| Project/Area Number |
10640572
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
物質変換
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| Research Institution | HOKKAIDO UNIVERSITY |
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Principal Investigator |
KOTORA Martin Hokkaido Univ., Catalysis Research Center, Asso. Pro., 触媒化学研究センター, 助教授 (60281846)
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| Co-Investigator(Kenkyū-buntansha) |
HARA Ryuichiro Hokkaido Univ., Catalysis Research Center, Inst., 触媒化学研究センター, 助手 (30281851)
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| Project Period (FY) |
1998 – 1999
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| Project Status |
Completed (Fiscal Year 1999)
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| Budget Amount *help |
¥3,200,000 (Direct Cost: ¥3,200,000)
Fiscal Year 1999: ¥1,200,000 (Direct Cost: ¥1,200,000)
Fiscal Year 1998: ¥2,000,000 (Direct Cost: ¥2,000,000)
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| Keywords | zirconium / dibutylzirconocene / cation species / zirconacycles / insertion / cyclization / methylalumoxane / ジルコニウム錯体 / ジルコナシクロペンタジエン / カチオン錯体 / 結合の活性化 / シクロペンテノン / 選択的反応 / カルボニレーション |
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| Research Abstract |
In order to develop novel type of reactions using zirconium cation species, we synthesized novel zirconium complexes which were used for the project as a target. Dienes which have a chloride at C2 carbon cyclized, when they were treated with dibutylzirconocene. In this reaction, the diene moiety cyclized to form a zirconacyclopentane as the cyclized product. The chloride at C2 carbon of dienes came to β-position of zirconacyclopentanes. And then further reaction proceeded because of the chloride at β-position. Elimination of the chloride occurred and this moiety was converted into a carbon-carbon double bond and the eliminated chloride was trapped by zirconium metal center. By this reaction alkylzirconocene chlorides were obtained. When the compounds were treated with MAO (methylalumoxane) and the phenylacetylene, novel type of insertion reaction was observed.
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