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Chemical Energy and Information Conversion by Utilizing Molecular Synchronization of Polymer Networks

Research Project

Project/Area Number 11167234
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionYokohama National University

Principal Investigator

WATANABE Masayoshi  Yokohama National Univ., Faculty of Engineering, Professor, 大学院・工学研究院, 教授 (60158657)

Co-Investigator(Kenkyū-buntansha) 竹岡 敬和  横浜国立大学, 大学院・工学研究院, 助手 (20303084)
今林 慎一郎  横浜国立大学, 大学院・工学研究院, 助教授 (50251757)
Project Period (FY) 1998 – 2002
Project Status Completed (Fiscal Year 2002)
Budget Amount *help
¥49,500,000 (Direct Cost: ¥49,500,000)
Fiscal Year 2002: ¥12,000,000 (Direct Cost: ¥12,000,000)
Fiscal Year 2001: ¥13,800,000 (Direct Cost: ¥13,800,000)
Fiscal Year 2000: ¥13,800,000 (Direct Cost: ¥13,800,000)
Fiscal Year 1999: ¥9,900,000 (Direct Cost: ¥9,900,000)
KeywordsMolecular Synchronization / Materials System / Energy Conversion / Information Conversion / Polymer Network / イオン性液体 / イオンゲル / プロトン伝導 / 電子輸送 / 生体電子移動反応 / 電子メディエーター / コロイド結晶 / ハイドロゲル / 化学情報変換 / 酸化還元酵素 / 電子伝達 / グルコースオキシダーゼ / フェノチアジン / タンパク質ハイブリッド / 化学エネルギー変換 / 多分岐高分子 / イオン伝導 / 固体電解質 / ポリマー電池 / ボリピロール / イオン伝導体 / 分子認識
Research Abstract

In polymer networks whose structures are determined by the balance between weak intermolecular-interactions, such as hydrogen bonding, ion-dipole, electrostatic, and hydrophobic interactions, it is frequently observed that a tiny fluctuation toward functional groups in the network polymers is quantitatively converted to a different fluctuation, which is transferred, in a spatially and chronologically synchronized manner, over the whole networks. In other words, the weakly correlated polymer networks function not only as a structural network but also as a network for transferring and converting energy and information. This research has been aimed at proposing a new methodology for the design of new materials system for chemical energy and information conversion by revealing "molecular synchronization" in the molecular level. In this research, the following three projects have been studied
1. In-situ polymerization of vinyl monomers in ionic liquids to form "ion gels" and their utilization in chemical energy conversion.
2. Electron transfer reaction of glucose oxidase modified with phenothiazine-labeled PEG for efficient chemical information conversion.
3. "Structurally-colored gels" prepared by using closest packing silica colloid crystals as a template and their structural color change in response to external stimuli.

Report

(5 results)
  • 2002 Annual Research Report   Final Research Report Summary
  • 2001 Annual Research Report
  • 2000 Annual Research Report
  • 1999 Annual Research Report
  • Research Products

    (39 results)

All Other

All Publications (39 results)

  • [Publications] K.Ban: "Electrical Communication between Glucose Oxidase and Electrodes Mediated by Phenothiazine-labeled Polyethylene oxide.) Bound to Lysine Residues on the Enzyme Surface"Anal.Chem.. 75. 910-917 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Y.Takeoka: "Template Synthesis of Chameleonic Poly(N-isopropylcrylamide)gels Using Self assembled Colloid Silica Crystals"Adv.Mater.. 15. 199-201 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] R.Kawano: "Equilibrium Potentials and Charge Transport of an I^-/I_3^- Redox Couple in an Ionic Liquid"Chem.Commun.. 2003. 330-331 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] A.Noda: "Bronsted Acid-Base Ionic Liquids as Proton Conducting Non-Aqueous Electrolytes"J.Phys.Chem.B. 107. 4024-4033 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Md.A, B.H.Susan: "Bronsted Acid-Base Ionic Liquids and Their Use as New Materials for Anhydrous Proton Conductors"Chem.Commun.. 2003. 938-939 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] K.Ban, T.Ueki, Y.Tamada, T.Saito, S.Imabayashi, M.Watanabe: "Electrical Communication between Glucose Oxidase and Electrodes Mediated by Phenothiazine-labeled Poly (ethyene oxide) Bound to Lysine Residues on the Enzyme Surface"Anal. Chem.. 75. 910-917 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Y.Takeoka, M.Watanabe: "Template Synthesis of Chameleonic Poly (N-isopropylcrylamide) gels Using Self-assembled Colloid Silica Crystals"Adv. Mater.. 15. 199-201 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] R.Kawano, M.Watanabe: "Equilibrium Potentials and Charge Transport of an I/I, Redox Couple in an Ionic Liquid"Chem. Commun.. 2003. 330-331

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] A.Noda, M.A.B.H.Susan, K.Kudo, S.Mitsushima, K.Hayamizu, M.Watanabe: "Bronsted Acid-Base Ionic Liquids as Proton Conducting Non-Aqueous Electrolytes"J. Phys. Chem. B.. 107. 4024-4033 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Md.A.B.H.Susan, A.Noda, S.Mitsushima, M.Watanabe: "Bronsted Acid-Base Ionic Liquids and Their Use as New Materials for Anhydrous Proton Conductors"Chem. Commun. 2003. 938-939

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] S.Imabayashi, K.Ban, T.Ueki, M.Watanabe: "Comparison of Catalytic Electrochemistry of Glucose Oxidase Between Covalently Modified and Freely-diffusing Phenothiazine-labeled Poly (ethylene oxide) Mediator Systems"J. Phys. Chem. B. 107. 8834-8839 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] D.Nakayama, Y.Takeoka, M.Watanabe, K.Kataoka: "Simple and Precision Preparation of Porous Gel for Colorimetric Glucose Sensor by Templating Technique"Angew. Chem. Int. Ed.. 42. 4197-4200 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] H.Tokuda: "Synthesis, Characterization, and Ion-conductive Behavior in an Organic Solvent and in a Polyether of a Novel Lithium Salt of a Perfluorinated Polyimide Anion"Macromolecules. 35. 1403-1411 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] Y.Takeoka: "Polymer Gels that Memorize Structures of Mesoscopically Sized Templates. Dynamic and Optical Nature of Periodic Ordered Mesoporous Chemical Gels"Langmuir. 18. 5977-5980 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] K.Ban: "Electrical Communication between Glucose Oxidase and Electrodes Mediated by Phenothiazine-labeled Poly(ethylene oxide) Bound to Lysine Residues on the Enzyme Surface"Anal. Chem.. 75. 910-917 (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] Y.Takeoka: "Template Synthesis of Chameleonic Poly(N-isopropylcrylamide)gels Using Self-assembled Colloid Silica Crystals"Adv. Mater.. 15. 199-201 (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] R.Kawano: "Equilibrium Potentials and Charge Transport of an I^-/I_3^-Redox Couple in an Ionic Liquid"Chem. Commun.. 2003. 330-331 (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] A.Noda: "Bronsted Acid-Base Ionic Liquids as Proton Conducting Non-Aqueous Electrolytes"J. Phys. Chem. B. (in press). (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] 渡邉 正義(共著): "物質科学入門"化学同人. 204 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] T.Hirakimoto: "Effects of Addition of a Boroic Acid Ester Monomer to Electrolyte Solutions and Gel Electrolytes on Their Ionic Transport Properties"Electrochim.Acta. 46. 1609-1614 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] M.Watanabe: "Anionic Effect on Ion Transport Properties in Network Polyether Electrolytes"Electrochim.Acta. 46. 1487-1491 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] K.Ban: "Fast Electron Transfer between Glucose Oxidase and Electrodes via Phenothiazine Mediators with Poly(ethylene oxide) Spacers"Electrochem.Commun.. 3. 649-653 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] D.Nakayama: "Electrochemical Study on Swelling Change of Poly(N-isopropyle acrylamide) Gels in Response to Additives by Using Hydrogel-modified Microdisk Electrodes and a Redox Probe"Electrochemistry. 69. 1002-1007 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] H.Tokuda: "Synthesis, Characterization, and Ion-conductive Behavior in an Organic Solvent and in a Polyether for Novel Lithium Salt of a Perfluorinated Polyimide Anion"Macromolecules. 35. 1403-1411 (2002)

    • Related Report
      2001 Annual Research Report
  • [Publications] S.Aoki: "Electron Transfer Reaction of Glucose Oxidase Hybrids Modified with Phenothiazine via Poly(ethylene oxide) Spacer on Acidic Amino Acid Residues"Chem.Lett.. 2002. 256-257 (2002)

    • Related Report
      2001 Annual Research Report
  • [Publications] 渡邉 正義(分担執筆): "21世紀のリチウム二次電池技術"シーエムシー. 215 (2002)

    • Related Report
      2001 Annual Research Report
  • [Publications] A.Noda: "Highly Conductive Polymer Electrolytes Prerared by in situ Polymerization or Vinyl Monomers in Room Temperature Molten Salts"Electrochim.Acta. 45. 1265-1270 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] M.Kono: "Characterization or Polymer Gel Electrolytes Based on a Poly (alkylene oxide) Macromonomer for Application to Lithium Batteries"J.Electrochem.Soc.,. 147. 2517-2524 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] S.Imabayashi: "Amperometric Detection of Polyphenols Using Peroxidase-Immobilized Gold Electrodes"Chem.Lett.. 2000. 1020-1021 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Ismail: "XPS Study of Lithium Surface after Contact with Lithium-Salt Doped Polymer Electrolytes"Electrochim.Acta. (in press).

    • Related Report
      2000 Annual Research Report
  • [Publications] J.Amanokura: "Polypyrrole/Polymer Electrolyte Composites Prepared by In-situ Polymerization of Pyrrole as Cathode/Electrolyte Material for Facile Electron Transfer at the Solid Interface"J.Electrochem.Soc.. (in press).

    • Related Report
      2000 Annual Research Report
  • [Publications] A.Noda: "Pulsed-Gradient Spin-Echo ^1NMR and ^<19>F NMR Ionic Diffusion Coefficient, Viscosity and Ionic Conductivity of Non-Chloroaluminate Room Temperature Ionic Liquids"J.Phys.Chem.B. (in press).

    • Related Report
      2000 Annual Research Report
  • [Publications] 渡辺正義 (分担執筆): "季刊化学総説No.48 新型電池の材料化学"学会出版センター (印刷中).

    • Related Report
      2000 Annual Research Report
  • [Publications] 渡辺正義 (分担執筆): "電気化学"丸善 (印刷中). . (2001)

    • Related Report
      2000 Annual Research Report
  • [Publications] A. Nishimoto, K. Agehara, N. Furuya, T. Watanabe, M. Watanabe: "High Ionic Conductivity of Polyether-Based Polymer Electrolytes Having Hyperbranched Side Chains"Macromolecules. 32. 1541-1548 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] T. Saito, M. Watanabe: "Electron Transfer Reaction from Glucose Oxidase to an Electrode via Redox Copolymers"Polym. J.. 31. 1149-1154 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] M. A. B. H. Susan, K. Tani, M. Watanabe: "Surface Activity and Redox Behavior of Nonionic Surfactants Containing an Anthraquinone Group as the Redox-active Site"Colloid & Polym. Sci.. 277. 1125-1133 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] J. Amanokura, Y. Suzuki, S. Imabayashi, M. Watanabe: "Preparation of Polypyrrole/Polymer Electrolyte Composites with Concentration Grandient of Polypyrrole as Cathode/Electrolyte Material for Lithium Secondary Battery"Electrochemistry. 67. 1159-1161 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] M. A. B. H. Susan, M. Begum, Y. Takeoka, M. Watanabe: "Effect of pH and the Extent of Micellization on the Redox Behavior of Nonionic Surfactants Containing an Anthraquinone Group"J. Electroanal. Chem.. (in press).

    • Related Report
      1999 Annual Research Report

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Published: 1999-04-01   Modified: 2018-03-28  

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