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Creation of multi-dimensional structures of functional molecules by metal complexation reactions

Research Project

Project/Area Number 11309003
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field 広領域
Research InstitutionThe University of Tokyo

Principal Investigator

NISHIHARA Hiroshi  The University of Tokyo, Graduate School of Science, Professor, 大学院・理学系研究科, 教授 (70156090)

Co-Investigator(Kenkyū-buntansha) KURIHARA Masato  The University of Tokyo, Graduate School of Science, Assistant, 大学院・理学系研究科, 助手 (50292826)
KUBO Kenya  The University of Tokyo, Graduate School of Science, Assistant, 大学院・理学系研究科, 助手 (60214988)
水谷 淳  東京大学, 大学院・理学系研究科, 助手 (00308256)
Project Period (FY) 1999 – 2001
Project Status Completed (Fiscal Year 2001)
Budget Amount *help
¥30,760,000 (Direct Cost: ¥29,800,000、Indirect Cost: ¥960,000)
Fiscal Year 2001: ¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2000: ¥8,400,000 (Direct Cost: ¥8,400,000)
Fiscal Year 1999: ¥18,200,000 (Direct Cost: ¥18,200,000)
Keywordsmetal nanoparticles / azo-coningated comolexes / photochromic complexes / donor-acceptor interaction / quinone / ferrocene / redox / intramolecular electron transfer / 錯体 / 共役 / 高次構造 / オリゴマー / フラスター / ポリマー / クラスター
Research Abstract

To construct new multi-dimensional functional molecular systems by utilizing complex reactions of transition metal complexes has been investigated in this research project. The molecular systems that have been focused are 1) azo-conjugated metal complexes with photo-functions, 2) donor-acceptor conjugated complexes with an ability of proton-coupled intramolecular electron-transfer reactions, and 3) metal nanoparticles modified with redox- and photo-functional complexes. The summary of the results is as follows.
The trans-to-cis isomerization of azoferrocene proceeds not only by the photoexcitation of the π-π^* transition band but also by photoexcitation of the MLCT (d-π^* transition) band. The trans/cis ratio of the azobenzene-attached bipyridine ligands in their cobalt complex is reversibly altered by a combination of photoirradiation with a single UV light source and the reversible redox change between Co(II) and Co(III). A newly synthesized Ni, Pd and Pt tolylazophenylenedithiolato c … More omplexes 2-4 show reversible trans-to-cis photoisomerization, proto-chromism, and novel proton-coupled cis-to-trans isomerization.
The protonation to carbonyl groups of the anthraquinone moiety in 1 -ferrocenylethynylanthraquinone causes intramolecular electron transfer leading to a novel structural change into a η^6-fulvene-cumulene Fe(II) complex. A 2:1 donor-acceptor complex, l,5-bis(ferrocenylethynyl)anthraquinone undergoes a two-step proton response, and the doubly protonated species involves a η^6-fulvene-Fe(II) complex-cumulene structure, and a novel spin-separated form of a ferrocenium (Fe(III)) ion and a semiquinone radical in the solution. Furthermore, the complex is in a thermal equilibrium between the valence tautomers of a donor-acceptor system in the solid state.
Synthesis and electrochemical deposition behavior of biferrocene and anthraquinone derivative-modified Au and Pd clusters have been investigated. It is also possible to fabricate hetero structures by alternative electrodeposition of Bfc-modified gold and palladium nanoparticles. Less

Report

(4 results)
  • 2001 Annual Research Report   Final Research Report Summary
  • 2000 Annual Research Report
  • 1999 Annual Research Report
  • Research Products

    (90 results)

All Other

All Publications (90 results)

  • [Publications] H.Nishihara, T.Horikoshi: "Intervalence-Transfer Bands for Mixed-Valence Oligo(1, 1'-dihexylferrocenylene)s"Synth. Metals. 101(1-3). 1523 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] H.Nishihara, M.Kurashina, K.Aramaki, K.Kubo: "Near-IR Photoconductivity of Poly(1, 1'-dihexylferrocenylene)-TCNE CT Complex"Synth. Metals. 101(1-3). 457-458 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] I.Matsuoka, H.Yoshikawa, M.Kurihara, H.Nishihara: "Synthesis and Redox Properties of Poly (cobaltacyclopentadienylene thienylene)"Synth. Metals. 102(1-2). 1519-1520 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] M.Kurihara, M.Kurosawa, T.Matsuda, H.Nishihara: "Synthesis and Physical Properties of Azo-ferrocene Oligomers and Polymers"Synth. Metals. 102(1-3). 1517-1518 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T.Horikoshi, M.Itoh, M.Kurihara, K.Kubo, H.Nishihara: "Synthesis, Redox Behaviors and Electrodeposition of Biferrocene-modified Gold Clusters"J. Electroanal. Chem.. 473(1-2). 113-116 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] K.N.Jayaprakash, P.C.Ray, I.Matsuoka, M.M.Bhadbhade, V.G.Puranik, P.K.Das, H.Nishihara, A.Sarkar: "Ferrocene in Conjugation with a Fischer Carbene : Synthesis NLO and Electrochemical Behavior of a Novel Organometallic Push-Pull system"Organometallics. 18(19). 3851-3858 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T.Horikoshi, K.Kubo, H.Nishihara: "Dependence of intervalence-transfer bands for mixed-valence oligo(1, 1'-dihexylferrocenylene)s on the oxidation number and the number of ferrocene units from two to six"J. Chem. Soc., Dalton Trans.. (19). 3355-3360 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] M.Kurosawa, T.Nankawa, T.Matsuda, K.Kubo, M.Kurihara, H.Nishihara: "Synthesis of Azo-bridged Ferrocene Oligomers and a Polymer and Electrochemical and Optical Analysis of Internuclear Electronic Interactions in Their Mixed-Valence States"Inorg. Chem.. 38(22). 5113-5123 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] K.Kubo, H.Kondow, H.Nishihara: "Oxidative-Decomposition and Electron-Transfer Kinetics of Self-Assembled Monolayers of Biferrocene-Terminated Alkanethiol on Gold"Electrochemistry. 67(12). 1229-1131 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] M.Yamada, K.Kubo, H.Nishihara: "Electroreductive Deposition of Au Clusters Modified with an Anthraquinone Derivative"Chem. Lett. (12). 1335-1336 (1999)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T.Yutaka, M.Kurihara, K.Kubo, H.Nishihara: "Novel Photoisomerization Behavior of Rh Binuclear Complexes Involving an Azobenzene-bridged Bis(terpyridine) Ligand -Strong Effects of Counterion and Solvent and the Induction of Redox Potential Shift"Inorg. Chem.. 39(16). 3438-3439 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T.Yutaka, M.Kurihara, H.Nishihara: "Synthesis and Physical Properties of a a-Conjugated Ruthenium(II) Dinuclear Complex Involving an Azobenzene-Bridged Bis(terpyridine) Ligand"Mol. Cryst. Liq. Cryst. 343. 193-198 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] M.Kurihara, K.Kubo, T.Horikoshi, M.Kurosawa, T.Nankawa, T.Matsuda, H.Nishihara: "Electron Transfer of Conjugated Polymeric Ferrocenes"Macromol. Symp.. 156. 21-27 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] M.Murata, T.Fujita, M.Yamada, M.Kurihara, H.Nishihara: "Novel Protonation-Induced Structural Conversion of an Ethynylene-bridged Ferrocene-Anthraquinone Complex"Chem. Lett. 1328-1329 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] M.Kurihara, T.Matsuda, A.Hirooka, T.Yutaka, H.Nishihara: "Novel Photo-isomerization of Azoferrocene with a Low-energy MLCT Band and Significant Change of the Redox Behavior between the Cis and Trans Isomers"J. Am. Chem. Soc. 122(49). 12373-12374 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] M.Murata, T.Hoshi, I.Matsuoka, T.Nankawa, M.Kurihara, H.Nishihara: "Synthesis and Redox Properties of a π-Conjugated Cyclobutadienecobalt Polymer Containing Ferrocenyl Groups"J. Inorg. Organomet. Polym.. 10(4). 209-219 (2000)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] M.Kurihara, H.Sano, M.Murata, H.Nishihara: "Synthesis of a Vinylene-Bridged Ferrocene-Hydroquinone Complex and Its Unusual Structural Change Originated by Proton-Coupled Electron Transfer"Inorg. Chem. 40(1). 4-5 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] H.Nishihara: "Redox and Optical Properties of Conjugated Ferrocene Oligomers"Bull. Chem. Soc. Jpn (Accounts). 74(1). 19-29 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] M.Yamada, T.Tadera, K.Kubo, H.Nishihara: "Electroreductive Deposition of Anthraquinone Derivative Attached Au Clusters : Optical Properties and Scanning Tunneling Microscopy Observation of the Electrodeposited Cluster Film"Langmuir. 17(8). 2363-2370 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] M.Yamada, I.Quiros, J.Mizutani, K.Kubo, H.Nishihara: "Preparation of palladium nanoparticles functionalized with biferrocene thiol derivatives and their electro-oxidative deposition"Phys. Chem. Chem. Phys.. 3. 3377-3381 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Y.Men, K.Kubo, M.Kurihara, H.Nishihara: "Syntheses of biferrocene dithiol and disulfide derivatives and their redox behavior in SAM with and without gold clusters on the gold substrate"Phys. Chem. Chem. Phys.. 3. 3427-3430 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] S.Kume, M.Kurihara, Hiroshi Nishihara: "Reversible trans-cis photoisomerization of azobenzene-attached bipyridine ligands coordinated to cobalt using a single UV light source and the Co(III)/Co(II) redox change"Chem. Commun.. 17. 1656-1657 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T.Yutaka, I.Mori, M.Kurihara, J.Mizutani, K.Kubo, S.Furusho, K.Matsumura, N.Tamai, H.Nishihara: "Synthesis, Characterization, and Photochemical Properties of Azobenzene-Conjugated Rh and Ru Bis(terpyridine) Complexes"Inorg. Chem.. 40(19). 4986-4995 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] M.Nihei, M.Kurihara, J.Mizutani, H.Nishihara: "Photo-and Proton-coupled Isomerization of Novel Azo-conjugated Platinadithiolene Complex"Chem. Lett. 9. 852-853 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Y.Yamada, J.Mizutani, M.Kurihara, H.Nishihara: "Synthesis of a New Bis(ferrocenyl)ruthenacyclopentatriene Compound with a Significant Inter-metal Electronic Communication"J. Organometal. Chem. 637-639. 80-83 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] M.Yamada, A.Kuzume, M.Kurihara, K.Kubo, H.Nishihara: "Formation of a novel porphyrin -gold nanoparticle network film induced by infrared light irradiation"Chem. Commun. 2476-2477 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] M.Murata, M.Yamada, T.Fujita, K.Kojima, M.Kurihara, K.Kubo, Y.Kobayashi, H.Nishihara: "Structural Conversion and Spin Separation in Bis(ferrocenylethynyl)anthraquinones Triggered by Proton-Coupled Intramolecular Electron Transfer"J. Am. Chem. Soc. 123(51). 12903-12904 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] K.Nishiyama, A.Kubo, I.Taniguchi, M.Yamada, H.Nishihara: "Effects of Alkyl Chain as a Spacer on Electrochemical Reaction and SEIRA Spectra for Self-assembled Monolayers' Having Anthraquinone Redox Center"Electrochemistry. 69(12). 980-983 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] I.Quiros, M.Yamada, K.Kubo, J.Mizutani, M.Kurihara, H.Nishihara: "Preparation of Alkyl Thiolate-Protected Palladium Nanoparticles and Their Size Dependence on Synthetic Conditions"Langmuir. (in press).

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] 西原 寛: "機能性金属錯体への期待"化学と教育. 49. 28-31 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] 西原 寛, 栗原正人: "金属錯体系のレドックス共役ナノ分子材料"化学工業. 52(8). 615-621 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] M.Kurihara, H.Nishihara: "Azo-and quinone-conjugated redox complexes -photo-and proton-coupled intramolecular reactions based on d-π interaction"Coord. Chem. Rev.. (in press).

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] 西原 寛: "「相性」,異なる物質間の相性"東京大学出版会. 249-270 (2001)

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] H.Nishihara: "Adv. Inorg. Chem."Redox Chemistry and Functionalities of Conjugated Ferrocene Systems(in press).

    • Description
      「研究成果報告書概要(和文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] M. Yamada, I. Quiros, J. Mizutani, K. Kubo, H. Nishihara: "Preparation of palladium nanoparticles functionalized with biferrocene thiol derivatives and their electro-oxidative deposition"Phys. Chem. Chem. Phys.. 3. 3377-3381 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] H.Nishihara, T.Horikoshi: "Intervalence-Transfer Bands for Mixed-Valence Oligo(1, 1'-dihexylferrocenylene)s"Synth. Metals. 102(1-3). 1523 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] H.Nishihara, M.Kurashina, K.Aramaki, K.Kubo: "Near-IR Photoconductivity of Poly(1, 1'-dihexylferrocenylene)-TCNE CT Complex"Synth. Metals. 101(1-3). 1523 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] M. Kurihara, M. Kurosawa, T. Matsuda, H. Nishihara: "Synthesis and Physical Properties of Azo-ferrocene Oligomers and Polymers"Synth. Metals. 102(1-3). 1517-1518 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T. Horikoshi, M. Itoh, M. Kurihara, K. Kubo, H. Nishihara: "Synthesis, Redox Behaviors and Electrodeposition of Biferrocene-modified Gold Clusters"J. Electroanal. Chem.. 473(1-2). 113-116 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] K. N. Jayaprakash, P. C. Ray, I. Matsuoka, M. M. Bhadbhade, V. G. Puranik, P. K. Das, H. Nishihara, A. Sarkar: "Ferrocene in Conjugation with a Fischer Carbene: Synthesis, NLO and Electrochemical Behavior of a Novel Organometallic Push-Pull system"Organometallics. 18(19). 3851-3858 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T. Horikoshi, K. Kubo, H. Nishihara: "Dependence of intervalence-transfer bands for mixed-valence oligo(1, 1 '-dihexylferrocenylene)s on the oxidation number and the number of ferrocene units from two to six"J. Chem. Soc., Dalton Trans.. (19). 3355-3360 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] M. Kurosawa, T. Nankawa, T. Matsuda, K. Kubo, M. Kurihara, H. Nishihara: "Synthesis ofAzo-bridged Ferrocene Oligomers and a Polymer and Electrochemical and Optical Analysis of Internuclear Electronic Interactions in Their Mixed-Valence States"Inorg. Chem.. 38(22). 5113-5123 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] K. Kubo, H. Kondow, H. Nishihara: "Oxidative-Decomposition and Electron-Transfer Kinetics of Self-Assembled Monolayers of Biferrocene-Terminated Alkanethiol on Gold"Electrochemistry. 67(12). 1129-1131 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] M. Yamada, K. Kubo, H. Nishihara: "Electroreductive Deposition of Au Clusters Modified with an Anthraquinone Derivative"Chem. Lett. (12). 1335-1336 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T. Yutaka, M. Kurihara, K. Kubo, H. Nishihara: "Novel Photoisomerization Behavior of Rh Binuclear Complexes Involving an Azobenzene-bridged Bis(terpyridine) Ligand - Strong Effects ofCounterion and Solvent and the Induction of Redox Potential Shift"Inorg. Chem.. 39(16). 3438-3439 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T. Yutaka, M. Kurihara, H. Nishihara: "Synthesis and Physical Properties of a π-Conjugated Ruthenium(II) Dinuclear Complex Involving an Azobenzene-Bridged Bis(terpyridine) Ligand"Mol. Cryst. Liq. Cryst.. 343. 193-198 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] M. Kurihara, K. Kubo, T. Horikoshi, M. Kurosawa, T. Nankawa, T. Matsuda, H. Nishihara: "Electron Transfer of Conjugated Polymeric Ferrocenes"Macromol. Symp.. 156. 21-27 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] M. Murata, T. Fujita, M. Yamada, M. Kurihara, H. Nishihara: "Novel Protonation-Induced Structural Conversion of an Ethynylene-bridged Ferrocene-Anthraquinone Complex"Chem. Lett.. 1328-1329 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] M. Kurihara, T. Matsuda, A. Hirooka, T. Yutaka, H. Nishihara: "Novel Photo-isomerization of Azoferrocene with a Low-energy MLCT Band and Significant Change of the Redox Behavior between the Cis and Trans Isomers"J. Am. Chem. Soc. 122(49). 12373-12374 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] M. Murata, T. Hoshi, I. Matsuoka, T. Nankawa, M. Kurihara, H. Nishihara: "Synthesis and Redox Properties of a π-Conjugated Cyclobutadienecobalt Polymer Containing Ferrocenyl Groups"J. Inorg. Organoment. Polym.. 10(4). 209-219 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] M. Kurihara, H. Sano, M. Murata, H. Nishihara: "Synthesis of a Vinylene-Bridged Ferrocene-Hydroquinone Complex and Its Unusual Structural Change Originated by Proton-Coupled Electron Transfer"Inorg. Chem.. 40(1). 4-5 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] H. Nishihara: "Redox and Optical Properties of Conjugated Ferrocene Oligomers"Bull. Chem. Soc. Jpn. (Accounts). 74(1). 19-29 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] M. Yamada, T. Tadera, K. Kubo, H. Nishihara: "Electroreductive Deposition of Anthraquinone Derivative-Attached Au Clusters: Optical Properties and STM Observation of the Electrodeposited Cluster Film"Langmuir. 17(8). 2363-2370 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Y. Men, K. Kubo, M. Kurihara, H. Nishihara: "Syntheses of biferrocene dithiol and disulfide derivatives and their redox behavior in SAM with and without gold clusters on the gold substrate"Phys. Chem. Chem. Phys.. 3. 3427-3430 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] S. Kume, M. Kurihara, H. Nishihara: "Reversible trans-cis photoisomerization of azobenzene-attached bipyridine ligands coordinated to cobalt using a single UV light source and the Co(III)/Co(II) redox change"Chem. Commun.. 2001(17). 1656-1657

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T. Yutaka, I. Mori, M. Kurihara, J. Mizutani, K. Kubo, S. Furusho, K. Matsumura, N. Tamai, H. Nishihara: "Synthesis, Characterization, and Photochemical Properties of Azobenzene- Conjugated Rh and Ru Bis(terpyridine) Complexes"Inorg. Chem.. 40(19). 4986-4995 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] M. Nihei, M. Kurihara, J. Mizutani, H. Nishihara: "Photo- and Proton-coupled Isomerization of Novel Azo-conjugated Platinadithiolene Complex"Chem. Lett.. 2001(9). 852-853

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] Y. Yamada, J. Mizutani, M. Kurihara, H. Nishihara: "Synthesis of a New Bis(ferrocenyl)ruthenacyclopentatriene Compound with a Significant Inter-metal Electronic Communication"J. Organometal. Chem.. 637-639. 80-83 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] M. Yamada, A. Kuzume, M. Kurihara, K. Kubo H. Nishihara: "Formation of a novel porphyrin - gold nanoparticle network film induced by infrared light irradiation"Chem. Commun.. 2476-2477 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] M. Murata, M. Yamada, T. Fujita, K. Kojima, M. Kurihara, K. Kubo, Y. Kobayashi, H. Nishihara: "Structural Conversion and Spin Separation in Bis(ferrocenylethynyl)anthraquinones Triggered by Proton-Coupled Intramolecular Electron Transfer"J. Am. Chem. Soc.. 123(51). 12903-12904 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] K. Nishiyama, A. Kubo, I. Taniguchi, M. Yamada, H. Nishihara: "Effects of Alkyl Chain as a Spacer on Electrochemical Reaction and SEIRA Spectra for Self-assembled Monolayers Having Anthraquinone Redox Center"Electrochemistry. 69(12). 980-983 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] I. Quiros, M. Yamada, K. Kubo, J. Mizutani, M. Kurihara, H. Nishihara: "Preparation of Alkyl Thiolate-Protected Palladium Nanoparticles and Their Size Dependence on Synthetic Conditions"Langmuir. (In press).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] M. Kurihara, H. Nishihara: "Azo- and quinone-conjugated redox complexes photo- and proton-coupled intramolecular reactions based on d-π interaction"Coord. Chem. Rev.. (In press).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] H. Nishihara: "Redox Chemistry and Functionalities of Conjugated Ferrocene Systems"Adv. Inorg. Chem.. (In press).

    • Description
      「研究成果報告書概要(欧文)」より
    • Related Report
      2001 Final Research Report Summary
  • [Publications] T.Yutaka, I.Mori, M.Kurihara, J.Mizutani, K.Kubo, S.Furusho, K.Matsumura, N. Tamai, H.Nishihara: "Synthesis, Characterization, and Photochemical Properties of Azobenzene- Conjugated Rh and Ru Bis(terpyridine) Complexes"Inorganic Chemistry. 40(19). 4986-4995 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] S.Kume, M, Kurihara, H.Nishihara: "Reversible trans-cis photoisomerization of azobenzene-attached bipyridine ligands coordinated to cobalt using a single UV light source and the Co(III)/Co(II) redox change"Chemical Communications. (17). 1656-1657 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] M.Nihei., M.Kurihara, J.Mizutani, H.Nishihara: "Photo- and Proton-coupled Isomerization of Novel Azo-conjugated Platinadithiolene Complex"Chemistry Letters. (9). 852-853 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] 西原寛, 栗原正人: "金属錯体系のレドックス共役ナノ分子材料"化学工業. 52(8). 615-621 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] H.Nishihara: "Redox Chemistry and Functionalities of Conjugated Ferrocene Systems"Advanced in Inorganic Chemistry. (印刷中).

    • Related Report
      2001 Annual Research Report
  • [Publications] M.Kurihara, H.Nishihara: "Azo- and quinone-conjugated redox complexes - photo- and proton-coupled intramolecular reactions based on d-□interaction"Coordination Chemistry Reviews. (印刷中).

    • Related Report
      2001 Annual Research Report
  • [Publications] M.Yamada, T.Tadera, K.Kubo, H.Nishihara: "Electroreductive Deposition of Anthraquinone Derivative-Attached Au Clusters : Optical Properties and STM Observation of the Electrodeposited Cluster Film"Langmuir. 17(8). 2363-2370 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] M.Yamada, I.Quiros, J.Mizutani, K.Kubo, H.Nishihara: "Preparation of palladium nanoparticles functionalized with biferrocene thiol derivatives and their electro-oxidative deposition"Phys. Chem. Chem. Phys.. 3. 3377-3391 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] Y.Men, K.Kubo, M.Kurihara, H.Nishihara: "Syntheses of biferrocene dithiol and disulfide derivatives and their redox behavior in SAM with and without gold clusters on the gold substrate"Phys. Chem. Chem. Phys. 3. 3427-3430 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] M.Yamada, A.Kuzume, M.Kurihara, K.Kubo, H.Nishihara: "Formation of a novel porphyrin-gold nanoparticle network film induced by infrared light irradiation"Chemical Commmmunications. 2476-2477 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] I.Quiros, M.Yamada, K.Kubo, J.Mizutani, M.Kurihara, H.Nishihara: "Preparation of Alkyl Thiolate-Protected Palladium Nanoparticles and Their Size Dependence on Synthetic Conditions"Langmuir. (印刷中).

    • Related Report
      2001 Annual Research Report
  • [Publications] M.Murata, M.Yamada, T.Fujita, K.Kojima, M.Kurihara, K.Kubo, Y.Kobayashi, H. Nishihara: "Structural Conversion and Spin Separation in Bis(ferrocenylethynyl)anthraquinones Triggered by Proton-Coupled Intramolecular Electron Transfer"J. Am. Chem. Soc. 123(51). 12903-12904 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] M.Murata, T.Hoshi, I.Matsuoka, T.Nankawa, M.Kurihara, H.Nishihara: "Synthesis and Redox Properties of a π-Conjugated Cyclobutadienecobalt Polymer Containing Ferrocenyl Groups"Journal of Inorganic and Organometallic Polymers. 10(4). 209-219 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] Y.Yamada, J.Mizutani, M.Kurihara, H.Nishihara: "Synthesis of a New Bis(ferrocenyl)ruthenacyclopentatriene Compound with a Significant Inter-metal Electronic Communication"Journal of the Organometallic Chemistry. 637-639. 80-83 (2001)

    • Related Report
      2001 Annual Research Report
  • [Publications] T.Yutaka,M.Kurihara,K.Kubo H.Nishihara: "Novel Photoisomerization Behavior of Rh Binuclear Complexes Involving an Azobenzene-bridged Bis(terpyridine)Ligand-Strong Effects of Counterion and Solvent and the Induction of Redox Potential Shift"Inorg.Chem. 39(16). 3438-3439 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] T.Yutaka,M.Kurihara,H.Nishihara: "Synthesis and Physical Properties of a π-Conjugated Ruthenium(II) Dinuclear Complex Involving an Azobenzene-Bridged Bis(terpyridine)Ligand."Mol.Cryst.Liq.Cryst.. 343. 193-198 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] M.Kurihara,K.Kubo,T.Horikoshi,M.Kurosawa,T.Nankawa,T.Matsuda,H.Nishihara: "Electron Transfer of Conjugated Polymeric Ferrocenes"Macromol.Symp.. 156. 21-27 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] M.Murata,T.Fujita,M.Yamada,M.Kurihara,H.Nishihara: "Novel Protonation-Induced Structural Conversion of an Ethynylene-bridged Ferrocene-Anthraquinone Complex."Chem.Lett.. (11). 1328-1329 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] M.Kurihara,T.Matsuda,A.Hirooka,T.Yutaka,H.Nishihara: "Novel Photo-isomerization of Azoferrocene with a Low-energy MLCT Band and Significant Change of the Redox Behavior between the Cis and Trans Isomers"J.Am.Chem.Soc.. 122(49). 12373-12374 (2000)

    • Related Report
      2000 Annual Research Report
  • [Publications] M.Kurihara,H.Sano,M.Murata,H.Nishihara: "Synthesis of a Vinylene-Bridged Ferrocene-Hydroquinone Complex and Its Unusual Structural Change Originated by Proton-Coupled Electron Transfer"Inorg.Chem.. 40(1). 4-5 (2001)

    • Related Report
      2000 Annual Research Report
  • [Publications] H.Nishihara: "Redox and Optical Properties of Conjugated Ferrocene Oligomers."Bull.Chem.Soc.Jpn.. 74(1). 19-29 (2001)

    • Related Report
      2000 Annual Research Report
  • [Publications] M.Murata,T.Hoshi,I.Matsuoka,T.Nankawa,M.Kurihara,H.Nishihara,: "Synthesis and Redox Properties of a π-Conjugated Cyclobutadienecobalt Polymer Containing Ferrocenyl Groups"J.Inorg.Organomet.Polym.. (印刷中).

    • Related Report
      2000 Annual Research Report
  • [Publications] M.Yamada,T.Tadera,K.Kubo,H.Nishihara: "Electroreductive Deposition of Anthraquinone Derivative-Attached Au Clusters : Optical Properties and STM Observation of the Electrodeposited Cluster Film"Langmuir. (印刷中).

    • Related Report
      2000 Annual Research Report
  • [Publications] T. Horikoshi, K. Kubo, H. Nishihara: "Dependence of Intervalence-transfer Bands for Mixed-valence Oligo (1,1'-dihexylferrocenylene) s on the Oxidation Number and the Number of Ferrocene Units from Two to Six"J. Chem. Soc., Dalton Trans.. 1999・19. 3355-3360 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] M. Kurosawa, T. Nankawa, T. Matsuda, K. Kubo, M. Kurihara, H. Nishihara: "Synthesis of Azo-bridged Ferrocene Oligomers and a polymer and Electrochemical and Optical Analysis of Internuclear Electronic Interactions in Their Mixed-Valence States"Inorganic Chemistry. 38・22. 5113-5123 (1999)

    • Related Report
      1999 Annual Research Report
  • [Publications] M. Yamada, K. Kubo, H. Nishihara: "Electroductive Deposition of Au Clusters Modified with an Anthraquinone Dericative"Chemistry Letters. 1999・12. 1335-1336 (1999)

    • Related Report
      1999 Annual Research Report

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Published: 1999-04-01   Modified: 2016-04-21  

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