| Project/Area Number |
11358007
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| Research Category |
Grant-in-Aid for Scientific Research (A).
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| Allocation Type | Single-year Grants |
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| Section | 展開研究 |
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| Research Field |
Nuclear engineering
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| Research Institution | Hokkaido University |
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Principal Investigator |
OHASHI Hiroshi Hokkaido Univ., Grad.School of Eng., Prof., 大学院・工学研究科, 教授 (20001315)
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| Co-Investigator(Kenkyū-buntansha) |
KOZAI Naofumi Japan Atomic Energy Research Institute, Dept.Environ.Safety, Researcher, 東海研究所・環境安全研究部, 研究員
KOZAKI Tamotsu Hokkaido Univ., Grad.School of Eng., Inst., 大学院・工学研究科, 助手 (60234746)
SATO Seichi Hokkaido Univ., Grad.School of Eng., Asso.Prof., 大学院・工学研究科, 助教授 (40117122)
KATO Hiroyasu Mitsubishi Materials Corp., Energy & Ecosystem Lab., Researcher, 環境エネルギー研究所, 研究員
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| Project Period (FY) |
1999 – 2000
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| Project Status |
Completed (Fiscal Year 2000)
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| Budget Amount *help |
¥16,700,000 (Direct Cost: ¥16,700,000)
Fiscal Year 2000: ¥2,800,000 (Direct Cost: ¥2,800,000)
Fiscal Year 1999: ¥13,900,000 (Direct Cost: ¥13,900,000)
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| Keywords | Atomic force microscope / nuclear waste / montmorillonite / sorption / diffusion / geological disposal / Np |
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| Research Abstract |
Diffusion behavior of radionuclides in compacted bentonite plays an important role in the performance assessment of bentonite buffer material in geological disposal of high-level radioactive waste. Microstructure of bentonite is considered to be one of the key parameters to affect the diffusion behavior. In this study, therefore, two kinds of montmorillonite(major clay mineral of bentonite)with different particle sizes were prepared, and characterized with several methods. In addition, the diffusion coefficients of HTO, Np(V)ions, Cs^+ ions, Cl^- ions, Ca^<2+> ions and He gas were determined using the montmorillonite samples with different particle sizes and dry densities. It was found that the montmorillonite layers, which compose the montmorillonite particles, have the same size, even if the particle sizes of the samples are different. In addition, the apparent diffusion coefficients of HTO and Cl^- for the fine grained sample were found to be higher tthan for the coarse grained sample at two dry densities, 1.0 and 1.8 Mg m^<-3>, while the opposite particle size effect was observed for Cs^+ ions. These findings cannot be explained by the conventional diffusion model, "pore water diffusion model". The activation energies for diffusion of Np(V), Cl^- and Ca^<2+> ions seemed to be closely related to the basal spacings of the montmorillonite. This suggests the contribution of the diffusion of ions in the interlayer of the montmorillonite. The contribution of a surface diffusion is also suggested for diffusion of Na^+ ions in the mixture of montmorillonite and silica sand. The sorption behavior of Se and Np were studied for Na-and Fe(II)-montmorillonite. The effects of exchangeable cations on the sorption coefficients were found in this study.
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