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Precise life-time measurements of EC decay nuclides in capsulated in Fullerene cage in the extreme conditions

Research Project

Project/Area Number 10640535
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic chemistry
Research InstitutionTOHOKU UNIVERSITY

Principal Investigator

OHTSUKI Tsutomu  School of Science, Tohoku University, Research Associate, 大学院・理学研究科, 助手 (50233193)

Co-Investigator(Kenkyū-buntansha) 須田 利美  東北大学, 大学院理学研究科, 助手 (30202138)
Project Period (FY) 1998 – 1999
Project Status Completed (Fiscal Year 1999)
Budget Amount *help
¥3,300,000 (Direct Cost: ¥3,300,000)
Fiscal Year 1999: ¥1,300,000 (Direct Cost: ¥1,300,000)
Fiscal Year 1998: ¥2,000,000 (Direct Cost: ¥2,000,000)
KeywordsFULLERENE / LIFE-TIME MEASUREMENT / Be-7 / 核外電子捕獲崩壊 / 元素内包フラーレン / 半減期
Research Abstract

In this project, a precise life-time measurements of ィイD17ィエD1Be encapsulated in fullerene cage were performed with extreme conditions, such as 6K temperature. The results measured in 6K were compared with the data for the normal temperature and the data presented so far in the different chemical form.
Radioactive endohedral fullerenes, ィイD17ィエD1B@CィイD260ィエD2, were detected using radiochemical and radiochromatographic techniques in the final solvent. Such a ィイD17ィエD1Be atom can penetrate into the CィイD260ィエD2 to produce ィイD17ィエD1Be@CィイD260ィエD2 by a recoil process of the nuclear reactions, ィイD112ィエD1C(γ, αn)ィイD17ィエD1Be or ィイD17ィエD1Li(p,n)ィイD17ィエD1Be.
To measure the life-time of ィイD17ィエD1Be encapsulated in the cage, ィイD17ィエD1B@CィイD260ィエD2, the same apparatus in a system (Ge-detector, MCA, Computer, etc.) was used due to the reduction of systematic errors. Data were collected at 8 hours intervals in a MCA system. Analysis was performed using by a least-squares fitting with the CERN program, PAW. Finally we obtained the life-time of 52.98【minus-plus】0.05 day for 6K. It seems that a relatively large change was obtained compared to the value presented so far.

Report

(3 results)
  • 1999 Annual Research Report   Final Research Report Summary
  • 1998 Annual Research Report
  • Research Products

    (27 results)

All Other

All Publications (27 results)

  • [Publications] T.Ohtuki et al.: "Insertion of Xe and Kr atoms in C_<60>,C_<70> fullerenes and formation of dimer"Physical Review Letters. 81. 967-970 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T.Ohtuki et al.: "Observation of radioactive hetero-fullerenes using radiochemical techniques"Journal of Radioanalytical and Nuclear Chemistry. 239. 365-370 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] K.Masumoto et al.: "Direct preparation of radioactive carbon labeled fullerenes using nuclear reaction"Journal of Radioanalytical and Nuclear Chemistry. 239. 201 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T.Ohtuki et al.: "Formation of dimer trimer, tetramer of C_<60> and C_<70> by γ-ray, charged-particle irradiation"Chemical Physics Letters. 300. 661-666 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T.Ohtuki et al.: "Formation of As-and Ge-doped hetero fullerenes"Physical Review B. 60. 1531-1534 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T.Ohtuki et al.: "Systematic study of foreign-atom-doped fullerenes by using nuclear recoil method and their simulation"Journal of Chemical Physics. 112. 2834-284* (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T.Ohtuki,K.Ohno: "Formation of foreign atom doped fullerenes"Physics and Chemistry of clusters. (分担分). 16 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T.Ohtuki,K.Ohno: "Systematic study of foreign-atom-incorporated-fullerenes by using a nuclear recoil and their MD simulation"Nuclear and Radiochemical Approaches to Fullerene Sciences. (分担分). 27 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T. Ohtsuki et al.: "Insertion of Xe and Kr Atoms in C60, C70 Fullerenes and Formation of Dimers"Phys. Rev. Lett.. 81. 967-970 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T. Ohtsuki et al.: "Observation of radioactive hetero-fullerenes using radiochemical techniques"J. Radioanal. Nucl. Chem.. 239. 365-370 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] K. Masumoto et al.: "Direct preparation of radioactive carbon labeled fullerenes using nuclear reaction"J. Radioanal. Nucl. Chem.. 239. 201-206 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T. Ohtsuki et al.: "Formation of Dimer, Trimer and Tetramer of C60 and C70 by γ-ray, charged-particle irradiation, and their HPLC separation"Chem. Phys. Lett.. 300. 661-666 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T. Ohtsuki, K. Ohno, K. Shiga, Y. Kawazoe, Y. Maruyama, K. Masumoto: "Formation of As- and Ge-doped heterofullerenes"Phys. Rev.. B60. 1531-1534 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T. Ohtsuki, K. Ohno, K. Shiga, Y. Kawazoe, Y. Maruyama, K. Masumoto: "Systematic study of foreign-atom-doped fullerenes using nuclear recoil method and their MD simulation"J. Chem. Phys.. 112. 2834-2842 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T. Ohtsuki, K. Masumot, K. Shikano, K. Sueki, T. Tanaka, K. Komatsu: "Direct preparation of radioactive fullerenes as a tracer for applications"Biol. Trace Element Research. 71. 489-491 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] K. Shiga et al.: "Ab Initio morecular dynamics study on noble-gas and alkali-metal atom insertion into C60"Modeling Simul. Mater. Sci. Eng.. 7. 621-630 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T. Ohtsuki, K. Ohno: "Systematic study of foreign-atom-incorporated fullerenes by using a nuclear recoil and their MD simulation"Nuclear and Radiochemical Approaches to Fullerene Sciences, Edited by T. Braun, Kluwer Academic Publisher. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T. Ohtsuki, K. Ohno: "Formation of foreign atom doped fullerenes"Springer and Verlage edited by Y. Kawazoe and T. Kondo. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T.Ohtsuki et al.: "Insertion of Xe and Kr atoms in C_<60>, C_<70> fullerenes and formation of dimer"Physical Review Letters. 81. 967-970 (1998)

    • Related Report
      1999 Annual Research Report
  • [Publications] T.Ohtsuki et al.: "Observation of radioactive hetero-fullerenes using radiochemical techniques"Journal of Radioanalytical and Nuclear Chemistry. 239. 365-370 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] K.Masumoto et al.: "Direct preparation of radioactive carbon labeled fullerenes using nuclear reaction"Journal of Radioanalytical and Nuclear Chemistry. 239. 201-206 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] T.Ohtsuki et al.: "Formation of dimer, trimer, tetramer of C_<60> and C_<70> by γ-ray, charged-particle irradiation"Chemical Physics.Letters. 300. 661-666 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] T.Ohtsuki et al.: "Formation of As- and Ge-doped heterofullerenes"Physical Review B. 60. 1531-1534 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] T.Ohtsuki et al.: "Systematic study of foreign-atom-doped fullerenes by using nuclear recoil method and their simulation"Journal of Chemical Physics. 112. 2834-2842 (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] T.Ohtsuki,K.Ohno: "Physics and Chemistry of Clusters"Formation of foreign atom doped fullerenes. 16 (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] T.Ohtsuki,K.Ohno: "Nuclear and Radiochemical Approaches to Fullerene Sciences"Systematic study of foreign-atom-incorporated fullerenes by using a nuclear recoil and their MD simulation. 27 (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] T.Ohtsuki: "Formation of dimer, trimer and tetramer of C_<60> and C_<70> by, γ-ray, charged-particle irradiation, and their HPLC separation" Chemical Physics Letters. 300. 661-666 (1999)

    • Related Report
      1998 Annual Research Report

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Published: 1998-04-01   Modified: 2016-04-21  

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