| Project/Area Number |
11440096
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
固体物性Ⅰ(光物性・半導体・誘電体)
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| Research Institution | Department of Materials Science and chemistry, Faculty of Systems Engineering, Wakayama University |
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Principal Investigator |
KAN'NO Ken-ichi Department of Materials Science and Chemistry, Professor, システム工学部, 教授 (80024339)
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| Co-Investigator(Kenkyū-buntansha) |
ITOH Chihiro Department of Materials Science and Chemistry, Associated Professor, システム工学部, 助教授 (60211744)
YAMAKADO Yuzo Department of Materials Science and Chemistry, Associated Professor, システム工学部, 助教授 (30242035)
SHINOZUKA Yuzo Department of Materials Science and Chemistry, Professor, システム工学部, 教授 (30144918)
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| Project Period (FY) |
1999 – 2001
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| Project Status |
Completed (Fiscal Year 2001)
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| Budget Amount *help |
¥14,600,000 (Direct Cost: ¥14,600,000)
Fiscal Year 2001: ¥1,700,000 (Direct Cost: ¥1,700,000)
Fiscal Year 2000: ¥4,100,000 (Direct Cost: ¥4,100,000)
Fiscal Year 1999: ¥8,800,000 (Direct Cost: ¥8,800,000)
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| Keywords | fullerene / carbon cluster / photo-polymezation / structural change / photoluminescence / absorption edge / photoconductivity / Raman scattering / フレンケル励起子 / ナノクラスター / アーバックテール / 光誘起固相重合 / 光物性 / ルミネッセンス |
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| Research Abstract |
Photoluminescence and near-band-edge electronic structure of pristine C_<60> single crystals have been investigated in the low temperature phase below 90K. By applying two-photon excitation spectroscopy, a monomorphic spectrum is extracted from the several crystals which exhibit apparent diversity for ordinary one-photon excitation. Also, a localized absorption band with discrete vibronic sub-peaks is clearly confirmed at 1.685 eV below the fundamental absorption edge (1.815 eV). Overall features of the luminescence-line-narrowing spectrum obtained by site-selective excitation into the localized absorp tion band are assigned to the vibronic progressions coupled with the Raman-active gerade-symmetry modes of individual C60 molecules (i.e., eight h_g, two a_g, and their combinations), accompanied by phonon-side-bands due to cooperative librations and intermolecular translations. The origin of photo luminescence and its relaxtion kinetics are fully discussed in connection with the inhomogeneously broadened localized states which are presumably due to perturbed Frenkel excitons stabilized with symmetry-lowering by adjacent intrinsic defect or some lattice disorder.
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