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Formation Process of Toxic Substances from Biomass Fuel

Research Project

Project/Area Number 10650222
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Thermal engineering
Research InstitutionHokkaido Institute of Technology

Principal Investigator

FUJIWARA Yasuhiro  Hokkaido Institute of Technology, Faculty of Engineering, Professor, 工学部, 教授 (30048045)

Co-Investigator(Kenkyū-buntansha) TOSAKA Shigeru  Hokkaido Institute of Technology, Faculty of Engineering, Professor, 工学部, 教授 (80048058)
Project Period (FY) 1998 – 2001
Project Status Completed (Fiscal Year 2001)
Budget Amount *help
¥3,700,000 (Direct Cost: ¥3,700,000)
Fiscal Year 2001: ¥400,000 (Direct Cost: ¥400,000)
Fiscal Year 2000: ¥400,000 (Direct Cost: ¥400,000)
Fiscal Year 1999: ¥1,000,000 (Direct Cost: ¥1,000,000)
Fiscal Year 1998: ¥1,900,000 (Direct Cost: ¥1,900,000)
KeywordsDiesel Engine / Biomass Fuel / Methyl Ester / Toxic Substance / Particulate Matter / SOF / Aldehyde / DNPH法 / 熱分解 / 生成機構 / ディーゼル燃料 / 成分分析 / 熱分解過程
Research Abstract

Biomass fuel is a good substitute fuel for petroleum because it is reproducible and because there is very little emission of CO_2 throughout the ecosystem cycle. Methyl-esterificated fuel produced from vegetable oil is particularly beneficial for diesel engines because almost the same engine performance as that achieved by the use of gas oil is possible but there is much less exhaust smoke. However, since oxygen molecules in esterified fuel contain oxygen, there is a risk that more toxic substance containing oxygen will be emitted from a diesel engine in which esterified fuel is used than from an engine in which gas oil is used as fuel.
As the experiment result, it is safe to say that a diesel fuel for the automobile van be made from esterified fuel. The differences in the constituent component and esterification ratio of the vegetable oil will be reflected in the methyl eater fuel as the difference in its component. However, this will not make an impact upon engine performance and emission characteristics in any great way. As for the emission of such specified harmful substances as methanol, formaldehyde, acetaldehyde and acrolein etc, the number of dublebonds in the fatty acid that constitute methyl eater was found to be responsible.
In comparison with gas oil, regardless of the combustion chamber types, the methyl ester fuel had 1,2 to 3times more of specified harmful substance such as methanol, formaldehyde, acrolein and benzene in the exhaust gas. The DI engine was found to emit a large quantity of particulates in the low to middle load range. A large portion of the particulates in question consist of SOF components. However, with the IDI engine, there was no significant difference in the emission of particulates between methyl ester fuel and light oil. We need to take countermeasures against the tempura small which is caused by propionaldehyde.

Report

(5 results)
  • 2001 Annual Research Report   Final Research Report Summary
  • 2000 Annual Research Report
  • 1999 Annual Research Report
  • 1998 Annual Research Report
  • Research Products

    (10 results)

All Other

All Publications (10 results)

  • [Publications] T.Murayama, T.Fujiwara, T.Noto: "Evaluating Waste Vegetable Oils as a Diesel Fuel"Proceedings of the Institution of Mechanical Engineers. Vol.214. 141-148 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] 藤原康博, 能戸正: "バイオ系燃料がディーゼル機関の性能ならびに排気特性に及ぼす影響"日本陸用内燃機関協会誌. 461号. 9-16 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] 野津弘志, 藤原康博, 登坂茂: "ディーゼル機関用バイオ系燃料から生成される有害成分に関する研究"北海道工業大学研究紀要. 第30号. 189-196 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T. Murayama, Y .Fujiwara, T. Noto: "Evaluatiing Waste Vegetable Oils as a Diesel Fuel"Proceedings of the Institution of Mechanical Engineers. Vo1. 214, No. D2. 141-148 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Y. Fujiwara, T. Noto: "Influence of Biomass Fuels on Performance and Exhaust Emission of a Diesel Engine"Land Engine manufactures Association. No.461. 9-16 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] S. Nozu, Y. Fujiwara, S. Tosaka: "Formation Process of Toxic Substance from Bio Diesel Fuel"Memories of the Hokkaido Institute Technology. No. 30. 189-198 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] 野津 弘志, 藤原 康博, 登坂 茂: "ディーゼル機関用バイオ系燃料から生成される要害成分に関する研究"北海道工業大学研究紀要. 第30号(平成14年3月掲載). 1-8 (2002)

    • Related Report
      2001 Annual Research Report
  • [Publications] 藤原 康博, 能戸 正: "バイオ系燃料がディーゼル機関の性能ならびに排気特性に及ぼす影響"日本陸用内燃機関誌. 461号(昨年度掲載漏れ). 9-16 (2000)

    • Related Report
      2001 Annual Research Report
  • [Publications] T.Murayama,Y.Fujiwara and T.Noto: "Evaluating waste vegetable oils as a diesel fuel"Institution of Mechanical Engineers PART D. Vol.214 No.D2. 141-148 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] 野津弘志,登坂茂,藤原康博: "バイオ系燃料から生成される有害成分について"日本機械学会北海道支部第40回講演会講演概要集. No.002-1. 180-181 (2000)

    • Related Report
      2000 Annual Research Report

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Published: 1998-04-01   Modified: 2016-04-21  

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