| Project/Area Number |
11223205
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| Research Category |
Grant-in-Aid for Scientific Research on Priority Areas (B)
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| Allocation Type | Single-year Grants |
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| Review Section |
Science and Engineering
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| Research Institution | KYOTO UNIVERSITY |
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Principal Investigator |
OSUKA Atsuhiro Kyoto University, Graduate School of Science, Professor, 大学院・理学研究科, 教授 (80127886)
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| Co-Investigator(Kenkyū-buntansha) |
SHINMORI Hideyuki Kyoto University, Graduate School of Science, Inst., 大学院・理学研究科, 助手 (40311740)
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| Project Period (FY) |
1999 – 2001
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| Project Status |
Completed (Fiscal Year 2001)
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| Budget Amount *help |
¥35,400,000 (Direct Cost: ¥35,400,000)
Fiscal Year 2001: ¥4,700,000 (Direct Cost: ¥4,700,000)
Fiscal Year 2000: ¥26,000,000 (Direct Cost: ¥26,000,000)
Fiscal Year 1999: ¥4,700,000 (Direct Cost: ¥4,700,000)
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| Keywords | porphyrin array / meso-meso linked porphyrin arrays / monodisperse giant molecule / molecular wire / porphyrin sheet / ポルフィリンシート / 励起エネルギー移動 / 光合成モデル / ポルフィリン / 拡張ポルフィリン / 縮環ポルフィリン / 光機能材料 / 超分子 |
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| Research Abstract |
1) We have prepared a series of meso-meso linked diporphyrins strapped with variable length dioxymethylene group. These diporphyrins exhibit systematic spectral changes upon the decrease in the dihendral angle. Two-bands shape Soret band in non-strapped diporphyrins changes into four-bands shape Soret band.
2) Discrete 1024-mer of meso-meso linked porphyrin arrays has been prepared and charactrized, which is by far the longest man-made dicrete molecule. It is to be noted that even 1-240mer is certainly soluble in organic solvents and can be manipulated.
3) Oxidation with Sc(OTf)_3 and DDQ realized very efficient transformation of end-phenyl capped meso-meso linked porphyrin arrays to triply-linked conjugated porphyrin arrays. The absorption spectra of these conjugated 6-mer, 8-mer and 12-mer display the electronic absorption band deep into infrared region up to 1500 cm^<-1>.
Starting from 5,10-diaryl metalloporphyrin, conjugated rectangular-shaped porphyrin sheets have been prepared in 10-15% yields, which have 2-dimensionally expanded π-network.
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