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Theory of Resonant X-ray Emission Spectra in f and Electron Systems

Research Project

Project/Area Number 10640299
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field 固体物性Ⅰ(光物性・半導体・誘電体)
Research InstitutionThe University of Tokyo

Principal Investigator

KOTANI Akio  Institute for Solid State Physics, The University of Tokyo, Professor, 物性研究所, 教授 (90029504)

Co-Investigator(Kenkyū-buntansha) OGASAWARA Haruhiko  Institute for Solid State Physics, The University of Tokyo, Research Associate, 物性研究所, 助手 (80262161)
OKADA Kozo  Okayama University, Faculty of Science, Associate Professor, 物理学部, 助教授 (70194355)
Project Period (FY) 1998 – 2001
Project Status Completed (Fiscal Year 2001)
Budget Amount *help
¥3,500,000 (Direct Cost: ¥3,500,000)
Fiscal Year 2001: ¥500,000 (Direct Cost: ¥500,000)
Fiscal Year 2000: ¥500,000 (Direct Cost: ¥500,000)
Fiscal Year 1999: ¥900,000 (Direct Cost: ¥900,000)
Fiscal Year 1998: ¥1,600,000 (Direct Cost: ¥1,600,000)
Keywordsspectroscopy / rare-earth compounds / transtion-metal compounds / cluster model / polarization-dependence / charge transfer / electron correlation / magnetic circular dichroism / 共鳴X線発光 / 干渉効果 / 電気四重極子励起 / 配置間相互作用 / 内殻正孔 / 遍歴性 / 局在性 / 円偏光二色性
Research Abstract

Among the magnetic materials known so far, CeSb has the most complex phase diagram as a function of temperature and magnetic field. The complex magnetic phase diagram is know as the devil's staircase. Generally, the series of CeX (X=P, As, Bi, Sb) have complex magnetic phase diagrams in different degree, which suggests that there is a common mechanism for the devil's staircase observed in CeX. A characteristic feature of CeX is smallness of carriers. The carriers of CeX consist of holes at the Γ point and electrons at the X points. Under this situation, a new type of scattering processes from holes to electrons and vice versa accompanied by spin exchange with f-spins. This process may be called off-diagonal exchange in contrast to the usual exchanges where the scattering are within a band. The momentum transfer associated with his off-diagonal exchange corresponds to the antiferromagnetic wave vector, favoring antiferromagnetic RKKY interaction among the f spins. On the other hand, the ordinary exchanges favor ferromagnetic coupling in the low carrier limit. In this project, we have shown that the frustration between the RKKY interactions originated from these two types of exchange mechanisms is the basic mechanism for the devil's staircase in CeX by using a simple/

Report

(5 results)
  • 2001 Annual Research Report   Final Research Report Summary
  • 2000 Annual Research Report
  • 1999 Annual Research Report
  • 1998 Annual Research Report
  • Research Products

    (36 results)

All Other

All Publications (36 results)

  • [Publications] J.P.Hill: "Resonant Inelastic X-Ray Scattering in Nd_2CuO_4"Phys. Rev. Lett.. 80. 4967-4970 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] A.Kotani: "Theoretical Study of Resonant X-Ray Emission in f and d Electron Systems-Impurity Anderson Model and Effects of Translational Symmetry-"J. Phys. Chem. Solids. 61. 419-424 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] M.Matsubara: "Polarization Dependence of Resonant X-Ray Emission Spectra in Early Transition Metal Compounds"J. Phys. Soc. Jpn.. 69. 1558-1565 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] A.Kotani: "Resonant Inelastic X-Ray Scattering Spectra for Electrons in Solids"Rev. Mod. Phys.. 73. 203-246 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] K.Fukui: "Magnetic Circular Dichroism of Resonant X-ray Emission Spectroscopy in Longitudinal and Transverse Geometries"J. Phys. Soc. Jpn.. 70. 3457-3463 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] K.Okada: "Copper-Related Information from the Oxygen 1s Resonant X-Ray Emission in Low-Dimensional Cuprates"Phys. Rev. B.. (to be published).

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] J. P. Hill: "Resonant Inelastic X-Ray Scattering in Nd_2 CuO_4"Phys. Rev. Lett.. 80. 4967-4970 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] A. Kotani: "Theoretical Study of Resonant X-Ray Emission in f and d Electron Systems - Impurity Anderson Model and Effects of Translational Symmetry -"J. Phys. Chem. Solids. 61. 419-424 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] M. Matsubara: "Polarization Dependence of Resonant X-Ray Emission Spectra in Early Transition Metal Compounds"J. Phys. Soc. Jpn.. 69. 1558-1565 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] A. Kotani: "Resonant Inelastic X-Ray Scattering Spectra for Electrons in Solids"Rev. Mod. Phys.. 73. 203-246 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] K. Fukui: "Magnetic Circular Dichroism of Resonant X-ray Emission Spectroscopy in Longitudinal and Transverse Geometries"J. Phys. Soc. Jpn.. 70. 3457-3463 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] K. Okada: "Copper-Related Information from the Oxygen Is Resonant X-Ray Emission in Low-Dimensional Cuprates"Phys. Rev. B. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Masahiko Matsubara: "Polarization Dependence of Resonant X-Ray Emission Spectra in 3d^n Transition Metal Compounds with n=0, 1, 2, 3"Journal of the Physical Society of Japan. 71-1. 347-356 (2002)

    • Related Report
      2001 Annual Research Report
  • [Publications] T.Uozumi: "Theoretical and experimental study of surface and bulk contributions in resonant inverse photoemission of CeRh_3"Physical Review B. 65. 045105-1-10 (2002)

    • Related Report
      2001 Annual Research Report
  • [Publications] Keihi Fukui: "Magnetic Circular Dichroism of Resonant X-Ray Emission Spectroscopy in Longitudinal and Transverse Geometries"Journal of the Physical Society of Japan. 70-11. 3457-3463 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] Keiji Fukui: "X-ray magnetic circular dichroism at rare-earth L_<2, 3> edges in R_2Fe_14B compounds (R=La, Pr, Nd, Sm, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu)"Physical Review B. 64. 104405-1-7 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] M.Taguchi: "Resonant Raman scattering at the L thresholds with final 3s hole in 3d^<2+> systems. I. Configuration interaction with two 3p hole final states in different systems"Physical Review B. 63. 245114-1-10 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] L.Braicovich: "Resonant Raman scattering at the L thresholds with final 3s hole in 3d^<2+> systems.II. The CoO case in the whole L_<2,3> region"Physical Review B. 63. 245115-1-8 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] Akio Kotani: "Resonant inelastic x-ray scattering spectra for electrons in solids"Reviews of Modern Physics. 73-1. 203-246 (2001)

    • Related Report
      2000 Annual Research Report
  • [Publications] Akio Kotani: "Theory of resonant X-ray emission spectra in strongly correlated electron systems"Journal of Electron Spectroscopy and Related Phenomena. 110-111. 197-212 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Makoto Nakazawa: "Theory of Polarization Dependence in Resonant X-Ray Emission Spectroscopy of Ce Compounds"Journal of the Physical Society of Japan. 69-12. 4071-4077 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Kozo Okada: "Resonant X-ray Emission Spectroscopy in Hubbard Model"Journal of the Physical Society of Japan. 69-9. 3100-3106 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] H.Ogasawara: "3d resonant photoemission spectra at the CeL_3 edge of CeRh_3"Physical Review B. 62-12. 7970-7975 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Tsuyoshi Ide: "Interplay between Raman and Fluorescence-Like Components in Resonant X-ray Emission Spectra of Degenerate d^0 and d^1 Systems"Journal of the Physical Society of Japan. 69-6. 1895-1906 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Tsuyoshi Ide: "Local and Nonlocal Excitations in Cu 4p-1s Resonant X-Ray Emission Spectra of Nd_2CuO_4"Journal of the Physical Society of Japan. 68・9. 3100-3109 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] K.Kanai: "Resonance effect on inverse-photoemission spectroscopy of CeRh_3,CePd_3,and CeSn_3"Physical Review B. 60・8. 5244-5250 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] P. Kruger: "3_s photoemission spectra of 3d transition-metal adatoms on graphite"Physical Review B. 59・23. 15093-15099 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] K. Fukui: "Phenomenological interpretation of MCXD in L_<2,3> XAS of trivalent cerium compound"Journal of Electron Spectroscopy and Related Phenomena. 104. 67-72 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Akio Kotani: "Theory of core-level spectroscopy in f and d electron systems"Journal of Electron Spectroscopy and Reiated Phenomena. 100. 75-104 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Akio Kotani: "Theoretical Study of X-Ray Emission Spectroscopy on Magnetic Materials"Japanese Journal of Applied Physics. 38. 354-359 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Kozo Okada: "Large-Cluster Effects on Core-Level Photoabsorption Spectrum of LaCuO_3" Journal of the Physical Society of Japan. 68・2. 666-673 (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] H.Ogasawara: "Caloulation of electron-energy-loss spectra for 3s→3d excitation in transition metal oxides" Journal of Electron Spectroscopy and Related Phenomena. 88-91. 261-266 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Akio Kotani: "Theory of X-ray emission spectra in f and d electron systems" Journal of Electron Spectroscopy and Related Phenomena. 92. 171-179 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] J.P.Hill: "Resonant Inelastic X-Ray Scattering in Nd_2CuO_4" Physical Review Letters. 80・22. 4967-4970 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Tsuyoshi Ide: "A Model Study on Cluster Size Effects of Resonant X-Ray Emission Spectra" Journal of the Physical Society of Japan. 67・10. 3621-3629 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] Yuksel Ufuktepe: "Resonant Photoemission Studies of Thulium Monochalcogenides around the Tm 4d Threshold" Journal of the Physical Society of Japan. 67・6. 2018-2026 (1998)

    • Related Report
      1998 Annual Research Report

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Published: 1998-04-01   Modified: 2020-05-15  

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