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Monitoring of environmental pollution caused by the heavy oil spill accident at the Japan sea and evaluation of toxicities of polluted environmental samples

Research Project

Project/Area Number 10672106
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Environmental pharmacy
Research InstitutionKanazawa University

Principal Investigator

KIZU Ryoichi  Kanazawa University Graduate School of Natural Science and Engineering, Associate Professor, 大学院・自然科学研究科, 助教授 (80143915)

Co-Investigator(Kenkyū-buntansha) HAYAKAWA Kazuichi  Kanazawa University Faculty of Pharmaceutical Sciences, Professor, 薬学部, 教授 (40115267)
Project Period (FY) 1998 – 1999
Project Status Completed (Fiscal Year 1999)
Budget Amount *help
¥3,100,000 (Direct Cost: ¥3,100,000)
Fiscal Year 1999: ¥1,000,000 (Direct Cost: ¥1,000,000)
Fiscal Year 1998: ¥2,100,000 (Direct Cost: ¥2,100,000)
Keywordsheavy oil / oil spill accident / oil contamination / sea pollution / soil pollution / polycyclic aromatic hydrocarbon / mutagenicity / endocrine disrupting activity / 多環芳香族炭化水素
Research Abstract

A Russian tanker Nakhodka met a hull-broken accident in sailing in the Sea of Japan on January 2, 1997, releasing a huge quantity of heavy oil into the Sea of Japan and the spilled oil polluted the coastline from the Shimane Prefecture through the Yamagata Prefecture. So, we conducted extensive scientific studies to assess where and how long the pollution by the oil or chemicals persist in the environment and the impact of the spill on biological systems. The following results were obtained in the present study: 1) The survey of oil-polluted area in Ishikawa Prefecture revealed that several area have been still heavily polluted with oil even at 2 years post-accident while number of polluted area has decreased in the course of years. 2) Many of the coasts polluted with oil located at the area steep and hard to get near and had surfaces covered with rocks or boulder / cobble / pebble / gravel. It has been considered that much effort to remove the reached oil was not made and natural cleaning effect with those areas was small. 3) As for polycyclic aromatic hydrocarbons (PAHs) in reached oils, concentrations of PAHs with 3-to 6-rings did not decrease significantly and were approximately half those of the oil loaded in the Nakhodka. 4) Indirect mutagenicities of reached oils sampled at 1 year post accident were approximately 80% of those sampled immediately after the accident and found to correspond to the PAH concentrations in reached oils. 5) Heavy oils including the Nakhodka-loaded oil were found to show antiestrogenicity and this activity was due in part to PAHs.

Report

(3 results)
  • 1999 Annual Research Report   Final Research Report Summary
  • 1998 Annual Research Report
  • Research Products

    (41 results)

All Other

All Publications (41 results)

  • [Publications] 木津良一: "日本海重油流出事故"衛生化学. 44. 321-333 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Nariaki Takayama: "HPLC/Chemiluminescence Detection of Methamphetamine and Amphetamine in Black and White Hair Samples"Japanese Journal of Toxicological and Environmental Health. 44. 116-121 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Ryoichi Kizu: "Significance of Water Solubility in the Gastrointestinal Absorption of trans-Bis (n-valerato)(1R,2R-cycloexanediamine)(oxalato)platinum(IV)"Anti-Cancer Drugs. 9. 167-174 (198)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Kazuichi Hayakawa: "Flow Injection Analysis of C-Fuel Oil-Contaminated Samples Based on Fluorescence Detection of Polycyclic Aromatic Hydrocarbons"Analytical Science. 14. 845-847 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Ryoichi Kizu: "A New Orally Active Antitumor 1R,2R,-Cyclohexanediamine-Platnum(IV) Complex : trans-(n-Valerato)chloro(1R,2R-cyclohexanediamine)(oxalato) platinum (IV)"Cancer Chemotherapy and Pharmacology. 43. 97-105 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 木津良一: "重油のエストロゲン作用とその評価法"分析化学. 48. 617-622 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 早川和一: "化学発光検出HPLCを用いた発癌性ニトロアレーンの大気内挙動と毒性に関する研究"Chromatography. 20. 37-43 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Tsuyoshi Murahashi: "2-Nitrofluoranthene, 1-, 2- and 4-Nitropyrenes and 6-Nitrochrysene in Diesel-Engine Exhaust and Airborne Particulates"Journal Health Science. 45. 244-250 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Nariaki Takayama: "HPLC Study on Effects Permanent Wave, Dye and Decolorant Treatments on Methamphetamine and Amphetamine in Hair"Biomedical Chromatography. 13. 257-261 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Hitoshi Kakimoto: "Comparison of Atmospheric Polycyclic Aromatic Hydrocarbons and Nitropolycyclic Aromatic Hydrocarbons in Kanazawa, Sapporo and Tokyo"Journal Health Science. 46. 5-15 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Kazuichi Hayakawa: "Comparison of Polycyclic Aromatic Hydrocarbons and Nitropolycyclic Aromatic Hydrocarbons in Airborne and Automobile Exhaust Particulates"Polycyclic Aromatic Compounds. (In Press). (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Ryoichi Kizu: "Antiandrogenic Effect of Crude Extract of C-Heavy Oil"Materials Science & Engineering C. (In Press). (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Kazuichi Hayakawa: "Oil and Hydrocarbon Spills, Modeling, Analysis and Control"Computational Mechanics Publications. 372 (1998)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 木津良一: "衛生薬学"廣川書店. (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 木津良一: "薬学生のための臨床化学"南江堂. 227 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] 木津良一: "最新機器分析学"南山堂. 376 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Ryoichi Kizu, Kyoko Ando, Kazuichi Hayakawa.: "Oil Spill Accident in the Sea of Japan."Eisei Kagaku. 44. 321-333 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Nariaki Takayama, Seishi Tanaka, Ryoichi Kizu, Kazuichi Hayakawa.: "HPLC / Chemiluminescenece Detection of Methamphetamine and Amphetamine in Black and White Hair Samples."Japanese Journal of Toxicology and Environmental Health. 44. 116-121 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Ryoichi Kizu, Takeo Nakanishi, Shigeki Yamamoto, Kazuichi Hayakawa, Akio Matsuzawa, Masazumi Eriguchi, Yasutaka Takeda, Nachio Akiyama, Yoshinori Kidani.: "Significance of Water Solubility in the Gastrointestinal Absorption of trans-Bis(n-valerato)(1R,2R-cyclohexanediamine)(oxalato)platinum(IV)"Anti-Cancer Drugs. 9. 167-174 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Kazuichi Hayakawa, Akiko Utsumi, Ryoichi Kizu, Kyoko Ando.: "Flow Injection Analysis of C-Fuel Oil-Contaminated Samples Based on Fluorescence Detection of Polycyclic Aromatic Hydrocarbons"Analytical Science. 14. 845-847 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Ryoichi Kizu, Takeo Nakanishi, Kazuichi Hayakawa, Akio Matsuzawa, Masazumi Eriguchi, Yasutaka Takada, Nachio Akiyama, Tatsuko Tashiro, Yochinori Kidani: "A New Orally Active Antitumor 1R,2R-Cyclohexanediamine-Platinum(IV) Complex: trans-(n-Valerato)chloro(1R,2R-cyclohexanediamine)(oxalato)platinum(IV)"Cancer Chemotherapy and Pharmacology. 43. 97-105 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Ryoichi Kizu, Shoko Kato, Osamu Usui, Kazuichi Hayakawa.: "Estrogenic Activity of Heavy Oil and Its Assay Method."Bunseki Kagaku. 48. 617-622 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Kazuichi Hayakawa, Ryoichi Kizu, Kyoko Ando.: "Study on Atmospheric Behavior and Toxicity of Carcinogenic Nitroarenes by High-Performance Liquid Chromatography Using Chemiluminescence Detection"Chromatography. 20. 37-43 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Tsuyoshi Murahashi, Ryoichi Kizu, Hitoshi Kakimoto, Akire Toriba, Kazuichi Hayakawa.: "2-Nitrofluoranthene, 1-,2-and 4-Nitropyrenes and 6-Nitrochrysene in Diesel-Engine Exhaust and Airborne Particulates."Journal of Health Science. 45. 244-250 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Nariaki Takayama, Seishi Tanaka, Ryoichi Kizu, Kazuichi Hayakawa.: "HPLC Study on Effects Permanent Wave, Dye and Decolorant Treatments on Methamphetamine and Amphetamine in Hair."Biomedical Chromatography. 13. 257-261 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Hitoshi Kakimoto, Moritugu Kitamura, Yutaka Matsumoto, Shigekatsu Sakai, Fumio Kanoh, Tsuyoshi Murahashi, Kazuhiko Akutsu, Ryoichi Kizu, Kazuichi Hayakawa.: "Comparison of Atmospheric Polycyclic Aromatic Hydrocarbons and Nitropolycyclic Aromatic Hydrocarbons in Kanazawa, Sapporo and Tokyo"Journal of Health Science. 46. 5-15 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Kazuichi Hayakawa, Tsuyoshi Murahashi, Kazuhiko Akutsu, Tetsuo Kanda, Nei. Tang, Hitoshi Kakimoto, Ryoichi Kizu: "Comparison of Polycyclic Aromatic Hydrocarbons and Nitropolycyclic Aromatic Hydrocarbons in Airborne and Automobile Exhaust Particulates"Polycyclic Aromatic Compounds. In Press.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Ryoichi Kizu, Katsuaki Ishii, Jun Kobayashi, Takuma Hashimoto, Eitetsu Koh, Mikio Namiki, Kazuichi Hayakawa.: "Antiandrogenic Effect of Crude Extract of C-Heavy Oil"Materials Science & Engineering C.. In Press.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      1999 Final Research Report Summary
  • [Publications] Ryoichi Kizu: "A New Orally Active Antiumor 1R, 2R,-Cyclohexanediamine-Platinum (IV) Complex : trans- (n- Valerato) chloro (1R, 2R-cyclohexanediamine)(oxalato) platinum (IV)"Cancer Chemotherapy and Pharmacology. 43. 97-105 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 木津良一: "重油のエストロゲン作用とその評価法"分析化学. 48. 617-622 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 早川和一: "化学発光検出HPLCを用いた発癌性ニトロアレーンの大気内挙動と毒性に関する研究"Chromatography. 20. 37-43 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Tsuyoshi Murahashi: "2-Nitrofluoranthene, 1-, 2- and 4-Nitropyrenes and 6-Nitrochrysene in Diesel-Engine Exhaust and Airborne Particulates"Journal of Health Science. 45. 244-250 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Nariaki Takayama: "HPLC Study on Effects Permanent Wave, Dye and Decolorant Treatments on Methamphetamine and Amphetamine in Hair"Biomedical Chromatography. 13. 257-261 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Hitoshi Kakimoto: "Comparison of Atmospheric Polycyclic Aromatic Hydrocarbons and Nitropolycyclic Aromatic Hydrocarbons in Kanazawa, Sapporo and Tokyo"Journal of Health Science. 46. 5-15 (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] Kazuichi Hayakawa: "Comparison of Polycyclic Aromatic Hydrocarbons and Nitroploycyclic Aromatic Hydrocarbons in Airborne and Automobile Exhaust Particulates"Polycyclic Aromatic Compounds. In Press. (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] Ryoichi Kizu: "Antiandrogenic Effect of Crude Extract of C-Heavy Oil"Materials Science & Engineering C. In Press. (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] 木津良一: "衛生薬学"廣川書店. 429 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 木津良一: "薬学生のための臨床化学"南江堂. 227 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] 木津良一: "最新機器分析学"南山堂. 376 (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] Kazuichi Hayakawa: "Flow Injection Analysis of C-Fuel Oil-Contaminated Samples Based on Fluorescence Detection of Polycyclic Aromatic Hydrocarbons" Analytical Sciences. 14・4. 845-847 (1998)

    • Related Report
      1998 Annual Research Report
  • [Publications] 木津良一: "日本海重油流出事故" 衛生化学. 44・5. 321-333 (1998)

    • Related Report
      1998 Annual Research Report

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Published: 1998-04-01   Modified: 2016-04-21  

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