• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Development of Sequential Metal Vapor Elution Analysis

Research Project

Project/Area Number 10650796
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field 工業分析化学
Research InstitutionMIE UNIVERSITY

Principal Investigator

OHTA Kiyohisa  Mie University, Faculty of Engineering, Professor, 工学部, 教授 (50024609)

Co-Investigator(Kenkyū-buntansha) MIZUNO Takayuki  Mie University, Faculty of Engineering, Professor, 工学部, 教授 (80200012)
Project Period (FY) 1998 – 1999
Project Status Completed (Fiscal Year 1999)
Budget Amount *help
¥3,400,000 (Direct Cost: ¥3,400,000)
Fiscal Year 1999: ¥1,600,000 (Direct Cost: ¥1,600,000)
Fiscal Year 1998: ¥1,800,000 (Direct Cost: ¥1,800,000)
KeywordsSequential metal vapor elution analysis (SMVEA) / Environmental sample analysis / Biological material analysis / metal alloy analysis / Cu / Zn / Cd / 金属蒸気分離分析 / SMVEA / ロジウム / ニッケル / オスミウム
Research Abstract

Many researchers have reported the determination of ultra trace metals in biological materials and waters by atomic absorption spectrometry (AAS), inductively coupled plasma atomic emission spectrometry (ICP-AES) or ICP mass spectrometry (MS). However, there are some problems such as optical and chemical interferences for the determination in these samples. To eliminate the interferences from matrix elements, adsorption, flotation, ion exchange, liquid-liquid extraction, matrix modifier, and standard addition methods have been used. Sequential metal vapor elution analysis (SMVEA), which separates metal vapors directly, can be expected to eliminate the interferences on the determination of trace metals. Therefore, the development of SMVEA using an AAS detector was studied.
◎ Fundamental study for the development of SMVEA
The following fundamental experiments were performed for the development of SMVEA.
○ Determination of nickel in water by electrothermal AAS (ETAAS) with preconcentration o … More n tungsten foil. ○ Determination of rhodium in waters by Mg-W cell electrodeposition and ETAAS. ○ Mg-W cell - ETAAS method - determination of gold in environmental samples. ○ Determination of bismuth in environmental samples with Mg-W cell - ETAAS. ○ Determination of cobalt with a tungsten tube atomizer by ETAAS and its use for the analysis biological materials. ○ Determination of osmium in waste by graphite furnace AAS.
These studies served to elucidate the atomization characteristics of Ni, Rh, Au, Sb, Te, Co, and Os in tungsten tube or graphite tube.
◎ Development and application of SMVEA
○ SMVEA of solid samples for determination of Cu and Mn in biological materials. ○ SMVEA for determination of Cu and Mn in biological materials and waters. ○ Lead and zinc determination in copper alloys by SMVEA with an improved column. From the studies, the advantages of SMVEA are as follows :
(1) direct separation of metal vapors. (2) Rapid analysis without prior chemical treatment. (3) Simplicity. (4) Elimination of Spectral and chemical interferences occurring in conventional AAS and ICP-AES. (5) Possibility as powerful accessory of analytical instruments like mass spectrometer. Less

Report

(3 results)
  • 1999 Annual Research Report   Final Research Report Summary
  • 1998 Annual Research Report
  • Research Products

    (34 results)

All Other

All Publications (34 results)

  • [Publications] S. Kaneco: "Determination of Rhodium in Waters by Mg-W Cell Electrodeposition and Electrothermal Atomic Absorption Spectrometry"Talanta. 46・1. 139-143 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] K. Ohta: "Determination of Nickel in Water by Electrothermal Atomic Absorption Spectrometry with Preconcentration on Tungsten Foil"Mikrochimica Acta. 129. 127-132 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T. Suzuki: "Determination of Osmium in Waste Water by Graphite Furnace Atomic Absorption Spectrometry"Mikrochimica Acta. 129. 259-263 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] S. Itoh: "Determination of Bismuth in Environmental Samples with Mg-W Cell-Electrothermal Atomic Absorption Spectrometry"Analytica Chimica Acta. 379. 169-173 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] S. Itoh: "Mg-W Cell-Electrothermal Atomic Absorption Spectrometry Method-Determination of Gold in Environmental Samples"Journal of Environmental Analytical Chemistry. 69・2. 181-189 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] S. Kaneko: "Determination of Cobalt with a Tungsten Tube Atomizer by Electrothermal atomic Absorption Spectrometry and its Use for the Anlysis of Biological Matherials"Microchimica Acta. 131・1. 205-210 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] K. Ohta: "Sequential Metal Vapor Elution Analysis of Solid Samples for The Determination of Cd and Zn in Biological Materials"Annali di Chimica. 89・5/6. 435-443 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] K. Ohta: "Lead and Zinc Determination in Copper Alloys by Sequential Metal Vapor Elution Analysis with an Improved Column"Chemia Analityczna. 44. 187-194 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] K. Ohta: "Sequential Metal Vapor Elution Analysis for Determination of Copper and Manganese in Biological Materials and Water"Talanta. 48・4. 943-949 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] S. Kaneko: "Determination of Rhodium in Waters by Mg-W Cell Electrodeposition and Electrothermal Atomic Adsorption Spectrometry"Talanta. 46(1). 139-143 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] K. Ohta: "Determination of Nickel in Water by Electrothermal Atomic Adsorption Spectrometry with Preconcentration on Tungsten Foil"Miktochim. Acta. 129. 127-132 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T. Suzuki: "Determination of Osmium in Waste Water by Graphite Furnace Atomic Adsorption Spectrometry"Miktochim. Acta. 129. 259-263 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] S. Itoh, S. Kaneko, K. Ohta, T. Mizuno: "Determination of Bismuth in Environmental Samples with Mg-W cell - Electrothermal Atomic Adsorption Spectrometry"Anal. Chim. Acta. 379. 169-173 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] S. Itoh: "Mg-W Cell - Electrothermal Atomic Adsorption Spectrometry Method - Determination of gold in Environmental Samples"J. Enviro. Anal. Chem.. 69(2). 181-189 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] S. Kaneko: "Determination of Cobalt with a Tungsten Tube Atomizer by Electrothermal Atomic Adsorption Spectrometry and its Use for the Analysis of Biological Materials"Microchim Acta.. 131(1). 205-210 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] K. Ohta, H. Uegomori, S. Kaneko, T. Mizuno: "Sequential Metal Vapor Elution Analysis of Solid Samples for the Determination of Cd and Zn in Biological Materials"Annali di Chimica. 98 (5/6). 435-443 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] K. Ohta: "Lead and Zinc Determination in Copper Alloys by Sequential Metal Vapor Elution Analysis with an Improved Column"ChemiaAnalityczna. 44. 187-194 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] K. Ohta: "Sequential Metal Vapor Elution Analysis for Determination of Copper and Manganese in Biological Materials and Water"Talanta. 48(4). 943-949 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] S.Kaneco: "Determination of Rhodium in Waters by Mg-W Cell Electrodeposition and Electrothermal Atomic Absorption Spectrometry"Talanta. 46・1. 139-143 (1998)

    • Related Report
      1999 Annual Research Report
  • [Publications] K.Ohta,: "Determination of Nickel in Water by Electrothermal Atomic Absorption Spectrometry with Preconcentration on Tungsten Foil"Mikrochimica Acta. 129. 127-132 (1998)

    • Related Report
      1999 Annual Research Report
  • [Publications] T.Suzuki: "Determination of Osmium in Waste Water by Graphite Furnace Atomic Absorption Spectrometry"Mikrochimica Acta. 129. 259-263 (1998)

    • Related Report
      1999 Annual Research Report
  • [Publications] S.Itoh,: "Determination of Bismuth in Environmental Samples with Mg-W Cell-Electrothermal Atomic Absorption Spectrometry"Analytica Chimica Acta. 379. 169-173 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] S.Itoh,: "Mg-W Cell-Electrothermal Atomic Absorption Spectrometry Method-Determination of Gold in Environmetal Samples"Journal of Environmental Analytical Chemistry. 69・2. 181-189 (1998)

    • Related Report
      1999 Annual Research Report
  • [Publications] S.Kaneco,: "Determination of Cobalt with a Tungsten Tube Atomizer by Electrothermal Atomic Absorption Spectrometry and its Use for the Analysis of Biological Materials"Microchimica Acta. 131・1. 205-210 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] K.Ohta,: "Sequential Metal Vapor Elution Analysis of Solid Samples for The Determination of Cd and Zn in Biological Materials"Annali di Chimica. 89・5/6. 435-443 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] K.Ohta,: "Lead and Zinc Determination in Copper Alloys by Sequential Metal Vapor Elution Analysis with an Improved Column"Chemia Analityczna. 44. 187-194 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] K.Ohta,: "Sequential Metal Vapor Elution Analysis for Determination of Copper and Manganese in Biological Materials and Water"Talanta. 48・4. 943-949 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] S.Kaneco,J.Ogawa,S.Itoh,K.Ohta and T.Mizuno: "Determination of Rhodium in Waters by Mg-W Cell Electrodeposition and Electrothermal Atomic Absorption Spectrometry." Talanta. 46・1. 139-143 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] K.Ohta,K.Ishida,S.Itoh,S.Kaneco and T.Mizuno: "Determination of Nickel in Water by Electrothermal Atomic Absorption Spectrometry with Preconcentration on Tungsten Foil." Mikrochimica Acta. 129. 127-132 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] T.Suzuki,M.Miyata,K.Ohta,S.Kaneco and T.Mizuno: "Determination of Osmium in Waste Water by Graphite Furnace Atomic Absorption Spectrometry." Mikrochimica Acta. 129. 259-263 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] S.Ahsan,S.Kaneco,K.Ohta,T.Mizuno,T.Suzuki,M.Miyada,Y.Taniguti: "Electrothermal Atomic Absorption Spectrometric Determination of Lead in Calcium Drug Samples by Direct Atomization." Analytica Chimica Acta. 362・2/3. 279-284 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] S.Itoh,J.ogawa,S.Kaneco K.Ohta and T.Mizuno: "Mg-W Cell-Electrothermal Atomic Absorption Spectrometry Method-Determination of Gold in Environmetal Samples." Jounal of Environmental Analytical Chemistry. 69・2. 181-189 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] S.Ahsan,S.Kaneco,K.ohta,T.Mizuno and Y.Taniguchi: "Direct Determination of Cadmium in Calcium Drug Samples Using Electrothermal Atomic Absorption Spectrometry with a Metal Tube Atomizer and Thiourea as a Matrix Modifier" Talanta. 48・1. 63-69 (1999)

    • Related Report
      1998 Annual Research Report
  • [Publications] K.Ohta,H.Uegomori,S.Kaneco and T.Mizuno: "Sequential Metal Vapor Elution Analysis for Determination of Copper and Manganese in Biological Materials and Water." Talanta. 48・4. 943-949 (1999)

    • Related Report
      1998 Annual Research Report

URL: 

Published: 1998-04-01   Modified: 2016-04-21  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi