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Microstructural Design of Fine Particles by Improved Spray Pyrolysis

Research Project

Project/Area Number 10650830
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field 無機工業化学
Research InstitutionShonan Institute of Technology

Principal Investigator

KIEDA Nobuo  Shonan Institute of Technology, Faculty of Engineering, Associate Professor, 工学部, 助教授 (80169812)

Project Period (FY) 1998 – 1999
Project Status Completed (Fiscal Year 1999)
Budget Amount *help
¥2,900,000 (Direct Cost: ¥2,900,000)
Fiscal Year 1999: ¥1,000,000 (Direct Cost: ¥1,000,000)
Fiscal Year 1998: ¥1,900,000 (Direct Cost: ¥1,900,000)
KeywordsSpray Pyrolysis / Fine Particles / Microstructure
Research Abstract

Spray pyrolysis was improved by some novel ideas to realize microstructural design of fine powders. Ammine complexes of some metal species were used as precursors to control various reactions which took place in the solution droplets. Zinc Oxide particles prepared from ammonium hydroxide solutions of zinc carbonate had spherical balloon-like morphologies. The size of the particles and the shell thickness were markedly changed by addition of nitrate irons to the solutions. Zinc oxide-silver and zinc oxide-palladium composite particles were successfully produced from the same precursor solutions that contained Ag or Pd ammine complex ions. The metals turned into nano-sized grains that dispersed uniformly on the surface of zinc oxide balloon particles. Sol of some oxides were also used as the precursor solutions. Highly porous titanium dioxide particles and oxidesilver composite particles with unique microstructures were prepared from optimized solution compositions and process conditions.

Report

(3 results)
  • 1999 Annual Research Report   Final Research Report Summary
  • 1998 Annual Research Report
  • Research Products

    (9 results)

All Other

All Publications (9 results)

  • [Publications] N.Kieda, G.L.Messing: "Micro-Foamy Particles of Copper Oxide and Nitride by Spray Pyrolysis of Copper-ammine Complex Solutions"J. Mater. Sci. Lett.. 17・4. 299-301 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] N.Kieda, G.L.Messing: "Preparation of Silver Particles by Spray Pyrolysis of Silver-Diammine Complex Solutions"J. Mater. Res.. 13・6. 1660-1665 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T.Arii, Y.Sawada, N.Kieda, S.Seki: "TG-DTA-MS and Controlled-Rate TG of Ammonium Oxalate Monohydrate (NH_4)_2C_2O_4H_2O"J. Mass Spectrom. Soc. Jpn.. 47・6. 354-359 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T.Arii, Y.Sawada, N.Kieda, and S.Seki: "TG-DTA-MS and Controlled-Rate TG of Ammonium Oxalate Monohydrate (NHィイD24ィエD2)ィイD22ィエD2CィイD22ィエD2OィイD24ィエD2HィイD22ィエD2O"J.Mass.Spectr.Soc.Japan. 47(6). 354-359 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] N.Kieda and G.L.Messing: "Micro-Foamy Particles of Copper Oxide and Nitride by Spray Pyrolysis of Copper-ammine Complex Solutions"J.Mater.Sci.Lett.. 17(4). 299-301 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] N.Kieda and G.L.Messing: "Preparation of Silver Particles by Spray Pyrolysis of Silver-diammine Complex Solutions"J.Master.Res.. 13(6). 1660-1665 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] T.Arii,Y.Sawada,N.Kieda,S.Saki: "TG-DTA-MS and Controlled-Rate TG of Ammonium Oxalate Monohydrate (NH_4)_2C_2O_4・H_2O"J.Mass Spectrom.Soc.Jpn.. 47(6). 354-359 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] N.Kieda,G.L.Messing: "Micro-Foamy Particles of Copper Okide and Nitride by Spray Pyrolysis of Copper-ammine Complex Solutions" J.Mater.Sis.Lett.17・. 299-301 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] N.Kieda,G.L.Messing: "Preparation of Silver Particles by Spray Pyrolysis of Silver-diammine Complex Solutions" J.Mater.Res.13・6. 1660-1665 (1998)

    • Related Report
      1998 Annual Research Report

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Published: 1998-04-01   Modified: 2016-04-21  

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