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Preparation of Monodispersed Particles by Self Assembe Controlling and Their Functions

Research Project

Project/Area Number 10640559
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field 機能・物性・材料
Research InstitutionOsaka Kyoiku University

Principal Investigator

KANDORI Kazuhiko  Faculty of Education, Osaka Kyoiku University Associ.Prof., 教育学部, 助教授 (70177765)

Co-Investigator(Kenkyū-buntansha) YASUKAWA Akemi  Faculty of Education, Osaka Kyoiku University Assistant., 教育学部, 助手 (70243285)
ISHIKAWA Tatsuo  Faculty of Education, Osaka Kyoiku University Prof., 教育学部, 教授 (30009055)
Project Period (FY) 1998 – 2000
Project Status Completed (Fiscal Year 2000)
Budget Amount *help
¥3,300,000 (Direct Cost: ¥3,300,000)
Fiscal Year 2000: ¥300,000 (Direct Cost: ¥300,000)
Fiscal Year 1999: ¥400,000 (Direct Cost: ¥400,000)
Fiscal Year 1998: ¥2,600,000 (Direct Cost: ¥2,600,000)
KeywordsMonodispesed nano particles / Hematite / Calcium hydroxyapatite / TPD-Mass-TG / Barium-calcium hydroxyapatite / バリウム-カルシウムヒドロキシアパタイト / バリウムーカルシウムヒドロキシアパタイト / 金属リン酸塩粒子 / カドミヒドロキシアパタイト / タンパク質吸着 / ヘアタイト / 鉛ヒドロキシアパタイト
Research Abstract

l) Forced hydrolysis reaction of FeCl_3-HCl solution with various amounts of Fe(NO_3)_3 and HNO_3 was performed. The size and crystallinity of the particles depended strongly on the amounts of Fe(NO_3)_3 and HNO_3 in the solutions.
2) Rod-like calcium hydroxyapatites (Hap) with micrometer size (particle length : 0.12 to 5.21 μm) were produced. The amount of adsorbed bovine serum albumin (BSA) onto the synthesized micrometer-sized Hap particles is strongly dependent upon their mean particle length (Lp), while that of lysozyme (LSZ) onto the Hap particles exhibited a minor dependence on the Lp. This protein adsorption behavior observed in the present paper provided a definitive evidence that the C sites exposed on ac or bc crystal faces are the adsorption sites for BSA.
3) Cadmium hydroxyapatite particles were prepared by using forced hydrolysis reaction of acetamide. The obtained particles were highly crystallized with needle-like strucuture.
4) Forced hydrolysis reaction of FeCl_3-HCl sol … More ution was performed in the presence of polyethylene glycol (PEG). The phase transformation from β-FeOOH to hematite was reduced with increase in the concentration of PEG.It was found that the particles produced with PEG were porous.
5) Barium-calcium hydroxyapatite solid solution particles were produced. The pure solid-solution was produced below the molar ratio of Ba/(Ca+Ba) of 0.5 in the solution. The particle produced were aggregates of the fine primary particles.
6) The simultaneous in-situ temperature programmed desorption, mass spectroscopy and termogravimetric (TPD-Mass-TG) measurement instrument was constracted and the measurement was employed for the well-defined spherical hematite particles with various sizes and porosity produced from the forced hydrolysis reaction. The elimination temperature of adsorbed H_2O and CO_2, surface OH groups and lattice OH^- ions strongly depended on the porosity and degree of aggregation of PNs. It was suggested that the porosity of the colloidal particles can be estimated by this in-situ TPD-Mass TG method. Less

Report

(4 results)
  • 2000 Annual Research Report   Final Research Report Summary
  • 1999 Annual Research Report
  • 1998 Annual Research Report
  • Research Products

    (38 results)

All Other

All Publications (38 results)

  • [Publications] Kazuhiko Kandori: "Preparation and Characterization of Hydrophobic Calcium Hydroxyapatite Particles Grafting Oleylphosphate Groups"Colloids and Surafces A :. 150. 161-170 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Akemi Yasukawa: "Preparation and Characterization of Carbonated Barium Hydroxyapatites"Journal of Colloid and Interface Science. 212. 220-227 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Kazuhiko Kandori: "Adsorption of Bovine Serum Albumin and Lysozyme on Hydrophobic Calcium Hydroxyapatites"Journal of Colloid and Interface Science. 212. 600-603 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Akemi Yasukawa: "Preparation and Nonstoichiometric Calcium Hydroxyapatites Using Foramide"Materials Research Bulletin. 34. 589-601 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Tatsuo Ishikawa: "Influence of Co^<2+>, Cu^<2+> and Cr^<3+> Ions on the Formation of Magnetites"Corrosion Science. 41. 1665-1680 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Akemi Yasukawa: "Preparation of Lead Hydroxyapatite Particles Using Acetamide"Journal of Materials Chemistry. 9. 1825-1830 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Kazuhiko Kandori: "Competitive and cooperative adsorptions of bovine serum albumin and lysozyme to synthetic calcium hydroxyapatites"Langmuir. 16(5). 2301-2305 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Tatsuo Ishikawa: "Structures of Ti(IV)-doped α-FeOOH particles"Journal of Materials Chemistry. 10. 543-547 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Hidekazu Tanaka: "Influence of thermal treatment on the structure of calcium hydroxyapatite"Phys.Chem.Chem.Phys.. 2. 2647-2650 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Kazuhiko Kandori: "Roles of Metal Ions in the Formation of Hematite Particles from Forced Hydrolysis Reaction"Industrial & Engineering Chemistry Research. 39. 2635-2643 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Kazuhiko Kandori: "Defnitive effects of chloride ions on the formation of spherical hematite particles in a forced hydrolysis reaction"Phys.Chem.Chem.Phys.. 2. 3293-3299 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Tatsuo Ishikawa: "FTIR Study on Deuteration of Calcium Hydroxyapatite Particles"Langmuir. 16. 10221-10226 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Kazuhiko Kandori, Aya Fijiwara, Akemi Yasukawa and Tatsuo Ishikawa: "Preparation and Characterization of Hydrophobic Calcium Hydroxyapatite Particles Grafting Oleylphosphate Groups"Colloids and Surfaces A. 150. 161-170 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Akemi Yasukawa, Manami Nakajima, Kazuhiko Kandori and Tatsuo Ishikawa: "Preparation and Characterization of Carbonated Barium Hydroxyapatite"J.Colloid Interface Sci.. 212. 220-227 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Kazuhiko Kandori, Megumi Mukai, Aya Fujiwara, Akemi Yasukawa and Tatsuo Ishikawa: "Adsorption of Bovine Serum Albumin and Lysozyme on Hydrophobic Calcium Hydroxyapatites"J.Colloid Interface Sci.. 212. 600-603 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Hidekazu Tanaka, Tohru Watanabe, Masatoshi Chikazawa, Kazuhiko Kandori and Tatsuo Ishikawa: "TPD, FTIR, and Molecular Adsorption Studies of Calcium Hydroxyapatite Surface Modified with Hexanoic and Decanoic Acids"J.Colloid Interface Sci.. 214. 31-37 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Akemi Yasukawa, Tomonori Matsuura, Minami Nakajima, Kazuhiko Kandori and Tatsuo Ishikawa: "Preparation of Nonstoichiometric Calcium Hydroxyapatite Using Formamide"Materials Research Bulletin. 34. 589-601 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Tatsuo Ishikawa, Hiroshi Nakazaki, Akemi Yasukawa, Kazuhiko Kandori and Makoto Seto: "Influences of Co^<2+> Cu^<2+> and Cr^<3+> ions on the formation of Magnetite"Corrsion Science. 41. 1665-1680 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Akemi Yasukawa, Takeshi Kunimoto, Kaoru Kamiuchi, Kazuhiko Kandori and Tatsuo Ishikawa: "Preparation of Lead Hydroxyapatite Particles Using Acetamide"J.Mater.Chem.. 9. 1825-1830 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Kazuhiko Kandori, Megumi Mukai, Akemi Yasukawa and Tatsuo Ishikawa: "Competitive and Cooperative Adsorptions of Bovine Serum Albumin and Lysozyme to Synthetic Calcium Hydroxyapatites"Langmuir. 16. 2301-2305 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Tatsuo Ishikawa, Hiroaki Yamashita, Akemi Yasukawa, Kazuhiko Kandori, Takenori Nakayama and Fumio Yuse: "Structures of Ti(IV)-doped α-FeOOH particles"J.Maker.Chem.. 10. 543-547 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Kazhiko Kandori, Aya Fudo and Tatsuo Ishikawa: "Adsorption of Myoblobin onto Various Synthetic Hydroxyapatite Particles"Phys.Chem.Chem.Phys.. 2. 2015-2020 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Hidekazu Tanaka, Masatoshi Chikazawa, Kazuhiko KAndori and Tatsuo Ishikawa: "Influences of Thermal Treatment on the Structure of Calcium Hydroxyapatite"Phys.Chem.Chem.Phys.. 2. 2647-2650 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Kazuhiko Kandori, Akemi Yasukawa and Tatsuo Ishikawa: "Roles of Metal Ions in the Formation of Hematite Particles from Forced Hydrolysis Reaction"Industrial & Engineering Chemistry Research. 39. 2635-2643 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Kazuhiko Kandori, Junko Sakai and Tatsuo Ishikawa: "Definitive Efects of Chloride Ions on the Formationof Spherical Hematite Particles in a Forced Hydrolysis Reaction"Phys.Chem.Chem Phys.. 2. 3293-3299 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Tatsuo Ishikawa, Akihiro Teramachi, Hidekazu Tanaka, Akemi Yasukawa and Kazuhiko Kandori: "Fourier Transform Infrared Spectroscopy Study of Deuteration of Calcium Hydroxyapatite Particles"Langmuir. 26. 10221-10226 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Kazuhiko Kandori : "Competitive and cooperative adsorptions of bovine serum albumin and lysozyme to synthetic calcium hydroxyapatites"Langmuir. 16(5). 2301-2305 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Tatsuo Ishikawa : "Structures of Ti(IV)-doped α-FeOOH particles"Journal of Materials Chemistry . 10. 543-547 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Hidekazu Tanaka: "Influence of thermal treatment on the structure calcium hydroxyapatite"Phys.Chem.Chem.Phys. 2. 2647-2650 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Kazuhiko Kandori: "Roles of Metal Ions in the Formation of Hematite Particles from Forced Hvdrolysis Reaction"Industrial & Engineering Chemistry Research. 39. 2635-2643 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Kazuhiko Kandori: "Defnitive effects of chloride ions on the formation of spherical hematite particles in a forced hydrolysis reaction"Phys.Chem.Chem.Phys.. 2. 3293-3299 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Tatsuo Ishikawa: "FTIR Study on Deuteration of Calcium Hydroxyapatite Particles"Langmuir. 16. 10221-10226 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Kazuhiko Kandori: "Preparation and Characterization of hydrophobic calcium hydroxyapatite particles grafing oleylphosphate groups"Colloids and Surfaces A: Physicochemical and Engineering Aspects. 150. 161-170 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Akemi Yasukawa: "Preparation and Characterization of Carbonated Barium"Juornal of Colloid and Interface Science. 212. 220-227 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Kazuhiko Kandori: "Adsorption of Bavine Serum Albumin and Lysozyme in Hydrophobic Calcium Hydroxyapatites"Journal of Colloid and Interface Science. 212. 600-603 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Akemi Yasukawa: "Preparation of Nonstoichiometric Calcium Hydroxyapatite Using Formamide"Materials Research Bulletin. 34. 589-601 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Tatsu Ishikawa: "Influences of Co^<2+>, Cu^<2+> and Cr^<3+> ions on the Formation of Magnetites"Corrosion Science. 41. 1665-1680 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Akemi Yasukawa: "Preparation of Lead hydroxyapatite particles using acetamide"Journal of Materials Chemistry. 9. 1825-1830 (1999)

    • Related Report
      1999 Annual Research Report

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Published: 1998-04-01   Modified: 2016-04-21  

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