, S.Yamamori, T.Yoshimura, and T.: "Effect of Stoichiometry and A-site Substitution on the Electrical Properties of Ferroelectric YMnO_3"Jpn.J.Appl.Phys.. 37. 5280 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] T.Yoshimura, N.Fujimura, and T.Ito: "Ferroelectric Properties of c-Oriented YMnO_3 Films Deposited on Si Substrates"Appl.Phys.Lett.. 73. 414 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] T.Yoshimura, N.Fujimura, N.Aoki, K.Hokayama, S.Tukui, K.Kawabata, and T.Ito: "Growth and Properties of YMnO_3 Thin Films for Non-volatile Memories"J.Kore.Phys.Soc.. 32. S1632 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Kitahata,K.Tadanaga, T.minami, N.Fujimura, and T.Ito: "Microstructure and Dielectric Properties of YMnO_3 Thin Films Prepared by Dip-Coating"J.Am.Ceram.Soc.. 81. 1357 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] K.Tadanaga, H.Kitahata, T.minami, N.Fujimura, and T.Ito: "Preparation and Dielectric Properties of YMnO_3 Ferroelectric Thin Films by the Sol-Gel Method"J.Sol-Gel.Sci.Tech.. 13. 903 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] 吉村武、伊藤大輔、藤村紀文、伊藤太一郎: "RMnO_3(R : rare earth element)/Y_2O_3/SiのC-V特性の解析"電子情報通信学会 技術報告. ED98-256,SDM98-209. 71 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] N.Fujimura, T.Yoshimura, D.Ito and T.Ito: "YMnO_3 and YbMnO_3 Thin Films for FET type FeRAM Application"Symposia Proc.of Materials Research Society. 574. 237 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] T.Yoshimura, N.Fujimura, D.Ito and T.Ito: "Detailed C-V Analysis for YbMnO_3/Y_2O_3/Si Structure"Symposia Proc.of Materials Research Society. 574. 359 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Kitahata, K.Tadanaga, T.Minami, N.Fujimura, and T.Ito: "Ferroelectricity of YMnO_3 thin Films Prepared via Solution"Appl.Phys.Lett.. 75. 719 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Kitahata, K.Tadanaga, T.Minami, N.Fujimura, and T.Ito: "Lowering the Crystallization Temperature of YMnO_3Thin films by the Sol-Gel Method Using an Yttrium Alkoxide"Jpn.J.Appl.Phys.. 38. 5448 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] N.Fujimura, T.Yoshimura, D.Ito and T.Ito: "Evaluation of Ferroelectricity in MFIS Type Capacitor Using Pulsed C-V Measurements"Symposia Proc.of Materials Research Society. 596. 407 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] N.Fujimura, D.Ito, K.Kakuno and T.Ito: "Improvement of Retention Property of YMnO_3/Y_2O_3/Si MFIS Capacitor"Symposia proc.of Materials Research Society 2000 fall meeting. (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] K.Tadanaga, H.Kitahata, T.minami, N.Fujimura, and T.Ito: "Preparation and Ferroelectric Properties of YMnO_3 Thin Films With c-Axis Preferred Orientation by the Sol-Gel Method"J.Sol-Gel Sci.ech. 19. 589 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] T.Yoshimura, N.Fujimura, D.Ito and T.Ito: "Characterization of ferroelectricity in metal/ferroelectric/insulator/semiconductor structure by pulsed C-V measurement ; Ferroelectricity in YMnO_3/Y_2O_3/Si structure"J.Appl.Phys.. 87. 3444 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] D.Ito, N.Fujimura, and T.Ito,: "Initial stage of film growth of pulsed laser deposited YMnO_3"Jpn.J.Appl.Phys.. 39. 5525 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] D.Ito, T.Yoshimura, N.Fujimura, and T.ito,: "Improvement of Y_2O_3/Si interface for FeRAM application"Appl.Sur.Sci.. 159. 138 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Kitahata, K.Tadanaga, T.Minami, N.Fujimura, and T.Ito: "Original of Leakage Current of YMnO_3 Thin Films Prepared by the Sol-Gel Method"Symposia Proc.of Materials Research Society. 596. 481 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] N.Fujimura, T.Yoshimura, D.Ito, T.Shimura and T.Ito: "Any candidates of ferroelectric material for transistor type FeRAM?"Applied Physics A,. in press. (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] N.Fujimura, S.Yamamori, A.Nakamoto, D.Ito, T.Yokota and T.Ito: "Effect of Carrier Concentration on the Magnetic Behavior of Ferroelectric YMnO_3 Ceramics and Thin Files."Proc.of Internayional Symposium on Application of Ferroelectrics. in press. (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] T.Shimura, N.Fujimura, S.Yamamori, T.Yoshimura, and T.Ito: "Effect of Stoichiometry and A-site Substitution on the Electrical Properties of Ferroelectric YMnO_3"Jpn.J.Appl.Phys.. 37. 5280 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] T.Yoshimura, N.Fujimura, and T.Ito: "Ferroelectric Properties of c-Oriented YMnO_3 Thin Films Deposited on Si Substrates"Appl.Phys.Lett.. 73. 414 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] T.Yoshimura, N.Fujimura, N.Aoki, K.Hokayama, S.Tukui, K.Kawabata, and T.Ito: "Microstructure and Dielectric Properties of YMnO_3 Thin Films Prepared by Dip-Coating"J.Am.Ceram.Soc.. 81. 1357 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] K.Tadanaga, H.Kitahata, T.minami, N.Fujimura, and T.Ito: "Preparation and Dielectric Properties of YMnO_3 Ferroelectric Thin Films by the Sol-Gel Method"J.Sol-Gel.Sci.Tech.. 13. 903 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] K.Tadanaga, H,Kitahata, T.minami, N.Fujimura, and T.Ito: "Preparation and Dielectric Properties of YMnO_3 Ferroelectric Thin Films by the Sol-Gel Method"J.sol-Gel.Sci.Tech.. 13. 903 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] N.Fujimura, T.Yoshimura, D.Ito and T.Ito: "YMnO_3 and YbMnO_3 Thin Films for FET type FeRAM Application"Symposia Proc.of Materials Research Society. 574. 237 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] T.Yoshimura, N.Fujimura, D.Ito and T.Ito: "Detailed C-V Analysis for YbMnO_3/Y_2O_3/Si Structure"Symposia Proc.of Materials Research Society. 574. 359 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Kitahata, K.Tadanaga, T.Minami, N.Fujimura, and T.Ito: "Ferroelectricity of YMnO_3 thin Films Prepared via Solution"Appl.Phys.Lett.. 75. 719 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Kitahata, K.Tadanaga, T.Minami, N.Fujimura, and T.Ito: "Lowering the Crystallization Temperature of YMnO_3 Thin films by the Sol-Gel Method Using Yttrium Alkoxide"Jpn.J.Appl.Phys.. 38. 5448 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] T.Yoshimura, N.Fujimura, D.Ito and T.Ito: "Characterization of ferroelectricity in metal/ferroelectric/insulator/semiconductor structure by pulsed C-V measurement ; Ferroelectricity in YMnO_3/Y_2O_3/Si structure"J.Appl.Phys.. 87. 3444 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] D.Ito, N.Fujimura, and T.Ito: "Initial stage of thin film growth of pulsed laser deposited YMnO_3 thin film"Jpn.J.Appl.Phys.. 39. 5525 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] K.Tadanaga, H.Kitahata, T.minami, N.Fujimura, and T.Ito: "Preparation and Ferroelectric Properties of YMnO_3 Thin Films With c-Axis Preferred Orientation by the Sol-Gel Method"J.Sol-Gel Sci.tech.. 19. 589 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] D.Ito, T.Yoshimura, N.Fujimura, and T.Ito: "Improvement of Y_2O_3/Si interface for FeRAM application"Appl.Sur.Sci.. 159. 138 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] N.Fujimura, T.Yoshimura, D.Ito and T.Ito: "Evaluation of Ferroelectricity in MFIS Type Capacitor Using Pulsed C-V Measurement"Symposia Proc.of Materials Research Society. 596. 407 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Kitahata, K.Tadanaga, T.Minami, N.Fujimura, and T.Ito: "Origin of Leakage Current of YMnO_3 Thin Films Prepared by the Sol-Gel Method"Symposia Proc.of Materials Research Society. 596. 481 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] N.Fujimura, T.Yoshimura, D.Ito, T.Shimura and T.Ito: "Any candidates of ferroelectric material for transistor type FeRAM?"Applied Physics A. (in press). (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] T.Shimura,N.Fujimura,S.Yamamori,T.Yoshimura,and T.Ito: "Effect of Stoichiometry and A-site Substitution on the Electrical Properties of Ferroelectric YMnO_3"Jpn.J.Appl.Phys.. 37. 5280 (1998)

    • Related Report
      2000 Annual Research Report
  • [Publications] T.Yoshimura,N.Fujimura,and T.Ito: ""Ferroelectric Properties of c-Oriented YMnO_3 Thin Films Deposited on Si Substrates"Appl.Phys.Lett.. 73. 414 (1998)

    • Related Report
      2000 Annual Research Report
  • [Publications] T.Yoshimura,N.Fujimura,N.Aoki,K.Hokayama,S.Tukui,K.Kawabata,and T.Ito: "Growth and Properties of YMnO_3 Thin Films for Nonvolatile Memories"J.Kore.Phys.Soc.. 32. S1632 (1998)

    • Related Report
      2000 Annual Research Report
  • [Publications] H.Kitahata,K.Tadanaga,T.minami,N.Fujimura,and T.Ito: "Microstructure and Dielectric Properties of YMnO_3 Thin Films Prepared by Dip-Coating",J.Am.Ceram.Soc.81,1357(1998). 81. 1357 (1998)

    • Related Report
      2000 Annual Research Report
  • [Publications] K.Tadanaga,H.Kitahata,T.minami,N.Fujimura,and T.Ito: "Preparation and Dielectric Properties of YMnO_3 Ferroelectric Thin Films by the Sol-Gel Method"J.Sol-Gel.Sci.Tech.. 13. 903 (1998)

    • Related Report
      2000 Annual Research Report
  • [Publications] K.Tadanaga,H.Kitahata,T.minami,N.Fujimura,and T.Ito: "Preparation and Dielectric Properties of YMnO_3 Ferroelectric Thin Films by the Sol-Gel Method"J.Sol-Gel.Sci.Tech.. 13. 903 (1998)

    • Related Report
      2000 Annual Research Report
  • [Publications] N.Fujimura,T.Yoshimura,D.Ito and T.Ito: "YMnO_3 and YbMnO_3 Thin Films for FET type FeRAM Application"Symposia Proc.of Materials Research Society. 574. ,237 (1999)

    • Related Report
      2000 Annual Research Report
  • [Publications] T.Yoshimura,N.Fujimura,D.Ito and T.Ito: "Detailed C-V Analysis for YbMnO_3/Y_2O_3/Si Structure"Symposia Proc.of Materials Research Society. 574. 359 (1999)

    • Related Report
      2000 Annual Research Report
  • [Publications] H.Kitahata,K.Tadanaga,T.Minami,N.Fujimura,and T.Ito: "Ferroelectricity of YMnO_3 thin Films Prepared via Solution"Appl.Phys.Lett.. 75. 719 (1999)

    • Related Report
      2000 Annual Research Report
  • [Publications] H.Kitahata,K.Tadanaga,T.Minami,N.Fujimura,and T.Ito: "Lowering the Crystallization Temperature of YMnO_3 Thin films by the Sol-Gel Method Using Yttrium Alkoxide"Jpn.J.Appl.Phys.. 38. 5448 (1999)

    • Related Report
      2000 Annual Research Report
  • [Publications] T.Yoshimura,N.Fujimura,D.Ito and T.Ito: "Characterization of ferroelectricity in metal/ferroelectric/insulator/semiconductor structure by pulsed C-V measurement ; Ferroelectricity in YMnO_3/Y_2O_3/Si structure"J.Appl.Phys.. 87. 3444 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] D.Ito,N.Fujimura,and T.Ito,: "Initial stage of thin film growth of pulsed laser deposited YMnO_3 thin film"Jpn.J.Appl.Phys.. 39. 5525 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] K.Tadanaga,H.Kitahata,T.minami,N.Fujimura,and T.Ito: "Preparation and Ferroelectric Properties of YMnO_3 Thin Films With c-Axis Preferred Orientation by the Sol-Gel Method"J.Sol-Gel Sci.tech. 19. 589 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] D.Ito,T.Yoshimura,N.Fujimura,and T.Ito,: "Improvement of Y_2O_3/Si interface for FeRAM application"Appl.Sur.Sci.. 159. 138 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] N.Fujimura,T.Yoshimura,D.Ito and T.Ito: "Evaluation of Ferroelectricity in MFIS Type Capacitor Using Pulsed C-V Measurement"Symposia Proc.of Materials Research Society. 596,407(2000). 596. 407 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] H.Kitahata,K.Tadanaga,T.Minami,N.Fujimura,and T.Ito: "Origin of Leakage Current of YMnO_3 Thin Films Prepared by the Sol-Gel Method"Symposia Proc.of Materials Research Society. 596. 481 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] N.Fujimura,T.Yoshimura,D.Ito,T.Shimura and T.Ito: "Any candidates of ferroelectric material for transistor type FeRAM?"Applied Physics A,. (In press). (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] N. Fujimura: "Electrical Characterization of Ferroelectric YMnO_3 Films for MF(I)S-FET Application"Proc. of the IEEE Int. Symp. on the Application of Ferroelectrics. 81-86 (1998)

    • Related Report
      1999 Annual Research Report
  • [Publications] H. Kitahata: "Lowering the Crystallization Temperature of YMnO_3 Thin Films by the Sol-Gel Method Using an Yttrium Alkoxide"Japanese Journal of Applied Physics. 38. 5448-5554 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] H. Kitahata: "Ferroelectricity of YMnO_3 Thin Films Prepared via Solution"Applied Physics Letters. 75. 719-721 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] D. Ito: "Improvement of Y_2O_3 /Si Interface for FeRAM Application"Applied Surface Science. (printing). (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] N. Fujimura: "YMnO_3 and YbMnO_3 Thin Films for FET type FeRAM Application"Symposia Proc. of Materials Research Society. 574. 237-242 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] T. Yoshimura: "Detailed C-V Analysis of YbMnO3/Y2O3/Si Structure"Symposia Proc. of Materials Research Society. 574. 359-364 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 吉村 武: "RMnO_3 (R:rare earth element)Y_2O_3/SiのC-V特性の解析"電子通信学会技報. 591. 71-76 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] T. Yoshimura: "Characterization of Ferroelectricity in Metal/Ferroelectric/Insulator/Semiconductor Structure by Pulsed Capacitance-Voltage measurement Ferroelectricity in YMnO_3/Y_2O_3/Si Structure"Journal of Applied Physics. April issue(Printing). (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] T.Yoshimura: "Ferroelectric Properties of C-Oriented YMnO3 Thin Films Deposited on SiSubstrate" Applied Phys.Lett.73. 414-417 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] T.Shimura: "Effect of stoicheometry and A-site substitution on the electrical properties of Ferroelectri YMnO3" Jpn Journal of Applied Phys.37. 5280-5284 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] K.Tadanaga: "Preparation and dielectric properties of YMnO3 ferroelectric thin films by so-gel method" J.of Sol-Gel Sci.Tech.13. 903-907 (1998)

    • Related Report
      1998 Annual Research Report

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Published: 1998-04-01   Modified: 2016-04-21  

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