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Development of Clean Coal Technology for Mitigating Global Warming

Research Project

Project/Area Number 11218101
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionKYOTO UNIVERSITY

Principal Investigator

MIURA Kouichi  Grad. School Engineering, Professor, 工学研究科, 教授 (40111942)

Co-Investigator(Kenkyū-buntansha) SUZUKI Toshimitsu  Kansai Univ., Faculty Eng., Professor, 工学部, 教授 (70026045)
TOMITA Akira  Tohoku Univ. Inst. Multi. Res. Professor, 多元物質科学研究所, 教授 (80006311)
TAKARADA Takayuki  Gunma Univ., Faculty Eng., Professor, 工学部, 教授 (70154929)
SAITO Ikuo  National Institute of Advanced Industrial Science and Technology., Group leader, グループ長
MASUMOTO Ken  The Research Institute for Electric and Magnetic Materials., Director, 所長
前 一廣  京都大学, 工学研究科, 教授 (70192325)
齋藤 郁夫  産業技術総合研究所, エネルギー利用研究部門, 研究グループ長
Project Period (FY) 1999 – 2002
Project Status Completed (Fiscal Year 2002)
Budget Amount *help
¥11,000,000 (Direct Cost: ¥11,000,000)
Fiscal Year 2002: ¥3,500,000 (Direct Cost: ¥3,500,000)
Fiscal Year 2001: ¥2,300,000 (Direct Cost: ¥2,300,000)
Fiscal Year 2000: ¥3,000,000 (Direct Cost: ¥3,000,000)
Fiscal Year 1999: ¥2,200,000 (Direct Cost: ¥2,200,000)
KeywordsClean Coal Technology / Global Warming / Coal Pretreatment Method / Flue Gas Treatment / Trace Elements / de-SOx methods / de-NOx methods / Solvent Extraction of Coal
Research Abstract

The purposes of this project were to do fundamental researches for supporting the development of (A) new coal pretreatment methods, (B) in situ de-Nox/de-Sox methods, and c enhanced flue gas treatment methods. The developed technologies are for the utilization of low rank coals in power generation in the near future. The project was revised and/or modified through the internal assessment and evaluation by the steering committee. Main results obtained are (A) the developments of new coal pretreatment methods utilizing solvents, various forms of CaO particles, (B) the proposal of a new fluidized bed coal combustion concept and the development of de-Nox/de-Sox methods utilizing a macro porous CaO, and c de-Nox/de-Sox methods at room temperature utilizing an activated carbon fiber and the development of several new types of de-Nox/de-Sox sorbents. Furthermore, several methods were proposed for the measurement and removal of trace elements such as Hg and As. These outcomes will be surely utilized in the coal utilization technologies in the near future.
Endeavor was also made to make public the outcome of this project. The final report was prepared in English, and all the presentations at the review meeting were also made in English. Four distinct researchers from abroad made plenary lectures at the review meeting and a panel discussion was made on the future development of clean coal technology and international cooperation. In March of this year a symposium called "Clean Coal Technology" was organized by the head investigator at 225^<th> national meeting of the American Chemistry to advertise the results of this project. Furthermore, the publication of a special issue of one of internationally prestigious journals, FUEL, is now in progress to make public the outcome of the symposium. These activities will help the outcome of this project to be utilized world wide.

Report

(5 results)
  • 2002 Annual Research Report   Final Research Report Summary
  • 2001 Annual Research Report
  • 2000 Annual Research Report
  • 1999 Annual Research Report
  • Research Products

    (55 results)

All Other

All Publications (55 results)

  • [Publications] Miura K, Mae K, Li W, Kusakawa T, Morozumi F, Kumano A: "Estimation of Hydrogen Bond Distribution in Coal through the Analysis of OH Strength Bands in Diffuse Reflectance Infrared Spectrum Measured by in-situ Technique"Energy & Fuels. 15(3). 599-610 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Miura K, Mae K, Shimada M, Minami H: "Analysis of Formation Rates of Sulfur-Containing Gases during the Pyrolysis of Various Coals"Energy & Fuels. 15(3). 629-636 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Miura K, Shimada M, Mae K, Hwang YS: "Extraction of Coal below 350 ℃ in Flowing Non-polar Solvent"Fuel. 80(11). 1573-1582 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Miura K, Mae K, Hasegawa I, Chen H, Kumano A, Tamura K: "Estimation of hydrogen Bond Distributions Formed between Coal and Polar Solvents Using in -situ IR Technique"Energy & Fuels. 16(1). 23-31 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Miura K, Mae K, Ashida R, Tamura T, Ihara T: "Dewatering of coal through solvent extraction"Fuel. 81(11-12). 1417-1422 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Miura K, Mae K, Shindo H, Ashida R, Ihara T: "Extraction of Low Rank Coals Derived Oils at 350 ℃ for Producing Clean Fuels"J. Chem. Eng. Jpn. (in press).

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] J.Wang, T.Takarada: "Role of Calcium Hydroxide in Supercritical Water Gasifiction of Low-Rank Coal"Energy & Fuels. 15(2). 356-362 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Jie Wang, Kayoko Motishita, Takayuki Takarada: "High-Temperature Interactions between Coal Char and Mixtures of Calcium Oxide, Quartz, and Kaolinite"Energy & Fuels. 15(5). 1145-1152 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Jie Wang, Akira Takaya, Akira Tomita: "Leaching of Ashes and Chars for Examining Transformations of Trace Elements during Coal Combustion and Pyrolysis"Fuel誌(本特定研究の成果特集号)に投稿中.

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Jie Wang, Atul Sharma, Akira Tomita: "Determination of the Modes of Occurrence of Trace Elements in Coal by Leaching Coal and Coal Ashes"Energy Fuels. 17(1). 29-37 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Hao-Jie Fan, Koichi Matsuoka, Jie Wang, Akira Tomita: "Ultrasonic Loading of Calcium on Coal for Enhanced SO_2 Capture"Fuel. 82(5). 481-486 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Koichi Matsuoka, Aki Abe, Yohsuke Suzuki, Akira Tomita: "Effectiveness of Hydrothermal Treatment of Coal with Lime for Removal of Trace Elements"Energy Fuels. 16(4). 920-924 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Koichi Matsuoka, Aki Abe, Akira Tomita: "Suppression of SO_2 Emission during Coal Oxidation with Calcium Loaded by Hydrothermal or Hydration Treatment"Energy Fuels. 15(3). 648-652 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] N.Ikenaga, N.Chiyoda, H.Matsushima, T.Suzuki: "Preparation of activated carbon-supported ferrite for absorbent of hydrogen sulfide at a low temperature"Fuel. 81. 1569-1576 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] H Matsushima, N.Ikenaga, T.Suzuki: "Development of Zinc Ferrite Absorbent for Hydrogen Sulfide Removal"Proceedings of the 7th China-Japan Symposium on Coal and Cl Chemistry. 415-418 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] T.Suzuki, H.Matsushima, N.Ikenaga: "Preparation and performance of activated carbon-supported zinc ferrite absorbent for hot-gas cleaning"Proceedings of 1 8th Annual International Pittsburgh Coal Conference. 03-11 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Y Ohgaito, H.Matsushima, N.I Ikenaga, T.Suzuki: "H_2S absorption behavior of ferrites prepared in the presence of coal"224th ACS National Meeting, Envir. Chem. Dey. Prep.. 135-135 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] N.Ikenaga, Y.Hirose, S.Yamamizu, H.Matsushima, T.Suzuki: "SO_2 Absorption Properties of CaO Prepared on Coal Char -As an absorbent in the fluidized-bed combusto"Proceedings of 19th Annual International Pittsburgh Coal Conference. 15-128 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] T.Suzuki, S.Yamamizu, N.Ikenaga: "Oyster Shell as a Novel Green Material for Gas Clean Up"Abstracts of The First International Conference on Green & Sustainable Chemistry A2-25. 148-148 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Miura K, Mae K, Li W, Kusakawa T, Morozumi F, Kumano A: "Est imation of Hydrogen Bond Distribution in Coal through the Analysis of OH Strength Bands in Diffuse Reflectance Infrared Spectrum Measured by in-situ Technique"Energy & Fuels. 15(3). 599-610 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Miura K, Mae K, Shimada M, Minami H: "Analysis of Formation Rates of Sulfur-Containing Gases during the Pyrolysis of Various Coals"Energy & Fuels. 15(3). 629-636 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Miura K, Shimada M, Mal K, Hwang YS: "Extraction of Coal below 350℃ in Flowing Non-polar Solvent"Fuel. 80(11). 1573-1582 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Miura K, Mae K, Hasegawa l, Chen H, Kumano A, Tamura K: "Estimation of hydrogen Bond Distributions Formed between Coal and Polar Solvents Using in -situ IR Technique"Energy & Fuels. 16(1). 23-31 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Miura K, Mae K, Ashida R, Tamura T, Ihara T: "Dewatering of coal through solvent extraction"Fuel. 81(11-12). 1417-1422 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Miura K, Mae K, Shindo H, Ashida R, Ihara T: "Extraction of Low Rank Coals Derived Oils at 350℃ for Producing Clean Fuels"J. Chem. Eng. Jpn. in press.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] J. Wang and T. Takarada: "Role of Calcium Hydroxide in Supercritical. Water Gasifiction of Low-Rank Coal"Energy & Fuels. 15(2). 356-362 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Jie Wang, Kayoko Motishita and Takayuki Takarada: "High-Temperature Interactions between Coal Char and Mixtures of Calcium Oxide, Quartz, and Kaolinite"Energy & Fuels. 15(5). 1145-1152 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Jie Wang, Akira Takaya, and Akira Tomita: "Leaching of Ashes and Chars for Examining Transformations of Trace Elements during Coal Combustion and Pyrolysis"Fuel.

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Haojie Fan, Koichi Matsuoka, Jie Wang, and Akira Tomita: "Ultrasonic Loading of Calcium on Coal for Enhanced SO_2 Capture"Fuel. 82(5), submitted. 481-486 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Jie Wang, Atul Sharm, and Akira Tomita: "Determination of the Modes of Occurrence of Trace Elements in Coal by Leaching Coal and Coal Ashes"Energy Fuels. 17(1). 29-37 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Koichi Matsuoka, Aki Abe, Yohsuke Suzuki, and Akira Tomita: "Effectiveness of Hydrothermal Treatment of Coal with Lime for Removal of Trace Elements"Energy Fuels. 16(4). 920-924 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Koichi Matsuoka, Aki Abe, and Akira Tomita: "Suppression of SO_2 Emission during Coal Oxidation with Calcium Loaded by Hydrothermal or Hydration Treatment"Energy Fuels. 15(3). 648-652 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] N. Ikenaga, N. Chiyoda, H. Matsushima, T. Suzuki: "Preparation of activated carbon-supported ferrite for absorbent of hydrogen sulfide at a low temperature"Fuel. 81. 1569-1576 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] H. matsushima, N. Ikenaga, T. Suzuki: "Development of Zinc Ferrite Absorbent for Hydrogen Sulfide Removal"Proceedings of the 7th China-Japan Symposium on Coal and Cl Chemistry, Hainan China. 415-418 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] T. Suzuki, H. Matsushima, N. Ikenaga: "Preparation and performance of activated carbon-supported zinc ferrite absorbent for hot-gas cleaning"Proceedings of 18th Annual International Pittsburgh Coal Conference. 3-11

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Y. Ohgaito, H. Matsushima, N. Ikenaga, T. Suzuki: "H2S absorption behavior of ferrites prepared in the presence of coal"224th ACS National Meeting. Envir. Chem. Dev. Prep. 135. (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] N. Ikenaga, Y. Hirose, S. Yamamizu, H. Matsushima, T. Suzuki: "SO2 Absorption Properties of CaO Prepared on Coal Char-As an absorbent in the fluidized-bed combustor"Proceedings of 19th Annual International Pittsburgh Coal Conference, Pittsburgh. 15-128 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] K.Miura, K.Mae, R.Ashida, T.Tamura, T.Ihara: "Dewatering of Coal through Solvent Extraction"Fuel. 81(11-21). 1417-1422 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] N.Ikenaga, N.Chiyoda, H.Matsushima, T.Suzuki: "Preparation of activated carbon-supported ferrite for absorption of hydrogen sulfide at a low temperature"Fuel. 81. 1569-1576 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] H.Fan, K.Matsuoka, J.Wang, A.Tomita: "Ultrasonic Loading of Calcium on Coal for Enhanced SO2 Capture"Fuel. 82. 481-486 (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] T.Yoshida, T.Takanohashi, K.Sakanishi, I.Saitou: "Relationship between Thermal Extraction Yield and Softening Temperature for Coals"Energy & Fuel. 16-4. 1006-1007 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] K.Mae, T.Maki, K.Miura: "A New Method for Estimating the Cross-linking Reaction during the Pyrolysis of Brown Coal"J. Chem. Eng. Japan. 35(8). 778-785 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] K.Matsuoka, A.Abe, Y.Suzuki, A.Tomita: "Effectiveness of Hydrothermal Treatment of Coal with Lime for Removal of Trace Elements"Energy & Fuel. 16-4. 920-924 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] K.Miura, K.Mae: "Dewatering of Coal through Solvent Extraction"Fuel. (印刷中).

    • Related Report
      2001 Annual Research Report
  • [Publications] T.Suzuki, H.Matsushima, N.Ikenaga: "Preparation and performance of activated carbon supported zinc ferrite absorbent for hot gas cleaning"Proceedings for 18th International Pittsburgh Coal Conference. (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] J.wang, K.Motishita, T.Takarada: "High-Temperature Interactions between Coal Char and Mixtures of Calcium Oxide, Quartz, and Kaolinite"Energy & Fuels. 15(5). 1145-1152 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] K.Matsuoka, A.Abe, A.Tomita: "Suppression of SO2 Emission during Coal Oxidation with Calcium Loaded by Hydrothermal or Hydration Treatment"Energy & Fuels. 15. 648-652 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] N.Ikenaga, H.Matsushima, Y.Ogaito.T.Suzuki: "Preparation of activated carbon-supported ferrite for absorbent of hydrogen sulfide at a low temperature"Fuel. (in press).

    • Related Report
      2001 Annual Research Report
  • [Publications] J.Wang, T.Takarada: "Role of Calcium Hydroxide in Supercritical Water Gasifiction"Energy & Fuels. 15-2. 356-362 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] K.Miura,K.Mae: "Extraction of Coal below 350℃ in a Flowing Non-polar Solvent"Fuel. (印刷中).

    • Related Report
      2000 Annual Research Report
  • [Publications] 三浦,前: "メタノール系混合溶剤で溶解した酸化改質炭の迅速熱分解"日本エネルギー学会. (印刷中).

    • Related Report
      2000 Annual Research Report
  • [Publications] K.Matsuoka,A.Abe,A.Tomita: "Suppression of SO2 emission during coal oxidation with calcium loaded by hydrothermal or hydration treatment."Energy & Fuels. (印刷中).

    • Related Report
      2000 Annual Research Report
  • [Publications] Jie Wang,Takayuki Takarada: "Fixation of Lead Chloride on Kaolinite and Bentonite at Temperatures between 550 and 950 ℃"IEA Research. 39. 335-341 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] T. Takarada: "Oxidation Behavior of CaS from Ca Ion-exchanged Coal"Fuel. 78. 883-890 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] K. Miura, K. Mae: "Examination of relationship between coal structure and pyrolysis yields using oxidized brown coals having different macromolecular networks"Fuel. 79・3. 417-425 (2000)

    • Related Report
      1999 Annual Research Report

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Published: 1999-04-01   Modified: 2018-03-28  

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