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Summary of Molecular Methodology and Reaction Control of Oxygen Active Species

Research Project

Project/Area Number 11228204
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionOsaka University

Principal Investigator

FUKUZUMI Shunichi  Osaka University, Graduate School of Engineering, Professor, 大学院・工学研究科, 教授 (40144430)

Co-Investigator(Kenkyū-buntansha) MORO-OKA Yoshihiko  Tokiwa University, Faculty of Community Development, Professor, コミュニティー振興学部, 教授 (70016731)
Project Period (FY) 1999 – 2003
Project Status Completed (Fiscal Year 2003)
Budget Amount *help
¥10,000,000 (Direct Cost: ¥10,000,000)
Fiscal Year 2003: ¥1,500,000 (Direct Cost: ¥1,500,000)
Fiscal Year 2002: ¥2,200,000 (Direct Cost: ¥2,200,000)
Fiscal Year 2001: ¥2,200,000 (Direct Cost: ¥2,200,000)
Fiscal Year 2000: ¥2,000,000 (Direct Cost: ¥2,000,000)
Fiscal Year 1999: ¥2,100,000 (Direct Cost: ¥2,100,000)
KeywordsActive Oxygen Complexes / Electron Transfer / SOD / Monooxygenase / Cytochrome / X-ray Crystal Structure / Metalloproteins / Hemerythrin / Oxygenation / 触媒化学 / 物質・エネルギー変換 / 反応制御法 / エネルギー問題 / 地球環境
Research Abstract

The structures and reactivities of a variety of active oxygen-metal complexes have been revealed in relation with enzymatic oxidation reaction. A large number of information about metal-dioxygen reactivity has been accumulated, providing profound insight into the mechanism of O_2-binding and activation at metal reaction sites involved in many biological systems as well as in a variety of catalytic oxidation processes. In particular, reversible dioxygen binding (functional model of hemocyanim) has been accomplished using a series of dinucleating ligands. The present research project has provided valuable insight into the mechanisms of the four-electron reduction of oxygen as well as the four-electron oxidation of water. The initial objectives of the present research project have been well accomplished by the intensive cooperative research activities among seven research groups. The final results are summarized in the international symposium on the active oxygen-metal complexes held in january 2004, when the future prospect of the field of active oxygen-metal complexes has been discussed

Report

(7 results)
  • 2003 Annual Research Report   Final Research Report Summary
  • 2002 Annual Research Report
  • 2001 Annual Research Report
  • 2000 Annual Research Report   Final Research Report Summary
  • 1999 Annual Research Report
  • Research Products

    (275 results)

All Other

All Publications (275 results)

  • [Publications] Fukuzumi, S. et al.: "Catalytic Effects of Dioxygen on Intramolecular Electron Transfer in Radical Ion Pairs of Zinc Porphyrin-Linked Fullerenes"Journal of the American Chemical Society. 123(11). 2571-2575 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Fukuzumi, S. et al.: "Change in Spin State and Enhancement of Redox Reactivity of Photoexcited States of Aromatic Carbonyl Compounds by Complexation with Metal Ion Salts Acting as Lewis Acids. LewisAcid-Catalyzed Photoaddition of Benzyltrimethylsilane and Tetramethyltin via Photoinduced Electron Transfer"Journal of the American Chemical Society. 123(32). 7756-7766 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Fukuzumi, S. et al.: "Scandium Ion-Promoted Photoinduced Electron-Transfer Oxidation of Fullerenes and Derivatives by p-Chloranil and p-Benzoquinone"Journal of the American Chemical Society. 123(50). 12458-12465 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Fukuzumi, S. et al.: "Metal Ion-Catalyzed Cycloaddition vs Hydride Transfer Reactions of NADH Analogues with p-Benzoquinones"Journal of the American Chemical Society. 123(42). 10191-10199 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Fukuzumi, S. et al.: "Fluorescence Maxima of 10-Methylacridone-Metal Ion Salt Complexes : A Convenient and Quantitative Mean of Lewis Acidity of Metal Ion Salts"Journal of the American Chemical Society. 124(35). 10270-10271 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Fukuzumi, S. et al.: "Metal Ion-Catalyzed Diets-Alder and Hydride Transfer Reactions. Catalysis of Metal Ions in the Electron Transfer Step"Journal of the American Chemical Society. 124(47). 14147-14155 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Fukuzumi, S. et al.: "Hydrogen-Bonding Dynamics in Photoinduced Electron Transfer in a Ferrocene-Quinone Linked Dyad with a Rigid Amide Spacer"Journal of the American Chemical Society. 124(24). 6794-6795 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Fukuzumi, S. et al.: "Highly Self-Organized Electron, Transfer from an Iridium Complex to p-Benzoquinone Due to Formation of a p-Dimer Radical Anion Complex Triply Bridged by Scandium Ions"Journal of the American Chemical Society. 125(40). 12090-12091 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Fukuzumi, S. et al.: "Selective Oxygenation of Ring-Substituted Toluenes with Electron-Donating and -Withdrawing Substituents by Molecular Oxygen via Photoinduced Electron Transfer"Journal of the American Chemical Society. 125(42). 12850-12859 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Fukuzumi, S. et al.: "Mechanisms of Hydrogen-, Oxygen-, and Electron-Transfer Reactions of Cumylperoxyl Radical"Journal of the American Chemical Society. 125(30). 9074-9082 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Fukuzumi, S. et al.: "Metal Ion-Catalyzed Diels-Alder and Hydride Transfer Reactions. Catalysis of Metal Ions in the Election-Transfer Step"Journal of the American Chemical Society. 124(42). 12566-12573 (2002)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Fukuzumi, S. et al.: "Metal Ion-Promoted intramolecular Electron Transfer in Ferrocene Naphthoquinone Linked Dyad Continuous Change in Driving Force and Reorganization Energy with Metal ion Concentration"Journal of the American Chemical Society. 125(23). 7014-7021 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Fukuzumi, S. et al.: "Fullerenes-Volume 13: Fullerenes and Nanotubes"Electrochemical Society. 27 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Fukuzumi, S. et al.: "Molecular and Supramolecular Photochemistry"Marcel dekker Inc.. 47 (2003)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Fukuzumi, S.: "Catalytic Effects of Dioxygen on Intramolecular Electron Transfer in Radical Ion Pairs of Zinc Porphyrin-Linked Fullerenes"J. Am. Chem. Soc.. 123(11). 2571-2575 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Fukuzumi, S.: "Change in Spin State and Enhancement of Redox Reactivity of Photoexcited States of Aromatic Carbonyl Compounds by Complexation with Metal Ion Salts Acting as Lewis Acids. LewisAcid-Catalyzed Photoaddition of Benzyltrimethylsilane and Tetramethyltin via Photoinduced Electron Transfer"J. Am. Chem. Soc.. 123(32). 7756-7766 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Fukuzumi, S.: "Scandium Ion-Promoted Photoinduced Electron-Transfer Oxidation of Fullerenes and Derivatives by p-Chloranil and p-Benzoquinone"J. Am. Chem. Soc.. 123(50). 12458-12465 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Fukuzumi, S.: "Metal Ion-Catalyzed Cycloaddition vs Hydride Transfer Reactions of NADH Analogues with p-Benzoquinones"J. Am. Chem. Soc.. 123(42). 10191-10199 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Fukuzumi, S.: "Fluorescence Maxima of 10-Methylacridone-Metal Ion Salt Complexes : A Convenient and Quantitative Measure of Lewis Acidity of Metal Ion Salts"J. Am. Chem. Soc.. 124(35). 10270-10271 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Fukuzumi, S.: "Metal Ion-Catalyzed Diels-Alder and Hydride Transfer Reactions. Catalysis of Metal Ions in the Electron Transfer Step"J. Am. Chem. Soc.. 124(47). 14147-14155 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Fukuzumi, S.: "Hydrogen-Bonding Dynamics in Photoinduced Electron Transfer in a Ferrocene-Quinone Linked Dyad with a Rigid Amide Spacer"J. Am. Chem. Soc.. 124(24). 6794-6795 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Fukuzumi, S.: "Highly Self-Organized Electron Transfer from an Iridium Complex to p-Benzoquinone Due to Formation of a p-Dimer Radical Anion Complex Triply Bridged by Scandium Ions"J. Am. Chem. Soc.. 125(40). 12090-12091 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Fukuzumi, S.: "Selective Oxygenation of Ring-Substituted Toluenes with Electron-Donating and-Withdrawing Substituents by Molecular Oxygen via Photoinduced Electron Transfer"J. Am. Chem. Soc.. 125(42). 12850-12859 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Fukuzumi, S.: "Mechanisms of Hydrogen-, Oxygen-, and Electron-TransferReactions of Cumylperoxyl Radical"J. Am. Chem. Soc.. 125(30). 9074-9082 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Fukuzumi, S.: "Metal Ion-Catalyzed Diels-Alder and Hydride Transfer Reactions. Catalysis of Metal Ions in the Electron-Transfer Step"J. Am. Chem. Soc.. 124(42). 12566-12573 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Fukuzumi, S.: "Metal Ion-Promoted Intramolecular Electron Transfer in Ferrocene-Naphthoquinone Linked Dyad. Continuous Changein Driving Force and Reorganization Energy with Metal Ion Concentration"J. Am. Chem. Soc.. 125(23). 7014-7021 (2003)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2003 Final Research Report Summary
  • [Publications] Fukuzumi, S.et al.: "pH-Dependent Chemoselective Synthesis of -Amino Acids. Reductive Amination of -Keto Acids with Ammonia Catalyzed by Acid-Stable Iridium Hydride Complexes in Water"Journal of the American Chemical Society. (In press). (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] Fukuzumi, S.et al.: "A Dramatic Elongation of the Lifetime of Charge-Separated State by Complexation with Yttrium Triflate in Ferrocene-Anthraquinorie Linked Dyad"Journal of the American Chemical Society. 126・1. 56-57 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] Fukuzumi, S.et al.: "Electron-Transfer State of 9-Mesityl-10-methylacridinium Ion with a Much Longer Lifetime and Higher Energy Than That of the Natural Photosynthetic Reaction Center"Journal of the American Chemical Society. 126・6. 1600-1601 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] Fukuzumi, S.et al.: "Highly Self-Organized Electron Transfer from an Iridium Complex to p-Benzoquinone Due to Formation of a p-Dimer Radical Anion Complex Triply Bridged by Scandium Ions"Journal of the American Chemical Society. 125・40. 12090-12091 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Fukuzumi, S.et al.: "Photovoltaic Properties of Self-Assembled Monolayers of Porphyrins and Porphyrin-Fullerene Dyads on ITO and Gold Surfaces"Journal of the American Chemical Society. 125・30. 9129-9139 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Fukuzumi, S.et al.: "Oxidation Mechanism of Phenols by Dicopper-Dioxygen (Cu2/O2) Complexes"Journal of the American Chemical Society. 125・36. 11027-11033 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] Fukuzumi, S.et al.: "Self-Promoted Electron Transfer from Cobalt(II) Porphyrin to p-Fluoranil To Produce a Dimer Radical Anion-Cobalt(III) Porphyrin Complex"Journal of the American Chemical Society. 125・41. 12416-12417 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Fukuzumi, S.et al.: "Selective Oxygenation of Ring-Substituted Toluenes with Electron-Donating and - Withdrawing Substituents by Molecular Oxygen via Photoinduced Electron Transfer"Journal of the American Chemical Society. 125・42. 12850-12859 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Fukuzumi, S.et al.: "Role of Electron-Transfer Processes in Reactions of Diarylcarbenium Ions and Related Quinone Methides with Nucleophiles"Journal of the American Chemical Society. 125・36. 10906-10912 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Fukuzumi, S.et al.: "Rational Design Principle for Modulating Fluorescence Properties of Fluorescein-Based Probes by Photoinduced Electron Transfer"Journal of the American Chemical Society. 125・28. 8666-8671 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Fukuzumi, S.et al.: "Accelerating Effect of a Proton on the Reduction of CO_2 Dissolved in Water under Acidic Conditions. Isolation, Crystal Structure, and Reducing Ability of a Water-Soluble Ruthenium Hydride Complex"Journal of the American Chemical Society. 125・47. 14266-14267 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Fukuzumi, S.et al.: "Quaternary Self-Organization of Porphyrin and Fullerene Units by Clusterization with Gold Nanoparticles on SnO_2 Electrodes for Organic Solar Cells"Journal of the American Chemical Society. 125・49. 14962-14963 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Fukuzumi, S.et al.: "Effects of hydrogen bonding on metal ion-promoted intramolecular electron transfer and photoinduced electron transfer in a ferrocene-quinone dyad with a rigid amide spacer"Journal of the American Chemical Society. 125・4. 1007-1013 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Fukuzumi, S.et al.: "Mechanisms of Electron-Transfer Oxidation of NADH Analogues and Chemiluminescence. Detection of the Keto and Enol Radical Cations"Journal of the American Chemical Society. 125・16. 4808-4816 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Fukuzumi, S.et al.: "Mechanisms of Hydrogen-, Oxygen-, and Electron-Transfer Reactions of Cumylperoxyl Radical"Journal of the American Chemical Society. 125・30. 9074-9082 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Fukuzumi, S.et al.: "Metal-Centered Photoinduced Electron Transfer Reduction of a Gold(III) Porphyrin Cation Linked with a Zinc Porphyrin to Produce a Long-Lived Charge-Separated State in Nonpolar Solvents"Journal of the American Chemical Society. 125・49. 14984-14985 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Fukuzumi, S.et al.: "Isolation and Crystal Structure of a Water-Soluble Iridium Hydride : A Robust and Highly Active Catalyst for Acid-Catalyzed Transfer Hydrogenations of Carbonyl Compounds in Acidic Media"Journal of the American Chemical Society. 125・14. 4149-4154 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Fukuzumi, S.et al.: "Metal Ion-Promoted Intramolecular Electron Transfer in a Ferrocene-Naphthoqujnone Linked Dyad. Continuous Change in Driving Force and Reorganization Energy with Metal Ion Concentration"Journal of the American Chemical Society. 125・23. 7014-7021 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Fukuzumi, S.et al.: "Excited-state deprotonation and H/D exchange of an iridium hydride complex"Angewandte Chemie, International Edition. 42・44. 5492-5495 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Fukuzumi, S.et al.: "A ruthenium pterin complex showing proton-coupled electron transfer : synthesis and characterization"Angewandte Chemie, International Edition. 42・40. 4951-4954 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Fukuzumi, S.et al.: "A Molecular Tetrad Allowing Efficient Energy Storage for 1.6s at 163K"Journal of Physical Chemistry A. 108・4. 541-548 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] Fukuzumi, S.et al.: "Ultrafast Photodynamics of Exciplex Formation and Photoinduced Electron Transfer in Porphyrin-Fullerene Dyads Linked at Close Proximity"Journal of Physical Chemistry A. 107・42. 8834-8844 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Fukuzumi, S.et al.: "Formation of a Supramolecular Porphyrin-Spacer-Acceptor Ternary Complex and Intracomplex Electron Transfer"Journal of Physical Chemistry A. 107・3. 379-385 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Fukuzumi, S.et al.: "Strong Inhibition of Singlet Oxygen Sensitization in Pyridylferrocene-Fluorinated Zinc Porphyrin Supramolecular Complexes"Journal of Physical Chemistry A. 107・29. 5515-5522 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Fukuzumi, S.et al.: "Light Energy Conversion Using Mixed Molecular Nanoclusters. Porphyrin and C_<60> Cluster Films for Efficient Photocurrent Generation"Journal of Physical Chemistry B. 107・44. 12105-12112 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Fukuzumi, S.et al.: "Diels-Alder Reactions of Anthracenes with Dienophiles via Photoinduced Electron Transfer"Journal of Physical Chemistry A. 107・28. 5412-5418 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Fukuzumi, S.et al.: "Driving Force Dependence of Photoinduced Electron Transfer Dynamics of Intercalated Molecules in DNA"Journal of Physical Chemistry B. 107・45. 12511-12518 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Fukuzumi, S.et al.: "Novel Photocatalytic Function of Porphyrin-Modified Gold Nanoclusters in Comparison with the Reference Porphyrin Compound"Journal of Physical Chemistry B. 107・43. 11979-11986 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Fukuzumi, S.et al.: "Oxygenation of a-Methylstyrene with Molecular Oxygen, Catalyzed by 10-Methylacridinium Ion via Photoinduced Electron Transfer"Journal of Physical Chemistry A. 107・22. 4339-4346 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Fukuzumi, S: "Catalytic control of electron-transfer processes"Pure and Applied Chemistry. 75・5. 577-587 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Fukuzumi, S.et al.: "Seconds Lasting Charge-Separated State Generated in Ferrocene-meso, meso-Linked Porphyrin Trimer-Fullerene Pentad with a High Quantum Yield"Chemistry--A European Journal. (In press). (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] Fukuzumi, S.et al.: "Effects of metal ions on photoinduced electron transfer in zinc porphyrin-naphthalenediimide linked systems"Chemistry-A European Journal. 10・2. 474-483 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] Fukuzumi, S.et al.: "Quantitative evaluation of d-p interaction in copper(I) complexes and control of copper(I)-dioxygen reactivity"Chemistry-A European Journal. 10・1. 237-246 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] Fukuzumi, S.et al.: "Driving force dependence of intermolecular electron-transfer reactions of fullerenes"Chemistry--A European Journal. 9・7. 1585-1593 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Fukuzumi, S.et al.: "Reversed effects of DNA on hydride transfer and electron transfer reactions of acridinium and quinolinium ions"Chemical Communications. 15. 1886-1887 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Fukuzumi, S.et al.: "Remarkable effects of counter ions on scandium ion-promoted electron transfer reactions"Chemical Communications. 9. 1070-1071 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Fukuzumi, S.et al.: "Enhancement of light harvesting and photocurrent generation by ITO electrodes modified with meso, meso-linked porphyrin oligomers"Nano Letters. 3・3. 409-412 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Fukuzumi, S.et al.: "Long-Lived Charge-Separated State Produced by Photoinduced Electron Transfer in a Zinc Imidazoporphyrin-C_<60> Dyad"Organic Letters. 5・15. 2719-2721 (2003)

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      2003 Annual Research Report
  • [Publications] Fukuzumi, S.et al.: "Structure and Photophysical Properties of Porphyrin-Modified Metal Nanoclusters with Different Chain Lengths"Langmuir. 20・1. 73-81 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] Fukuzumi, S.et al.: "Substituent Effects on the Site of Electron Transfer during the First Reduction for Gold(III) Porphyrins"Inorganic.Chemistry. (In press). (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] Fukuzumi, S.: "New perspective of electron transfer chemistry"Organic & Biomolecular Chemistry. 1・4. 609-620 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Fukuzumi, S.et al.: "Fast self-exchange electron transfer and delocalization of unpaired electron between zinc porphyrin radical cations and zinc porphyrins"Journal of Porphyrins and Phthalocyanines. 7・4&5. 328-336 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Fukuzumi, S.et al.: "A Planar Catechin Analogue as a Promising Antioxidant with Reduced Prooxidant Activity"Chemical Research in Toxicology. 16・1. 81-86 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Fukuzumi, S.et al.: "π-Complex Formation in Electron-Transfer Reactions of Porphyrins"Journal of Porphyrins and Phthalocyanines. (In press).

    • Related Report
      2003 Annual Research Report
  • [Publications] Fukuzumi, S.et al.: "Porphyrin and Fullerene-Based Molecular Photovoltaics"Advanced Functional Materials. (In press).

    • Related Report
      2003 Annual Research Report
  • [Publications] Fukuzumi, S.et al.: "Supramolecular Photovoltaic Cells of Porphyrin Dendrimers and Fullerene"Advanced Materials. (In press).

    • Related Report
      2003 Annual Research Report
  • [Publications] Fukuzumi, S.et al.: "Kinetic study of the electron-transfer oxidation of the phenolate anion of a vitamin E model by molecular oxygen generating superoxide anion in an aprotic medium"Organic & Biomolecular Chemistry. 1・22. 4085-4088 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Fukuzumi, S.et al.: "Nanostructured assembly of porphyrin clusters for light energy conversion"Journal of Materials Chemistry. 13・10. 2515-2520 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Fukuzumi, S.et al.: "Thermochromism of the disproportionation equilibrium of -dimer radical anion complexes bridged by scandium ions"Organic & Biomolecular Chemistry. 2・5. 642-644 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] Fukuzumi, S.et al.: "A Planar Catechin Analogue Having a More Negative Oxidation Potential than (+)-Catechin as an Electron Transfer Antioxidant against a Peroxyl Radical"Chemical Research in Toxicology. 17・1. 26-31 (2004)

    • Related Report
      2003 Annual Research Report
  • [Publications] Fukuzumi, S.et al.: "Layer-by-layer assembly of porphyrin-fullerene dyads"Journal of Porphyrins and Phthalocyanines. 7・4&5. 357-364 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Fukuzumi, S.et al.: "Molecular Engineering of Myoglobin : Influence of Residue 68 on the Rate and the Enantioselectivity of Oxidation Reactions Catalyzed by H64D/V68X Myoglobin"Biochemistry. 42・34. 10174-10181 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Fukuzumi, S.et al.: "Fluorinated photosensitizers : synthesis, photophysical, electrochemical, intracellular localization, in vitro photosensitizing efficacy and determination of tumor-uptake by 19F in vivo NMR spectroscopy"Tetrahedron. 59・50. 10059-10073 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Fukuzumi, S.et al.: "Synthesis and Structural, Electrochemical, and Optical Properties of Ru(II) Complexes with Azobis(2,2'-bipyridine)s"Inorganic Chemistry. 42・9. 3057-3066 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Fukuzumi, S.et al.: "Quantitative Evaluation of Lewis Acidity of Metal Ions with Different Ligands and Counterions in Relation to the Promoting Effects of Lewis Acids on Electron Transfer Reduction of Oxygen"Journal of Organic Chemistry. 68・12. 4720-4726 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Fukuzumi, S.et al.: "Efficient radical scavenging ability of artepillin C, a major component of Brazilian propolis, and the mechanism"Organic & Biomolecular Chemistry. 1・9. 1452-1454 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Fukuzumi, S.et al.: "Kinetic study of the electron-transfer oxidation of the phenolate anion of a vitamin E model by molecular oxygen generating superoxide anion in an aprotic medium"Organic & Biomolecular Chemistry. 1・22. 4085-4088 (2003)

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      2003 Annual Research Report
  • [Publications] Fukuzumi, S.et al.: "C_<70> vs. C_<60> in zinc porphyrin-fullerene dyads : Prolonged charge separation and ultrafast energy transfer from the second excited singlet state of porphyrin"Photochemical & Photobiological Sciences. 2・3. 251-258 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Fukuzumi, S.et al.: "Metal and size effects on structures and photophysical properties of porphyrin-modified metal nanoclusters"Journal of Materials Chemistry. 13・12. 2890-2898 (2003)

    • Related Report
      2003 Annual Research Report
  • [Publications] Fukuzumi, S.et al.: "Structure and photoelectrochemical properties of ITO electrodes modified with self-assembled monolayers of meso, meso-linked porphyrin oligomers"Journal of Porphyrins and Phthalocyanines. 7・4&5. 296-312 (2003)

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  • [Publications] Fukuzumi, S.et al.: "Fullerenes--Volume 13:Fullerenes and Nanotubes"Electrochemical Society. 27 (2003)

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  • [Publications] Fukuzumi, S.: "Sentan Kagaku Shirizu"丸善(株). 10 (2003)

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      2003 Annual Research Report
  • [Publications] Fukuzumi, S.: "Molecular and Supramolecular Photochemistry"Marcel dekker Inc.. 47 (2003)

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      2003 Annual Research Report
  • [Publications] Fukuzumi, S.: "Tanpakushitsu Kakusan Koso 48 (11, Zokango)"共立出版(株). 7 (2003)

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  • [Publications] Fukuzumi, S.: "Gendai Kagaku 393"(株)東京化学同人. 6 (2003)

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  • [Publications] Fukuzumi, S. et al.: "Effects of Hydrogen Bonding on Metal Ion-Promoted Intramolecular Electron Transfer and Photoinduced Electron Transfer in a Ferrocene-Quinone Dyad with a Rigid Amide Spacer"Journal of the American Chemical Society. 125・4. 1007-1013 (2003)

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      2002 Annual Research Report
  • [Publications] Ogo, S.et al.: "Isolation and Crystal Structure of Water-Soluble Iridium Hydride. Robust and Highly Active Catalyst for Acid-Catalyzed Transfer Hydrogenations of Carbonyl Compounds in Acidic Media"Journal of the American Chemical Society. 125(in press). (2003)

    • Related Report
      2002 Annual Research Report
  • [Publications] Fukuzumi, S. et al.: "Scandium Ion-Promoted Reduction of Heterocyclic N : N Double Bond. Hydride Transfer vs Electron Transfer"Journal of the American Chemical Society. 124・42. 12566-12573 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] Fukuzumi, S. et al.: "Direct detection of radical cations of NADH analogues"Journal of the American Chemical Society. 124・49. 14538-14539 (2002)

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      2002 Annual Research Report
  • [Publications] Fukuzumi, S. et al.: "Metal Ion-Catalyzed Diels-Alder and Hydride Transfer Reactions. Catalysis of Metal Ions in the Electron-Transfer Step"Journal of the American Chemical Society. 124・47. 14147-14155 (2002)

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      2002 Annual Research Report
  • [Publications] Fukuzumi, S. et al.: "A Negative Temperature Dependence of the Electron Self-Exchange Rates of Zinc Porphyrin π Radical Cations"Journal of the American Chemical Society. 124・37. 10974-10975 (2002)

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      2002 Annual Research Report
  • [Publications] Fukuzumi, S. et al.: "Fluorescence Maxima of 1O-Methylacridone-Metal Ion Salt Complexes : A Convenient and Quantitative Measure of Lewis Acidity of Metal Ion Salts"Journal of the American Chemical Society. 124・35. 10270-10271 (2002)

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      2002 Annual Research Report
  • [Publications] Fukuzumi, S. et al.: "Asymmetric Sulfoxidation and Amine Binding by H64D/V68A and H64D/V68S Mb : Mechanistic Insight into the Chiral Discrimination Step"Journal of the American Chemical Society. 124・29. 8506-8507 (2003)

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      2002 Annual Research Report
  • [Publications] Fukuzumi, S. et al.: "Significant Enhancement of Electron Transfer Reduction of NAD+ Analogues by Complexation with Scandium Ion and the Detection of the Radical Intermediate-Scandium Ion complex"Journal of the American Chemical Society. 124・31. 9181-9188 (2002)

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      2002 Annual Research Report
  • [Publications] Fukuzumi, S. et al.: "Exciplex intermediates in photoinduced electron transfer of porphyrin-fullerene dyads"Journal of the American Chemical Society. 124・27. 8067-8077 (2002)

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      2002 Annual Research Report
  • [Publications] Fukuzumi, S. et al.: "Hydrogen-bonding dynamics in photoinduced electron transfer in a ferrocene-quinone linked dyad with a rigid amide spacer"Journal of the American Chemical Society. 124・24. 6794-6795 (2002)

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      2002 Annual Research Report
  • [Publications] Fukuzumi, S. et al.: "Fine-Tuning of Copper(I)-Dioxygen Reactivity by 2-(2-Pyridyl)ethylamine Bidentate Ligands"Journal of the American Chemical Society. 124・22. 6367-6377 (2002)

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      2002 Annual Research Report
  • [Publications] Fukuzumi, S. et al.: "Stepwise charge separation and charge recombination in ferrocene-meso, meso-linked porphyrin dimer-fullerene triad"Journal of the American Chemical Society. 124・18. 5165-5174 (2002)

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      2002 Annual Research Report
  • [Publications] Fukuzumi, S. et al.: "Oxo-Transfer Reaction from a Bis(μ-oxo) dicopper(III) Complex to Sulfides"Journal of the American Chemical Society. 124・6. 998-1002 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] Fukuzumi, S. et al.: "Large Photocurrent Generation of Gold Electrodes Modified with [60] Fullerene-Linked Oligothiophenes Bearing a Tripodal Rigid Anchor"Journal of the American Chemical Society. 124・4. 532-533 (2002)

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      2002 Annual Research Report
  • [Publications] Fukuzumi, S. et al.: "Comparison of reorganization energies for intra-and intermolecular electron transfer"Angewandte Chemie, International Edition. 41・13. 2344-2347 (2002)

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      2002 Annual Research Report
  • [Publications] Fukuzumi, S. et al.: "Thermal intramolecular electron transfer in a ferrocene-naphthoquinone linked dyad promoted by metal ions"Angewandte Chemie, International Edition. 41・4. 620-622 (2002)

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      2002 Annual Research Report
  • [Publications] Fukuzumi, S. et al.: "Mechanisms of Electron Transfer Oxidation of NADH Analogs and the Chemiluminescence. Detection of the Keto and Enol Radical Cations"Journal of the American Chemical Society. 125(in press). (2003)

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  • [Publications] Fukuzumi, S. et al.: "Activation of electron transfer reduction of p-benzoquinone derivatives by intermolecular regioselective hydrogen bond formation"Chemical Communications (Cambridge, United Kingdom). 17. 1984-1985 (2002)

    • Related Report
      2002 Annual Research Report
  • [Publications] Fukuzumi, S. et al.: "Evidence that gold(III) porphyrins are not electrochemically inert : facile generation of gold(II) 5,10,15,20-tetrakis(3,5-di-tert-butylphenyl) porphyrin"Chemical Communications (Cambridge, United Kingdom). 4. 356-357 (2002)

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  • [Publications] Fukuzumi, S. et al.: "Driving Force Dependence of Intermolecular Electron Transfer Reactions of Fullerenes"Chemistry A European Journal. 9(in press). (2003)

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  • [Publications] Fukuzumi, S. et al.: "Formation of a Supramolecular Porphyrin-Spacer-Acceptor Ternary Complex and Intracomplex Electron Transfer"Journal of Physical Chemistry A. 107・3. 379-385 (2003)

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  • [Publications] Fukuzumi, S. et al.: "Small Reorganization Energy of Intramolecular Electron Transfer in Fullerene-Based Dyads with Short Linkage"Journal of Physical Chemistry A. 106・46. 10991-10998 (2002)

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  • [Publications] Fukuzumi, S. et al.: "Effects of Metal Ions Distinguishing between One-Step Hydrogen-and Electron-Transfer Mechanisms for the Radical-Scavenging Reaction of (+)-Catechin"Journal of Physical Chemistry A. 106・46. 11123-11126 (2002)

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  • [Publications] Fukuzumi, S. et al.: "Photophysical and Electrochemical Properties of New Bacteriochlorins and Characterization of Radical Cation and Radical Anion Species"Journal of Physical Chemistry A. 106・20. 5105-5113 (2002)

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  • [Publications] Fukuzumi, S. et al.: "Linkage dependent charge separation and charge recombination in porphyrin-pyromellitimide-fullerene triads"Journal of Physical Chemistry A. 106・12. 2803-2814 (2002)

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  • [Publications] Fukuzumi, S. et al.: "Electron transfer properties of singlet oxygen and promoting effects of scandium ion"Journal of Physical Chemistry A. 106・7. 1241-1247 (2002)

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      2002 Annual Research Report
  • [Publications] Fukuzumi, S. et al.: "Dehydrogenation vs. Oxygenation in Rhotosensitized Oxidation of 9-Substituted 1O-Methyl-9,10-dihydroacridine in the Presence of Scandium Ion"Journal of Physical Chemistry A. 106・7. 1465-1472 (2002)

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      2002 Annual Research Report
  • [Publications] Fukuzumi, S. et al.: "Uphill photooxidation of NADH analogues by hexyl viologen catalyzed by zinc porphyrin-linked fullerenes"Journal of Physical Chemistry A. 106・10. 1903-1908 (2002)

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      2002 Annual Research Report
  • [Publications] Fukuzumi, S. et al.: "DNA Cleavage via Superoxide Anion Formed in Photoinduced Electron Transfer from NADH to γ-Cyclodextrin-Bicapped C_<60> in an Oxygen-Saturated Aqueous Solution"Journal of Physical Chemistry B. 106・9. 2372-2380 (2002)

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  • [Publications] Ogo, S.et al.: "Structural and Spectroscopic Features of a cis (Hydroxo)-Fe^<III>-(Carboxylato) Configuration as an Active Site Model for Lipoxygenases"Inorganic Chemistry. 41・21. 5513-5520 (2002)

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  • [Publications] Fukuzumi, S. et al.: "Enhancement of photocurrent generation by ITO electrodes modified chemically with self-assembled monolayers of porphyrin-fullerene dyads"Advanced Materials (Weinheim, Germany). 14・12. 892-895 (2002)

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  • [Publications] Fukuzumi, S. et al.: "A key role for old yellow enzyme in the metabolism of drugs by Trypanosoma cruzi"Journal of Experimental Medicine. 196・9. 1241-1251 (2002)

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  • [Publications] Fukuzumi, S. et al.: "A Planar Catechin Analogue as a Promising Antioxidant with Reduced Prooxidant Activity"Chemical Research in Toxicology. 16・1. 81-86 (2003)

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      2002 Annual Research Report
  • [Publications] Fukuzumi, S. et al.: "Acceleration and deceleration of photoinduced electron transfer rates by an electric field in porphyrin-fullerene dyads"Chemical Physics Letters. 368・1, 2. 230-235 (2002)

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  • [Publications] Fukuzumi, S. et al.: "Porphyrin-fullerene dyad with a long linker : formation of charge transfer conformer in Langmuir-Blodgett film"Chemical Physics Letters. 366・3, 4. 245-252 (2002)

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  • [Publications] Fukuzumi, S. et al.: "Dioxygen activation by copper complexes. Mechanistic insights into copper monooxygenases and copper oxidases"Bulletin of the Chemical Society of Japan. 75・10. 2081-2095 (2002)

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  • [Publications] Fukuzumi, S. et al.: "Formation of superoxide-metal ion complexes and the electron transfer catalysis"Coordination Chemistry Reviews. 226・1-2. 71-80 (2002)

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  • [Publications] Fukuzumi, S. et al.: "Direct detection of superoxide anion generated in C_<60>-photosensitized oxidation of NADH and an analogue by molecular oxygen"Journal of the Chemical Society, Perkin Transactions 2. 11. 1829-1833 (2002)

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      2002 Annual Research Report
  • [Publications] Fukuzumi, S. et al.: "Effects of magnesium ion on kinetic stability and spin distribution of phenoxyl radical derived from a vitamin E analogue : mechanistic insight into antioxidative hydrogen-transfer reaction of vitamin E"Journal of the Chemical Society, Perkin Transactions 2. 9. 1520-1524 (2002)

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  • [Publications] Fukuzumi, S. et al.: "Catalysis in electron transfer reactions : Facts and mechanistic insights"Journal of Physical Organic Chemistry. 15・8. 448-460 (2002)

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      2002 Annual Research Report
  • [Publications] Fukuzumi, S. et al.: "Photocurrent generation using gold electrodes modified with self-assembled monolayers of a fullerene-porphyrin dyad"Journal of Materials Chemistry. 12・7. 2034-2040 (2002)

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      2002 Annual Research Report
  • [Publications] Fukuzumi, S. et al.: "Enhancement of Light-Harvesting and Photocurrent Generation by ITO Electrodes Modified with meso, meso-Linked Porphyrin Oligomers"Nano Letters. 3(in press). (2003)

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      2002 Annual Research Report
  • [Publications] Fukuzumi, S. et al.: "Electron transfer reduction of a highly electron-deficient fullerene, C_<60>F_<18>"Chemical Communications (Cambridge, United Kingdom). 17. 1952-1953 (2002)

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  • [Publications] Fukuzumi, S. et al.: "Electron transfer in electron donor-acceptor ensembles containing porphyrins and metalloporphyrins"Journal of Porphyrins and Phthalocyanines. 6・4. 289-295 (2002)

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  • [Publications] Fukuzumi, S. et al.: "Electron Transfer Mechanism in Radical-Scavenging Reactions of Flavonoids"Free Radical Biol. Med.. 33. S308-S309 (2002)

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      2002 Annual Research Report
  • [Publications] Fukuzumi, S. et al.: "Conducting molecular materials and electrochemistry. 1. Photoelectron transfer at electrodes modified with fullerene derivatives"Electrochemistry (Tokyo, Japan). 70・4. 274-278 (2002)

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  • [Publications] Fukuzumi, S. et al.: "Clean energy from inexhaustible solar light"Gendai Kagaku. 375. 46-50 (2002)

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  • [Publications] Fukuzumi, S. et al.: "Nanoscale artificial photosynthesis system using porphyrins and fullerenes"Kagaku Furontia (Bunshi Nanotekunoroji). 6. 115-125 (2003)

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      2002 Annual Research Report
  • [Publications] Fukuzumi, S. et al.: "Catalytic Control of Electron Transfer Processes"Pure Appl. Chem.. (in press). (2003)

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      2002 Annual Research Report
  • [Publications] Fukuzumi, S. et al.: "C_<70> vs. C_<60> in zinc porphyrin-fullerene dyads : prolonged charge separation and ultrafast energy transfer from the second excited singlet state of porphyrin"Photochemical & Photobiological Sciences. (in press). (2003)

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      2002 Annual Research Report
  • [Publications] Fukuzumi, S.: "New Perspective of Electron Transfer Chemistry"Organic & Biomolecular Chemistry. (in press). (2003)

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      2002 Annual Research Report
  • [Publications] Fukuzumi, S. et al.: "Electron Transfer Properties of Bisphenol Derivatives in Relation with the Developing Properties in Silver Salt Photothermographic Systems"J. Imag. Sci. Tech.. 47(in press). (2003)

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      2002 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Fullerenes 2002--Volume 12. (Proceedings of the 201^<st> Meeting of the Electrochemical Society)"The Electrochemical Society, INC. 37 (2002)

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  • [Publications] Fukuzumi, S.et al.: "生産と技術"生産技術振興協会. 3 (2002)

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  • [Publications] Fukuzumi, S.et al.: "先端ウオッチングシリーズ「錯体化学」"日本化学会. 6 (2002)

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  • [Publications] Shunichi Fukuzumi et al.: "Fine Tuning of the Interaction between the Copper(I) and Disulfide Bond. Formation of a Bis(m-thiolato)dicopper(II) Complex by Reductive Cleavage of the Disulfide Bond with Copper(I)"J.Am.Chem.Soc.. 123・17. 4087-4088 (2001)

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      2001 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "C-H Bond Activation of External Substrates with a Bis(m-oxo)dicopper(III) Complex"J.Am.Chem.Soc.. 123・25. 6203-6204 (2001)

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      2001 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Charge Separation in a Novel Artificial Photosynthetic Reaction Center Lives 380ms"J.Am.Chem.Soc.. 123・27. 6617-6628 (2001)

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      2001 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Oxygenation of Phenols to Catechols by A (μ-η^2:η^2-peroxo)dicopper(II) Complex : Mechanistic Insight into the Phenolase Activity of Tyrosinase"J.Am.Chem.Soc.. 123・27. 6708-6709 (2001)

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      2001 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Change in Spin State and Enhancement of Redox Reactivity of Photoexcited States of Aromatic Carbonyl Compounds by Complexation with Metal Ion Salts Acting as Lewis Acids. Lewis Acid-Catalyzed Photoaddition of Benzyltrimethylsilane and Tetramethyltin via Photoinduced Electron Transfer"J.Am.Chem.Soc.. 123・32. 7756-7766 (2001)

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      2001 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Photoalkylation of 1O-Alkylacridinium Ion via a Charge-Shift Type of Photoinduced Electron Transfer Controlled by Solvent Polarity"J.Am.Chem.Soc.. 123・35. 8459-8467 (2001)

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      2001 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Metal Ion-Catalyzed Cycloaddition vs Hydride Transfer Reactions of NADH Analogues with p-Benzoquinones"J.Am.Chem.Soc.. 123・42. 10191-10199 (2001)

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      2001 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Photochemical and Electrochemical Properties of Zinc Chlorin-C_<60>, Dyad as Compared to Corresponding Free-Base Chlorin-C_<60>, Free-Base Porphyrin-C_<60> and Zinc Porphyrin-C_<60> Dyads"J.Am.Chem.Soc.. 123・43. 10676-10683 (2001)

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      2001 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Formation, Characterization, and Reactivity of Bis(μ-oxo)dinickel(III) Complexes Supported by A series of Bis[2-(2-pyridyl)ethyl]amine Ligands"J.Am.Chem.Soc.. 123・45. 11168-11178 (2001)

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  • [Publications] Shunichi Fukuzumi et al.: "Extremely Slow Long-Range Electron Transfer Reactions across Zeolite-Solution Interface"J.Am.Chem.Soc.. 123・45. 11331-11332 (2001)

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      2001 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Scandium Ion-Promoted Photoinduced Electron-Transfer Oxidation of Fullerenes and Derivatives by p-Chloranil and p-Benzoquinone"J.Am.Chem.Soc.. 123・50. 12458-12465 (2002)

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      2001 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Large Photocurrent Generation of Gold Eelectrodes Modified with [60]Fullerene-Linked Oligothiophenes Bearing a Tripodal Rigid Anchor"J.Am.Chem.Soc.. 124・4. 532-533 (2002)

    • Related Report
      2001 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "OXo-transfer Reaction from A Bis(μ-oxo)dicopper(III) Complex"J.Am.Chem.Soc.. 124・6. 998-1002 (2002)

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      2001 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Efficient Catalysis of Rare-Earth Metal Ions in Photoinduced Electron-Transfer Oxidation of Benzyl Alcohols by a Flavin Analogue"J.Phys.Chem.A. 105・46. 10501-10510 (2001)

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      2001 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Electron Transfer Properties of Singlet Oxygen and Promoting Effects of Scandium Ion"J.Phys.Chem.A. 106・7. 1241-1247 (2002)

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      2001 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Dehydrogenation vs Oxygenation in Photosensitized Oxidation of 9-Substituted 10-Methyl-9,10-dihydroacridine in the Presence of Scandium Ion"J.Phys.Chem.A. 106・7. 1465-1472 (2002)

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      2001 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Characterization of Imidazolate-Bridged Dinuclear and Mononuclear Hydroperoxo Complexes"Inorg.Chem.. 40・13. 3200-3207 (2001)

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      2001 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Modulation of Coordination Chemistry in Copper(I) Complexes Supported by Bis[2-(2-pyridyl)ethyl]amine-Based Tridentate Ligands"Inorg.Chem.. 40・26. 6604-6609 (2001)

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      2001 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Spectroscopy and Photocurrent Generation in Nanostructured Thin Films of Porphyrin-Fullerene Dyad Clusters"Chem.Lett. 784-785 (2001)

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  • [Publications] Shunichi Fukuzumi et al.: "Quantitative Evaluation of Lewis Acidity of Zinc Ion with Tetradentate Tripodal Ligands in Formation of the Superoxide Complexes"Chem.Lett. 920-921 (2001)

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      2001 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Evaluation of Lewis Acidity of Organotin Compounds and the Catalytic Reactivity in Electron Transfer"Chem.Lett. 978-979 (2001)

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      2001 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Superoxide Anion Generation via Electron-Transfer Oxidation of Catechin Dianion by Molecular Oxygen in an Aprotic Medium"Chem.Lett. 1152-1153 (2001)

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      2001 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Coordination of Semiquinone and Superoxide Radical Anions to the Zinc Ion in SOD Model Complexes that Act as the Key Step in Disproportionation of the Radical Anions"Chem.Eur.J.. 7・22. 4947-4953 (2001)

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  • [Publications] Shunichi Fukuzumi et al.: "Concentration Effects of Porphyrin Monolayers on the Structure and Photoelectrochemical Properties of Mixed Self-Assembled Monolayers of Porphyrin and Alkanethiol on Gold Electrodes"Langmuir. 17・16. 4925-4931 (2001)

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  • [Publications] Shunichi Fukuzumi et al.: "Porphyrin Monolayer-Modified Gold Clusters as Photoactive Materials"Adv.Mater. 13・15. 1197-1199 (2001)

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      2001 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Charge-transfer emission of compact porphyrin-fullerene dyad analyzed by Marcus theory of electron-transfer"Spectrochim.Acta Part A. 57. 2229-2244 (2001)

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      2001 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Evidence that gold(III) porphyrins are not electrochemically inert : facile generation of gold(II) 5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)porphyrin"Chem.Commun.. 356-357 (2002)

    • Related Report
      2001 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Thermal Intramolecular Electron Transfer in a Ferrocene-Naphthoquinone Linked Dyad Promoted by Metal Ion"Angew.Chem.Int.Ed.. 41・4. 620-622 (2002)

    • Related Report
      2001 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Fullerenes 2001--Volume 11. (Proceedings of the Eighth International Symposium of the 197th Meeting of The Electrochemical Society)"The Electrochemical Society, INC. 69 (2001)

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      2001 Annual Research Report
  • [Publications] Naruta,Y. et al.: "Synthesis and Characterization of Alkanethiolate-coordinated Iron Porphyrins and Their Dioxygen Adducts as Models for the Active Center of Cytochrome P-450"J.Am.Chem.Soc.. 123・6. 1133-1142 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Fukuzumi,S. et al.: "Catalytic Effects of Dioxygen on Intramolecular Electron Transfer in Radical Ion Pairs of Zine Porphyrin-Linked Fullerenes"J.Am.Chem.Soc.. 123・11. 2571-2575 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Fukuzumi,S.et al.: "Effects of Metal Ions on Physicochemical Properties and Redox Reactivity of Phenolates and Phenoxyl Radicals : Mechanistic Insight into Hydrogen Atom Abstraction by Fhenoxyl Padical-Retal Complexes"J.Am.Chem.Soc.. 123・10. 2165-2175 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Fukuzumi,S.et al.: "Modulating Charge Separation and Charge Recombination Dynamics in Porphyrin-Fullerene Linked Dyads and Triads : Marcus-Normal versus Inverted Region,"J.Am.Chem.Soc.. 123・11. 2607-2617 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Itoh,S.; Fukuzumi,S.et al.: "Fine Tuning of Interaction between Copper (I) and Disulfide Bond.Formation of a Bis (μ-thiolato) dicopper (II) Complex by Reductive Cleavage or Disulfide Bond with Copper (I),"J.Am.Chem.Soc.. 123・(in press). (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Naruta,Y.et al.: "Direct Binding of Hydroxylamine to the Heme Iron of Arthromyces ramousus Peroxidase"J.Biol.Chem.. 275・. 32919-32924 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Watanabe,Y. et al.: "Molecular Engineering of myoglobin : The Improvement of Oxidation Activity by Replacing Phe-1β with Tryplophan"Biochemistry. 40・4. 1044-1052 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Itoh,S.; Fukuzumi,S.et al.: "Effects of Metal Ions on the Electronic, Redox, and Catalytic Properties of Cofactor TTQ of Quinoprotein Amine Dehydrogenases"J.Am.Chem.Soc.. 122・49. 12087-12097 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Watanabe,Y.; Suzuki,M.; Moro-oka,Y.et al.: "Synthesis, Structures, and Properties of Bis (μ-oxo) nickel (III) and Bis (μ-superoxo) nickel (II) Complexes : An Unusual Conversion of a Ni (III) _2(μ-O)_2 Core into a Ni (II)_2(μ-OO)_2 Core by H_2O_2 and Oxygenation of Ligand"J.Am.Chem.Soc.. 122・2. 254-262 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Suzuki,M.; Watanabe,Y. et al.: "A Bis (μ-oxo) dicopper (III) Complex with Aromatic Nitrogen Donors : Structural Characterization and Reversible Conversion between Copper (I) and Bis (μ-oxo) dicopper (III) Species"J.Am.Chem.Soc.. 122・9. 2124-2125 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Shunichi Fukuzumi et al.: "Synthesis and Characterization of Imidazolate-Bridged Dinuclear Complexes as Active Site Models of Cu, Zn-SOD"J.Am.Chem.Soc.. 122・24. 5733-5741 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Itoh,S.; Fukuzumi,S.et al.: "Resonance Raman Spectroscopy as a Probe of the Bis(μ-oxo)dicopper Core"J.Am.Chem.Soc.. 122・5. 792-802 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Watanabe,Y. et al.: "Effects of the Location of Distal Histidine in the Reaction of Myoglobin with Hydrogen Peroxide"J.Biol.Chem.. 273・. 2838-2844 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Suzuki,M. et al.: "Crystal Structure and Reversible O_2-Binding of a Room Temperature Stable μ-η^2 : η^2 Peroxodicopper(II)Complex of a Sterically Hindered Hexapyridine Dinucleating Ligand"J.Am.Chem.Soc.. 121・47. 11006-11007 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Watanabe,Y. et al.: "Effects of the Arrangement of Distal Catalytic Residue on Regioselectivity and Reactivity in the Coupled oxidation of Sperm Whale Myoglobin Mutants"J.Am.Chem.Soc.. 121・10. 2007-2011 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Watanabe,Y. et al.: "Formation and Catalytic Roles of Compound I in the Hydrogen Peroxide-Dependent Oxidations by His64 Myoglobin Mutants"J.Am.Chem.Soc.. 121・43. 9952-9957 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Watanabe,Y.; Fukuzumi,S.: "Mechanisms of Sulfoxidation Catalyzed by High-Valent Intermediates of Heme Enzymes : Electron Transfer vs Oxygen Transfer Mechanism"J.Am.Chem.Soc.. 121・41. 9497-9502 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Fukuzumi,S. et al.: "ESR Spectra of Superoxide Anion-Scandium Complexes Detectable in Fluid Solution"J.Am.Chem.Soc.. 121・7. 1605-1606 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Fukuzumi,S. et al.: "Electron Transfer in Chemistry, Vol.2"Wiley-VCH. 3-59 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Fukuzumi,S. et al.: "Electron Transfer in Chemistry, Vol.4"Wiley-VCH. 270-326 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Fukuzumi,S. et al.: "Electron Transfer in Chemistry, Vol.2"Wiley-VCH. 927-966 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Fukuzumi,S. et al.: "Porphyrin Handbook, Vol.8"Academic Press. 115-152 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Watanabe,Y. et al.: "Characterization of High-Valent Oxo-Metalloporphyrins"Springer Verlag. 62-89 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Naruta, Y.et al.: "Synthesis and Characterization of Alkanethiolate-coordinated Iron Porphyrins and Their Dioxygen Adducts as Models for the Active Center of Cytochrome P-450"J.Am.Chem.Soc.. 123. 1133-1142 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Itoh, S. ; Fukuzumi, S.et al.: "Fine Tuning of Interaction between Copper (I) and Disulfide Bond. Formation of a Bis (μ-thiolato) dicopper (II) Complex by Reductive Cleavage of Disulfide Bond with Copper (I)"J.Am.Chem.Soc.. 123, (in press.). (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Fukuzumi, S.et al.: "Catalytic Effects of Dioxygen on Intramolecular Electron Transfer in Radical Ion Pairs of Zinc Porphyrin-Linked Fullerenes"J.Am.Chem.Soc.. 123. 2571-2575 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Itoh, S. ; Fukuzumi S.et al.: "Effects of Metal Ions on Physicochemical Properties and Redox Reactivity of Phenolates and Phenoxyl Radicals : Mechanistic Insight into Hydrogen Atom Abstraction by Phenoxyl Radical-Metal Complexes"J.Am.Chem.Soc.. 123. 2165-2175 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Fukuzumi, S.et al.: "Light-Harvesting and Photocurrent Generation by Gold Electrodes Modified with Mixed Self-Assembled Monolayers of Boron-Dipyrrin and Ferrocene-Porphyrin-Fullerene Triad"J.Am.Chem.Soc.. 123. 100-110 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Fukuzumi, S.et al.: "Photoactive Three-Dimensional Monolayers : Porphyrin-Alkanethiolate-Stabilized Gold Clusters"J.Am.Chem.Soc.. 123. 335-336 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Watanabe, Y.et al.: "Molecular Engineering of myoglobin : The Improvement of Oxidation Activity by Replacing Phe-43 with Tryptophan"Biochemistry. 40. 1044-1052 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Naruta, Y.et al.: "Direct Binding of Hydroxylamine to the Heme Iron of Arthromyces ramousus Peroxidase"J.Biol.Chem.. 275. 32919-32924 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Itoh, S. ; Fukuzumi, S.et al.: "Effects of Metal Ions on the Electronic, Redox, and Catalytic Properties of Cofactor TTQ of Quinoprotein Amine Dehy drogenases"J.Am.Chem.Soc.. 122. 12087-12097 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Watanabe, Y. ; Suzuki, M. ; Moro-oka, Y.et al.: "Synthesis, Structures, and Properties of Bis (μ-oxo) nickel (III) and Bis (μ-superoxo) nickel (II) Complexes : An Unusual Conversion of a Ni (III)_2 (μ-O)_2 Core into a Ni (II)_2 (μ-OO)_2 Core by H_2O_2 and Oxygenation of Ligand"J.Am.Chem.Soc.. 122. 254-262 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Suzuki, M. ; Watanabe, Y.et al.: "A Bis (μ-oxo) dicopper (III) Complex with Aromatic Nitrogen Donors : Structural Characterization and Reversible Conversion between Copper (I) and Bis (μ-oxo) dicopper (III) Species"J.Am.Chem.Soc.. 122. 2124-2125 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Watanabe, Y.et al.: "Investigations of the Myoglobin Cavity Mutant H93G with Unnatural Imidazole Proximal Ligands as a Modular Peroxide O-O Bond Cleavage Model System"Biochemistry. 39. 1446-1454 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Itoh, S. ; Fukuzumi, S.et al.: "Resonance Raman spectroscopy as a probe of the bis (μ-oxo) dicopper core"J.Am.Chem.Soc.. 122. 792-802 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Iroh, S. ; Fukuzumi, S.et al.: "Photochemical Reactions of Coenzyme PQQ (Pyrroloquinolinequinone) and Analogues with Benzyl Aleohol Derivatives via Photoinduced Electron Transfer"J.Am.Chem.Soc.. 122. 8435-8443 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Fukuzumi, S. ; Itoh, S.et al.: "Synthesis and Characterization of Imidazolate-Bridged Dinuclear Complexes as Active Site Models of Cu, Zn-SOD"J.Am.Chem.Soc.. 122. 5733-5741 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Watanabe, Y.et al.: "Effects of the Location of Distal Histidine in the Reaction of Myoglobin with Hydrogen Peroxide"J.Biol.Chem.. 273. 2838-2844 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Suzuki, M.et al.: "Crystal Structure and Reversible O_2-Binding of a Room Temperature Stable μ-η^2 : η^2 Peroxodicopper (II) Complex of a Sterically Hindered Hexapyridine Dinucleating Ligand"J.Am.Chem.Soc.. 121. 11006-11007 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Watanabe, Y.et al.: "Effects of the Arrangement of Distal Catalytic Residue on Regioselectivity and Reactivity in the Coupled oxidation of Sperm Whale Myoglobin Mutants"J.Am.Chem.Soc.. 121. 2007-2011 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Watanabe, Y. ; Fukuzumi, S.et al.: "Mechanisms of Sulfoxidation Catalyzed by High-Valent Intermediates of Heme Enzymes : Electron Transfer vs Oxygen Transfer Mechanism"J.Am.Chem.Soc.. 121. 9497-9502 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Itoh, S. ; Fukuzumi, S.et al.: "Aliphatic Hydroxylation by a Bis (μ-oxo) dinickel (III) Complex"J.Am.Chem.Soc.. 121. 8945-8946 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Watanabe, Y.et al.: "Formation and Catalytic Roles of Compound I in the Hydrogen Peroxide-Dependent Oxidations by Ilis64 Myoglobin Mutants"J.Am.Chem.Soc.. 121. 9952-9957 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Fukuzumi, S.et al.: "ESR Spectra of Superoxide Anion-Scandium Complexes Detectable in Fluid Solution"J.Am.Chem.Soc.. 121. 1605-1606 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Fukuzumi, S.et al.: "Electron-Transfer Kinetics for Generation of Organoiron (IV) Porphyrins and the Iron (IV) Porphyrin π Radical Cations"J.Am.Chem.Soc.. 121. 785-790 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Fukuzumi, S.et al.: "Electron Transfer in Chemistry ; Balzani, V., Ed. Vol.2"Wiley-VCH : Weinheim. 270-326,927-966 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Fukuzumi, S.et al.: "Electron Transfer in Chemistry ; Balzani, V., Ed. Vol.4"Wiley-VCH : Weinheim. 3-59 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Watanabe, Y.et al.: "Characterization of High-Valent Oxo-Metalloporphyrins ; Meunier, B., Ed. Vol.97"Springer Verlag : Berlin. 62-89 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Watanabe, Y.: "High-Valent Intermediates, Kadish, K.M., Smith, K.M.and Guilard, R., Ed. Vol.4"Academic Press : San Diego. 97-118 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Fukuzumi, S.et al.: "Porphyrin Handbook ; Kadish, K.M. ; Smith, K.M. ; Guilard, R., Eds. Vol.8"Academic Press : New York. 115-152 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2000 Final Research Report Summary
  • [Publications] Shunichi Fukuzumi et al.: "Light-Harvesting and Photocurrent Generation by Gold Electrodes Modified with Mixed Self-Assembled Monolayers of Boron-Dipyrrin and Ferrocene-Porphyrin-Fullerene Triad"J.Am.Chem.Soc.. 123・1. 100-110 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Photoactive Three-Dimensional Monolayers : Porphyrin-Alkanethiolate-Stabilized gold Clusters"J.Am.Chem.Soc.. 123・2. 335-336 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Catalytic Effects of Dioxygen on Intramolecular Electron Transfer in Radical Ion Pair of Zinc Porphyrin-Linked Fullerenes"J.Am.Chem.Soc.. 123・(in press). (2001)

    • Related Report
      2000 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Effects of Metal Ions on Physicochemical Properties and Redox Reactivity of Phenolates and Phenoxyl Radicals : Mechanistic Insight into Hydrogen Atom Abstraction by Phenoxyl Radical-Metal Complexes"J.Am.Chem.Soc.. 123・(in press). (2001)

    • Related Report
      2000 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Modulating Charge Separation and Charge Recombination Dynamics in Porphyrin-Fullerene Linked Dyads and Triads : Marcus-Normal versus Inverted Region,"J.Am.Chem.Soc.. 123・(in press). (2001)

    • Related Report
      2000 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Effects of Metal Ions on the Electronic, Redox, and Catalytic Properties of Cofactor TTQ of Quinoprotein Amine Dehydrogenases"J.Am.Chem.Soc.. 122・49. 12087-12097 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Photochemical Reactions of Coenzyme PQQ (Pyrroloquinolinequinone) and Analogues with Benzyl Alcohol Derivatives via Photoinduced Electron Transfer"J.Am.Chem.Soc.. 122・35. 8435-8443 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Hydride Transfer from 9-Substituted 10-Methl-9,10-dihydroacridines to Hydride Acceptors via Charge-transfer Complexes and Sequential Electron-Proton-Electron Transfer. A Negative Temperature Dependence of the Rates"J.Am.Chem.Soc.. 122・18. 4286-4294 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Stepwise Bond Formation in Photochemical and Thermal Diels-Alder Reactions of C_<60> with Danishefsky's Dienes"J.Am.Chem.Soc.. 122・10. 2236-2243 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Resonance Raman Spectroscopy as a Probe of the bis(μ-oxo) dicopper Core"J.Am.Chem.Soc.. 122・5. 792-802 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Synthesis and Characterization of Imidazolate-Bridged Dinuclear Complexes as Active Site Models of Cu, Zn-SOD"J.Am.Chem.Soc.. 122・24. 5733-5741 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Electrosynthesis and Structural Characterization of Two (C_6H_5CH_2)_4C_<60> Isomers"J.Am.Chem.Soc.. 122・4. 563-570 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Photoinduced energy transfer in mixed self-assembled monolayers of pyrene and porphyrin"Chem.Commun.. ・8. 661-662 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Catalytic effect of monovalent cations on the amine oxidation by cofactor TTQ of quinoprotein amine dehydrogenases"Chem.Commun.. ・5. 329-330 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Regioreversed Thermal and Photochemical Reduction of 10-Methylacridinium and 1-Methylquinolinium Ions by Organosilanes and Oraganostannanes"J.Phys.Chem.A. 105・(in press). (2001)

    • Related Report
      2000 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "An Extremely Small Reorganization Energy of Electron Transfer in Porphyrin-Fullerene Dyad"J.Phys.Chem.A. 105・(in press). (2001)

    • Related Report
      2000 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Solvent Dependence of Charge Separation and Charge Recombination Rates in Porphyrin-Fullerene Dyad"J.Phys.Chem.A. 105・2. 325-332 (2001)

    • Related Report
      2000 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Effects of Lowering Symmetry on the ESR Spectra of Radical Anions of Fullerene Derivatives and the Reduction Potentials"J.Phys.Chem.A. 104・46. 10688-10694 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Effect of Addition Pattern on the Electrochemical and Spectroscopic Properties of Neutral and Reduced 1,2- and 1,4-(C_6H_5CH_2)_2C_<60> Isomers"J.Phys.Chem.A. 104・17. 3878-3883 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Splitting of Degenerate Orbitals of Dibenzyl and Tetrabenzyl Adducts of C_<60> : ESR of the Radical Anions and the Rotation Barriers of Benzyl Groups"J.Phys.Chem.A. 104・13. 2908-2913 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Electrogeneration and Characterization of (C_6H_5CH_2)_2C_<70>"J.Phys.Chem.A. 104・13. 2902-2907 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Comparison between Electron Transfer and Nucleophilic Reactivities of Ketene Silyl Acetals with Cationic Electrophiles"J.Org.Chem.. 66・4. 1450-1454 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Photochemical Generation of Cyclopentadienyliron Dicarbonyl Anion by a Nicotinamide Adenine Dinucleotide Dimer Analogue"Inorg.Chem.. 40・(in press). (2001)

    • Related Report
      2000 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Model Complexes for the Active Form of Galactose Oxidase. Physicochemical Properties of Cu(II)- and Zn(II)-Phenoxyl Radical Complexes"Inorg.Chem.. 39・16. 3708-3711 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "100% Selective Oxygenation of p-Xylene to p-Tolualdehyde via Photoinduced Electron Transfer"Org.Lett.. 2・23. 3647-3650 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Aliphatic Hydroxylation by a Bis (μ-oxo) dicopper (III) Complex"Angew.Chem.Int.Ed.. 39・2. 398-400 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Quantitative Evaluation of Lewis Acidity of Metal Ions Derived from the g Values of ESR Spectra of Superoxide : Metal Ion Complexes in Relation to the Promoting Effects in Electron Transfer Reactions"Chem.Eur.J. 6・24. 4532-4535 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "The Essential Role of a Zn^<II> Ion in the Disproportionation of Semiquinone Radical Anion by an Imidazolate-Bridged Cu^<II>-Zn^<II> Model of Superoxide Dismutase"Angew.Chem.Int.Ed.. 39・24. 4537-4539 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Characterization of Imidazolate-bridged Cu(II)-Zn(II) Heterodinuclear and Cu(II)-Cu(II) Homodinuclear Hydroperoxo Complexes as Reaction Intermediate Models of Cu, Zn-SOD"Chem.Commun.. ・12. 1051-1052 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Remarkable enhancement of photocurrent generation by ITO electrodes modified with a self-assembled monolayer of porphyrin"Chem.Commun.. ・19. 1921-1922 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Electron Transfer in Chemistry, Vol.2"Wiley-VCH (in press). (2001)

    • Related Report
      2000 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Electron Transfer in Chemistry, Vol.4"Wiley-VCH (in press). (2001)

    • Related Report
      2000 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Hydride Transfer from 9-Substituted 10-Methyl-9, 10-dihydroacridines to Hydride Acceptors via Charge-Transfer Complexes and Sequential Electron-Proton-Electron Transfer. A Negative Temperature Dependence of the Rates"J. Am. Chem. Soc.. 122 (in press). (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Stepwise Bond Formation in Photochemical and Thermal Diels-Alder Reactions of C with Danishefsky's Dienes"J. Am. Chem. Soc.. 122 (in press). (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Synthesis and Characterization of Imidazolate-Bridged Dinuclear Complexes as Active Site Models of Cu, Zn-SOD"J. Am. Chem. Soc.. 122 (in press). (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Electrosynthesis and Structural Characterization of Two (C_6H_5CH_2)_4C_<60> Isomers"J. Am. Chem. Soc.. 122・4. 563-570 (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Resonance Raman Spectroscopy as a Probe of the Bis(μ-oxo) dicopper Core"J. Am. Chem. Soc.. 122・5. 792-802 (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "ESR Spectra of Superoxide Anion-Scandium Complexes Detectable in Fluid Solution"J. Am. Chem. Soc.. 121・7. 1605-1606 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Electron Transfer Kinetics for Generation of Organoiron (IV) Porphyrins and the Iron (IV) Porphyrin π Radical Cations"J. Am. Chem. Soc.. 121・4. 785-790 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Electron Transfer Properties of C_<60> and tert-Butyl-C_<60> Radical"J. Am. Chem. Soc.. 121・14. 3468-3474 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Mechanisms of Sulfoxidation Catalyzed by High-Valent Intermediates of Heme Enzymes : Electron Transfer vs Oxygen Transfer Mechanism"J. Am. Chem. Soc.. 121・41. 9497-9502 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Alphatic Hydroxylation by (μ-oxo) dinickel (III) Complex"J. Am. Chem. Soc.. 121・38. 8945-8946 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Oxidation of Benzyl Alcohol with Cu(II) and Zn(II) Complexes of Phenoxyl Radical as a Model Reaction of Galactose Oxidase"Angew. Chem., Int. Ed. Engl.. 38・15. 2774-2776 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Decreased Electron Transfer Rates of Manganese Porphyrins with Conformational Distortions of the Macrocycle"Angew. Chem. Int. Ed. Engl.. 38・7. 964-966 (1999)

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      1999 Annual Research Report
  • [Publications] Shunishi Fukuzumi et al.: "Electron Transfer in Chemistry, Vol. 2"Wiley-VCH (in press). (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] Shunishi Fukuzumi et al.: "Electron Transfer in Chemistry, Vol. 5"Wiley-VCH (in press). (2000)

    • Related Report
      1999 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Porphyrin Handbook, Vol. 8"Academic Press. 115-152 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] Shunichi Fukuzumi et al.: "Advances in Photochemistry, Vol. 25"Wiley. 107-172 (1999)

    • Related Report
      1999 Annual Research Report

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Published: 1999-04-01   Modified: 2018-03-28  

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