• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Plasma Steam Reforming of Natural Gas

Research Project

Project/Area Number 10680463
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field プラズマ理工学
Research InstitutionNAGASAKI UNIVERSITY

Principal Investigator

TANABE Shuji  Nagasaki University, Faculty of Engineering, Associate Professor, 工学部, 助教授 (50171814)

Co-Investigator(Kenkyū-buntansha) OKITSU Kenji  Nagasaki University, Faculty of Engineering, Research Fellow, 工学部, 助手 (60295095)
MATSUMOTO Hiroshige  Nagasaki University, Faculty of Engineering, Professor, 工学部, 教授 (10039787)
Project Period (FY) 1998 – 2000
Project Status Completed (Fiscal Year 2000)
Budget Amount *help
¥2,700,000 (Direct Cost: ¥2,700,000)
Fiscal Year 2000: ¥500,000 (Direct Cost: ¥500,000)
Fiscal Year 1999: ¥500,000 (Direct Cost: ¥500,000)
Fiscal Year 1998: ¥1,700,000 (Direct Cost: ¥1,700,000)
KeywordsPlasma / Steam-Reforming / Silent Discharge / Hydrogen / Natural Gas / Methane / 水素製造
Research Abstract

To produce hydrogen from the natural gas and water some plasma reactors and reaction system were investigated for three years since 1998. Two types of the reactors, i.e., dielectric-barrier discharge (DBD) type and packed bed discharge type reactors were made and examined. The former reactor was consisted of a cylindrical Cu rod (inner electrode), quartz-glass tube, and a piece of Cu foil tape (outer electrode). High voltage electric power was applied between two electrodes, and the plasma occurred in a small space between inner electrode and quartz tube. The natural gas and water reacted through such small plasma zone. Then, hydrogen was produced. During the reaction, some carbon species were produced by cracking of methane because C2 radicals were observed with emission spectroscopy. These carbon species were quite active, and could react with excited water molecules in the plasma zone. We concluded that methane was easily converted to hydrogen with water, via active carbon species on electrode surface. The latter reactor was consisted of two electrodes and pelletized BaTiO3. BaTiO3 was placed between two disc-type electrode. High voltage was applied between the electrodes, and plasma occurred small space between BaTiO3 grains. The performance of this reactor is not better than that of dielectric barrier discharge reactor because the reaction conditions were not optimized. We expected that the packed bed reactor would show similar performance with DBD reactor if optimized condition could be found out.

Report

(4 results)
  • 2000 Annual Research Report   Final Research Report Summary
  • 1999 Annual Research Report
  • 1998 Annual Research Report
  • Research Products

    (30 results)

All Other

All Publications (30 results)

  • [Publications] H.Matsumoto: "Selective oxidation of Methane to Methanol and Formaldehyde with Nitrous Oxide"J.Phys.Chem.A. (in press). (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] K.Okitsu: "Catalytic Behavior of Au Core- Pd Shell Nanoparticles on Silica Prepared by Sonochemical and Sol-Gel Processes"Chem.Lett.. 2000. 1336-1337 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Tanabe: "Generation of Hydrogen from Methanal in a Dielectric Barrier Discharge- Plasma"Chem.Lett. 2000. 1116-1117 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] K.Okitsu: "Sonachemical Preparation and Catalytic Behavior of Highly Dispersed Palladiam Nanoparticles on Alumina"Chem.Mater.. 12. 3006-3010 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] K.Okitsu, S.Nagaoka, S.Tanabe, and H.Matsumoto: "Sonochemical Preparation of Size-Controlled Palladium Nanopaulicles on Alumina Surface"Chem.Lett.. 271-272 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Tanabe, K.Egashira, K.Okitsu, and H.Matsumoto: "Partial Oxidation of Methane with Nitrous Oxide in a Dielectric-Barier Discharge System."Chem.Lett.. 871-872 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Matsumoto, S.Tanabe, K.Okitsu, Y.Hayashi and S.L.Suib: "Profiles of Carbon Dioxide Decomposition in a Dielectric-Barrier Discharge-Plasma Reactor"Bull.Chem.Soc.Jpn.. 72. 2567-2571 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Tanabe, H.Matsuo, H.Matsuguma, K.Okitsu, Y.Hayashi, H.Matsumoto, and S.L.Suib: "Oligomerization and Carbon Dioxide Reforming of Methane in a Dielectric-Barrier Discharge-Plasma."J.Petrol.Inst.Jpn.(Sekiyugakkaishi). 42. 383-391 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.L.Brock, T.Shimojo, M.Marquez, C.Marun, S.L.Suib, H.Matsumoto, and Y.Hayashi: "Factor Influencing the Decomposition of CO2 in AC Discharge Fan-Type Plasma Reactor : Frequency, Waveform, and Concentration Effects."J.Catal.. 184. 123-133 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] J.Wang, G.Xia, A.Huang, S.L.Suib, Y Hayashi, and H.Matsumoto: "CO2 Decomposition using Glow Discharge."J.Catal.. 185. 152-159 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] J.Luo, S.L.Suib, Y.Hayashi, and H.Matsumoto: "Emission Spectroscopic Stidies of Plasma Induced NO Decomposition and H2O Splitting."J.Phys.Chem.A. 103. 6151-6161 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] S.Tanabe. H.Matsuguma, K.Okitsu, and H.Matsumoto: "Generation of Hydrogen from Methanol in a Dielectric-Barrier Discharge-Plasma System."Chem.Lett.. 1116-1117 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] A.Huang, G.Xia, J.Wang, S.L.Suib, Y.Hayashi, and H.Matsumoto: "CO2 Reforming of CH4 by Atmospheric Pressure AC Discharge-Plasma."J.Catal.. 189. 349-359 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] K.Okitsu, A.Yue, S.Tanabe, and H.Matsumoto: "Sonochemical Preparation and Catalytic Behavior of Highly Dispersed Palladium Nanoparticles on Alumina."Chem.Mater.. 12. 3006-3010 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] J.Luo, S.L.Suib, Y.Hayashi, and H.Matsumoto: "Water Splitting in Low-Temperature AC Plasmas at Atmospheric Pressure."Research Chem.Intermediate. 26. 851-876 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] K.Okitsu, M.Murakami. S.Tanabe, and H.Matsumoto: "Sonochemical Preparation of Supported Metal Catalysts."Trans.Mater.Res.Soc.Jpn.. 25. 87-90 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] K.Okitsu, M.Murakami, S.Tanabe, and H.Matsumoto: "Catalytic Behavior of Au Core-Pd Shell Nanoparticles on Silica Prepared by Sonochemical and Sol-Gel Processes."Chem.Lett.. 1336-1337 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] F.J.Spiess, X.Chen, S.L.Brock, S.L.Suib, Y.Hayashi, and H.Matsumoto: "Destruction of Freons by the Use of High Voltage Glow Plasma."J.Phys.Chem.A. 104. 11111-11120 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] A.Huang, G.Xia, F.J.Spiess, X.Chen, J.Rozak, S.L.Suib, Y.Hayashi, and H.Matsumoto: "Combination of Glow-Discharge and Arc plasmas for CF4 Abatement."J.Catal.. (in press). (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Matsumoto, S.Tanabe, K.Okitsu, Y.Hayashi, and S.L.Suib: "Selective Oxidation of Methane to Methanol and Formaldehyde with Nitrous Oxide in a Silent-Discharge Plasmas."J.Phys.Chem.A. 105 (in press). (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] K.Okitsu, A.Yue, S.Tanabe, and H.Matsumoto: "Characterization of Quantum-Sized Palladium Clusters on Y-Zeolite Prepared by Sonochemical Process."Chem.Mater.. 13 (in press). (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] G.Xia, J.Wang, A.Huang, S.L.Suib, Y.Hayashi, and H.Matsumoto: "A Novel Y-Type Reactor for Selective Excitation of Atmospheric Pressure Glow Discharge Plasma."Review Sci.Instruments. (in press). (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] H.Matsumoto: "Selective Oxidation of Methane to Methanol and Formaldehyde with Nitrous Oxide"J.Phys.Chem.A. (in press). (2001)

    • Related Report
      2000 Annual Research Report
  • [Publications] K.Okitsu: "Catalytic Behavior of Au Core-Pd Shell Nanoparticles on Silica Prepared by Sonochemical and Sol-Gel processes"Chem.Lett.. 2000. 1336-1337 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] S.Tanabe: "Generation of Hydrogen from Methanal in a Dielectric Barrier Discharge-Plasma"Chem.Lett. 2000. 1116-1117 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] K.Okitsu: "Sonochemical Preparation and Catalytic Behavior of Highly Dispersed Palladium Nanoparticles on Alumina"Chem.Mater.. 12. 3006-3010

    • Related Report
      2000 Annual Research Report
  • [Publications] Shuji Tanabe: "Partial Oxidation of Methane with Nitrous Oxide in a Dielectric-Barrier Discharge System"Chemistry Letters. 1999・5. 871-872 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Shuji Tanabe: "Oligomerization and Carbon Dioxide Reforming of Methane in a Dielectric-barrier Discharge-plasma System"Journal of The Japan Petroleum Institute. 42・5. 383-391 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Hiroshige Matsumoto: "Profiles of Carbon Dioxide Decomposition in a Dielectric-barrier Discharge-Plasma System"Bulletin of the Chemical Society of Japan. 72・5. 2567-2571 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Kenji Okitsu: "Sonochemical Preparation of Size-Controlled Palladium Nanoparticles on Alumina Surface"Chemistry Letters. 1999・2. 271-272 (1999)

    • Related Report
      1999 Annual Research Report

URL: 

Published: 1998-04-01   Modified: 2016-04-21  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi