| Project/Area Number |
10650862
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
高分子合成
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| Research Institution | IBARAKI UNIVERSITY |
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Principal Investigator |
KANEKO Masao IBARAKI Univ., Faculty of Science, Prof., 理学部, 教授 (90109794)
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| Project Period (FY) |
1998 – 2000
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| Project Status |
Completed (Fiscal Year 2000)
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| Budget Amount *help |
¥3,500,000 (Direct Cost: ¥3,500,000)
Fiscal Year 2000: ¥900,000 (Direct Cost: ¥900,000)
Fiscal Year 1999: ¥1,100,000 (Direct Cost: ¥1,100,000)
Fiscal Year 1998: ¥1,500,000 (Direct Cost: ¥1,500,000)
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| Keywords | Photoinduced electron transfer / Bipyridine Ru complex / Methylviologen / Nafion / Mechanism of electron transfer / Water oxidation catalyst / Proton reduction catalyst / 人工光合成 / ベルリンブラウン / 可視光 / フタロシアニン / 太陽光 / ルテニウム-アンミン錯体 / 人工光合成系 |
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| Research Abstract |
Electron transfer in a photoexcited state was investigated which is of importance for photochemical energy conversion. Ru(bpv)_3^<2+> and methylviologen (MV^<2+>) were adsorbed into a Nafion film and the electron transfer from the photoexcited Ru complex to MV^<2+> was studied. In order to elucidate the role of water, wet and dry films were compared with respect to the electron transfer. From the photoluminescence intensity of the Ru complex and its decay as a function of the MV^<2+> concentration, it was found that the electron transfer takes by a static mechanism for which the molecules do not move during the electron transfer. For the dry film the molecules do not move at all resulting in an entirely static mechanism. However, for the wet film, the molecules can move a little bit during the photoexcited state resulting in the partial involvement of a dynamic mechanism, and the reaction efficiency was much higher than that of the dry film. Electron transport in a ground state was studied electrochemically, and it was clarified that the mechanism, i.e., diffusion of molecules or charge hopping between molecules, are different depending on the system and the positive or negative charge.
As water oxidation catalysts, the catalytic activity of Ru complexes with ammonia or bipyridine ligands has been analyzed. The effects of interaction between the catalyst molecules in the polymer film on the four-electron process and on the bimolecular decomposition have been investigated. It was found that porphines and phthalocyanines dispersed in a polymer film has a high activity for the electrocatalytic proton reduction, and their fundamental behavior was studied.
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