| Project/Area Number |
11305007
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| Research Category |
Grant-in-Aid for Scientific Research (A)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
表面界面物性
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| Research Institution | OSAKA UNIVERSITY |
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Principal Investigator |
KUWAHARA Yuji DEPT. OF PREC. SCI. & TECH., OSAKA UNIV., ASSOCIATE PROF., 大学院・工学研究科, 助教授 (00283721)
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| Co-Investigator(Kenkyū-buntansha) |
SAITO Akira DEPT. OF PREC. SCI. & TECH., OSAKA UNIV., ASSISTANT PROF., 大学院・工学研究科, 助手 (90294024)
AONO Masakazu DEPT. OF PREC. SCI. & TECH., OSAKA UNIV., PROF., 大学院・工学研究科, 教授 (10184053)
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| Project Period (FY) |
1999 – 2001
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| Project Status |
Completed (Fiscal Year 2001)
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| Budget Amount *help |
¥43,110,000 (Direct Cost: ¥42,000,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2001: ¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2000: ¥3,600,000 (Direct Cost: ¥3,600,000)
Fiscal Year 1999: ¥34,700,000 (Direct Cost: ¥34,700,000)
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| Keywords | funcitonal organic molecules / scanning tunneliing microscopy / evaluation of functions / independently driven double-tip / quantum device |
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| Research Abstract |
The aim of this research is to construct one-dimensional molecular wires, especially, conducting nanowires, and to control their patterns on the solid surface, consequently, fabricating single-electron tunneling device with organic molecules. In addition, independently-driven double-tip scanning tunneling microscope (WT-STM), which is a novel system to evaluate functionalities of such nanoscale structures, is newly constructed.
This year, we investigated the two-dimensionally ordered structures of two component molecular monolayers, in which the molecules of diacetylene compounds and fatty acid lay parallel to the surface on the underlying HOPG. The possibility of obtaining the microscopically mixed regions varied depending on the ratio of the relative lengths of the two molecules. Poly-diacetylene molecular wires can be successfully fabricated at intended positions on the surface using chain polymerization by applying pulsed bias voltage from the STM tip.
We have evaluated the conductivity of ultrathin molecular sheet of diacetylene compounds using WT-STM. We made the sample of six layers with poly-diacetylene compounds by LB method and irradiation of UV light. The distances of the two tips were varied from sub-micron to hundreds microns. Obtained results showed a significantly high conductivity of its film compared with that of the bulk structure. It is considered that electronic feature of one-dimensional and microscopic structures of molecular systems are quite different from that of three dimensional and macroscopic, that is, bulk molecular system. And this result is quite promising for the constructions of nanoscale molecular-based devices with various noble functions.
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