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Development of Clean Utilization Technologies of Low-grade Coals Combined with Biomass

Research Project

Project/Area Number 11218205
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionToyohashi University of Technology

Principal Investigator

NARUSE Ichiro  Faculty of Engineering, Associate Professor, 工学部, 助教授 (80218065)

Project Period (FY) 1999 – 2002
Project Status Completed (Fiscal Year 2002)
Budget Amount *help
¥28,200,000 (Direct Cost: ¥28,200,000)
Fiscal Year 2002: ¥2,600,000 (Direct Cost: ¥2,600,000)
Fiscal Year 2001: ¥8,300,000 (Direct Cost: ¥8,300,000)
Fiscal Year 2000: ¥8,500,000 (Direct Cost: ¥8,500,000)
Fiscal Year 1999: ¥8,800,000 (Direct Cost: ¥8,800,000)
KeywordsLow-grade coal / Biomass / Co-combustion / Nitrogen oxides / Ash particulates / Pulverized coal combustion / Coal gasification / Molten salt / 石炭 / 高温ガス精製 / 燃焼 / ガス化 / 脱硫 / バイオブリケット / 脱硝
Research Abstract

In order to utilize low-grade coals efficiently and cleanly, technologies of co-combustion or co-gasification of coal with biomass will contribute to enhancing utilization of low-grade coals. In this study, three kinds of experiments such as a biobriquette combustion, using an electrically heated batch combustor, co-combustion of coal with biomass, using an electrically heated drop tube furnace, and fundamental gasification of coal or biomass, using a molten salt gasifier, were carried out. For the biobriquette combustion, the ignition lag and burning rate of the biobriquette becomes shorter and faster than that of the coal briquette, respectively, since the biomass in the biobriquette plays a role for a trigger of ignition. Slaked lime can capture in situ SO_2 produced from the briquette. In the co-combustion experiments, the biomass can enhance ignition and burnout of the low-grade coal during the co-combustion. But, trend of NO and N_2O emissions during the co-combustion is similar with that during the coal combustion. The chemical kinetic simulation relating to NOx can also explain the trend of NOx behaviors obtained experimentally. However, heterogeneous reaction scheme seems to affect the trend of N_2O. In the biomass combustion, fine particulates with the particle size of less than 2μm are produced as ash particles. Burning the biomass with the coal, however, the fine particulates from the biomass are captured by the ash from the coal during the combustion. The molten salt coal gasifier seems to have such functions as in-furnace desulfurization, dust collection and catalytic action of carbon. It may be possible for the gasifier to produce a clean synthesis gas without a gas cleaning-up system even at relatively low temperature.

Report

(5 results)
  • 2002 Annual Research Report   Final Research Report Summary
  • 2001 Annual Research Report
  • 2000 Annual Research Report
  • 1999 Annual Research Report
  • Research Products

    (31 results)

All Other

All Publications (31 results)

  • [Publications] I.Naruse: "Fundamentals on co-combustion characteristics of low-grade coal with biomass"Proc. of the 225th American Chemical Society National Meeting in Fuel Symposia. 23-27 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] K.Sugiura: "Feasibility study of the co-generation system with direct internal reforming-molten carbonate fuel cell (DIR-MCFC) for residential use"Journal of Power Sources. 106. 51-59 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] H.Kim: "Modeling on Combustion Characteristics of Biocoalbriquttes"Journal of Energy Resources Technology. 123. 27-31 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] I.Naruse: "Fundamental Characteristics on Co-combustion of Low-rank Coal with Biomass"Proc. of the 18th Annual International Pittsburgh Coal Conference. Session 4 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] G.Lu: "Experimental study on combustion and pollutant control of biobriquette"Energy & Fuels. 14・6. 1133-1138 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] 杉浦公彦: "DIR-MCFCにおける触媒活性と触媒中の気相汚染度との関係(気相汚染触媒の再生法)"日本機械学会論文集(B編). 66・641. 249-255 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] 王青躍: "石炭バイオブリケットの燃焼特性と硫黄固定効果に関する研究"エアロゾル研究. 15・4. 364-371 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] 杉浦公彦: "直接内部改質式溶融炭酸塩型燃料電池における改質触媒の活性劣化(気相炭酸塩付着の影響)"日本機械学会論文集(B編). 65・629. 330-336 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] I. Naruse: "Fundamentals on co-combustion characteristics of low-grade coal with biomass"Proc. of the 225th American Chemical Society National Meeting in Fuel Symposia. 23-27 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] K. Sugiura: "Feasibility study of the co-generation system with direct internal reforming-molten carbonate fuel cell (DIR-MCFC) for residential use"Journal of Power Sources. 106. 51-59 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] H. Kim: "Modeling on Combustion Characteristics of Biocoalbriquttes"Journal of Energy Resources Technology. 123. 27-31 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] I. Naruse: "Fundamental Characteristics on Co-combustion of Low-rank Coal with Biomass"Proc. of the 18th Annual International Pittsburgh Coal Conference. Session 4. (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] G. Lu: "Experimental study on combustion and pollutant control of biobriquette"Energy & Fuels. 14(6). 1133-1138 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] K. Sugiura: "Relationship between catalytic activity and gas-phase pollution fractions in the catalyst in DIR-MCFC (Reactivation method of polluted catalyst by vapor-phase carbonate)"Transaction of the Japan Society of Mechanical Engineers, (B). 66(641). 249-255 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] Q-Y. Wang: "Studies on combustion and sulfur fixation characteristics of coal-biomass briquette"J. Aerosol Res., Jpn. 15(4). 364-371 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] K. Sugiura: "Deterioration of a catalytic activity in direct internal reforming-molten carbonate fuel cells"Transaction of the Japan Society of Mechanical Engineers, (B). 65(629). 330-336 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2002 Final Research Report Summary
  • [Publications] I.Naruse, K.Nishikawa, K.Morishita: "Fundamentals on co-combustion characteristics of low-grade coal with biomass"Proc. of the 225^<th> American Chemical Society National Meeting in Fuel Symposia. (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] K.Sugiura, I.Naruse: "Feasibility study of the co-generation system with direct internal reforming-molten carbonate fuel cell (DIR-MCFC) for residential use"Journal of Power Sources. 106. 51-59 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] I.Naruse, A.Gani, K.Morishita: "Fundamental Characteristics on Co-combustion of Low-rank Coal with Biomass"Proc. of the 18th Annual International Pittsburgh Coal Conference. Session4 (2001)

    • Related Report
      2002 Annual Research Report
  • [Publications] H.Kim, G.Lu, I.Naruse, J.Yuan, K.Ohtake: "Modeling on Combustion Characteristics of Biocoalbriquttes"Journal of Energy Resources Technology. 123. 27-31 (2001)

    • Related Report
      2002 Annual Research Report
  • [Publications] 杉浦公彦, 成瀬一郎: "DIR-MCFCにおける触媒活性と気相汚染度との関係(気相汚染触媒の再生法)"日本機械学会論文集(B編). 66・641. 249-255 (2000)

    • Related Report
      2002 Annual Research Report
  • [Publications] 王青躍, 成瀬一郎他8名: "石灰バイオブリケットの燃焼特性と硫黄固定効果に関する研究"エアロゾル研究. 15・4. 364-371 (2000)

    • Related Report
      2002 Annual Research Report
  • [Publications] G.Lu, I.Naruse他7名: "Experimental study on combustion and pollutant control of biobriquette"Energy & Fuels. 14・6. 1133-1138 (2000)

    • Related Report
      2002 Annual Research Report
  • [Publications] 杉浦公彦, 成瀬一郎, 大竹一友: "直接内部改質式溶融炭酸塩型燃料電池における改質触媒の活性劣化(気相炭酸塩付着の影響)"日本機械学会論文集(B編). 65・629. 330-336 (1999)

    • Related Report
      2002 Annual Research Report
  • [Publications] Ichiro Naruse: "Fundamental characteristics on co-combustion of low-rank coal with biomass"Proc. of the 18^<th> Pittsburgh Intl.Coal Conf.. (CD-ROM). (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] Hee-Joon Kim: "Modeling on Combustion Characteristics of Biocoalbriquttes"J. Energy Res. Tech.. 123. 27-31 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] 成瀬 一郎: "団体燃焼I 固体燃焼総論124,35-46,2001"燃焼研究. 124. 35-46 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] 成瀬 一郎: "石炭の燃焼技術"日本エネルギー学会誌. 80, 4. 216-228 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] G.Lu: "Experimental Study on Combustion and Pollutant Control of Biobriquette"Energy & Fuels. 14・6. 1133-1138 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Khairil: "Fundamental Reaction Characteristics of Pulverized Coal at High Temperature"ISIJ. 41・2. 136-141 (2001)

    • Related Report
      2000 Annual Research Report
  • [Publications] Ichiro Naruse et al.: "Ash deposition characteristics of pulverized coal under high temperature reaction conditions"Proc. of the 4th Intl. Symp. on Coal Combus.. 527-534 (1999)

    • Related Report
      1999 Annual Research Report

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Published: 1999-04-01   Modified: 2018-03-28  

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